Download TOCSIN 102 PhotoIonisation Gas Detector Manual

TOCSIN 102PID
INSTALLATION
AND
USER INSTRUCTIONS
EEx d IIC T6
0518
II 2 D G
Sira 02ATEX1271X
OLIVER
IGD
Oliver IGD Limited
4a Pepper Road
Stockport
SK7 5BW
England
Tel:
Fax:
Email:
Web Site:
+44(0)161 483 1415
+44(0)161 484 2345
[email protected]
www.oliver-igd.co.uk
V1.0
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Table of Contents
Specification
3
CE Declaration
4
Installation
5
ATEX Junction Boxes and Sealing
Requirements
5
ATEX Markings and Electrical Interface 420mA
6
Introduction to PID
7
VOC's
8
Lamp Types and Detection Methods
9
PID Detection Sensitivity
10
PID Correction Factor Tables
12
The PID
Maintenence
Lamp Life
23
Lamp Cleaning
23
Replacing the Electrode Stack
24
Accessories
25
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PERFORMANCE
Low Range
Target gases
Minimum detection level
Linear range
Overrange
Sensitivity
Full stabilisation time
Warm up time
Response time (t 90)
VOCs with ionisation potentials < 10.6eV
(ppb isobutylene)
(ppm isobutylene)(5% deviation)
(ppm isobutylene)
(linear range) (mV / ppm Isobutylene)
(minutes to 100ppb)
(seconds) time to full operation
(seconds) diffusion mode
5
50
50
> 20
20
5
ELECTRICAL
Power consumption
Supply voltage
Output signal
0.9W typical (at 24V DC)
18 to 32VDC
Linear 4-20mA Output for set range. RS232 Interface
ENVIRONMENTAL
Temperature range
Temperature dependence
Relative humidity range
Humidity sensitvity
-10ºC to +55ºC
0°C to 40°C: 95% to 100% of signal at 25°C
-20°C: 125% of signal at 25°C
0 to 95%rh, non-condensing
Near zero
KEY SPECIFICATIONS
Expected operating life
Approval
Onboard filter
Lamp replacement
Electrode stack
Position sensitivity
Weight
5 years (excluding replaceable lamp and electrode stack)
SIRA02ATEX1271X EEXd 2C T6 2 II GD
a
To remove liquids and particulates
User replaceable (10.6 eV)
User replaceable
None
550 grams (detector excluding any junction box)
SIZE AND MOUNTING INFORMATION (OPTIONAL JUNCTION BOX/TOCSIN 903 SHOWN)
145.0
126.0
COVER SECURING SCREW
M20 x 1.5
128.5
25.0
40.0
128.0
Ø7.0
Ø110
EXTERNAL EARTH
63.7
TOCSIN 102 PID
DETECTOR SHOWN
3
High Range
100
300
6,000
> 0.6
20
5
<25
IGD
OLIVER
EC Declaration of Conformity
Oliver IGD affirm under our sole responsibility that the following
electrical equipment manufactured by us fulfills the
requirements of the:
ATEX Directive 94/9/EC,
EMC directive 2004/108/EC
LVD directive 2006/95/EC.
Oliver Ref
T102ECDEC
Product
Description
Tocsin 102
2 or 3 wire 4-20mA Gas Detector Head or Camera
Date of First Application
JULY 2007
Approval to Type
ISO9001:2000 Quality system and ATEX Quality Module
ATEX Marking
II 2 GD Ex d IIC T6 +55°C
EC Type Certificate
Notified Body Name, Number and
Address
Sira 02ATEX1271X
Sira 0539
Rake Lane,
Eccleston
Chester.
UK
Manufactured By
Oliver IGD Limited,
4a Pepper Road,
Stockport,
SK7 5BW
England.
Standards Applied
BS EN 61000-4-6 2009
BS EN 61000-4-2 2009
BS EN 60079-1 2004 inc corr 1
BS EN 60079-0 2006
BS EN 61241-0 2006
BS EN 61241-1
Oliver IGD Limited operate an ISO9001:2000 Quality System
which incorporates the requirements of the ATEX directive.
Signed
Andrew Collier.
Managing Director
75 Years In Gas Detection
PIONEERS
30 Years In Gas Analysis
Registered in England No. 1044944
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CUSTOMER SEALING AND EARTHING RESPONSABILITIES
The Tocsin 102PID is designed for use in Zone 1 and Zone 2 hazardous areas and is ATEX certified. To
maintain compliance it is imperative the installer of the equipment observes the following installation
guidelines. Failure to do so could compromise the protection concept of the equipment. The Tocsin
102PID must be installed using a junction box which is suitable for the zone into which the equipment is
being installed. Suitable junction boxes are available from Oliver IGD Limited. A typical example is
indicated.
Parallel glands and blanking
plugs should have O Ring seals
EXTERNAL EARTH TERMINAL
or sealing washers to maintain
IP66 rating use Atex rated glands
and blanking plugs
Taper glands and blanking plugs
should use suitable thread
sealant to maintain IP66 rating,
typical LOCTITE 577 use Atex
rated glands and blanking plugs
On final assembly the cover screw
must be locked in place.
Use 2mm Allen Key
Gas detectors are supplied
with sealing washers. These
must be fitted to meet
approval requirements
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TOCSIN 102PID 4-20mA 3 Wire VOC Gas Transmitter Fitting and Markings.
Blue Signal
Red +Ve
Black -Ve
Serial Programming
Interface. DO NOT
ACCESS IN A HAZARDOUS
AREA
Green
Earth
There are no user serviceable components
inside the Tocsin 102.
Do not connect to portable equipment
Observe Marked Warnings
DO NOT OPEN WHEN AN
EXPLOSIVE ATMOSPHERE
MAY BE PRESENT.
Under no circumstances should the
housing be opened in a potentially
hazardous atmosphere.
Oliver IGD Address
OLIVER IGD Ltd
4a Pepper Rd, Stockport, England
EEx d IIC T6
IP66
Rating 6W Max
Sira 02ATEX1271X
Serial Number 102PID-xxxxx-2002
0518
Environmental Rating
Test Body Report Number
Calibration should be undertaken at a
maximum of six monthly intervals.
Device Serial Number
EU 'CE' Marking and ATEX Lab Number
II 2 GD
ATEX Markings With Explosive Protection Marking
Explanation of Markings
Flameproof Housing Concept
Gas Group
Maximum Housing Temperature Taking
Into Account Maximum Ambient Temperature
Maximum Rating Of
Internal Circuitry
Certificate Number
EEx d IIC T6
Rating 4W Max
Sira 02ATEX1271X
IP66
Ingress Protection Rating
6-Complete Protection From
Live Components Inside
Housing, Dust Ingress
Protection
6-Protection Against
Conditions On Ships Decks
II 2 GD
Suitable For Use In
Zone 1 & 2 Areas
In Potentially Explosive
Atmospheres Due To Gases, Vapours
Mists or Dusts.
Typical Control Card
Connections 0V DC
Fitting, Instructions
24V DC
Allowable
Operating
Region
R (Ohms)
Sense
18
Blue Sig
Serial
Port
Plug
200
Black -Ve
Red +Ve
1000
250 Ohms
Green
Enclosure
Earth
32
SUPPLY VOLTS
Use Lock
Nut Supplied
Fit Fibre
Washer
Do not overtighten the 102
into the junction box housing
DO NOT OPEN WHEN AN
EXPLOSIVE ATMOSPHERE
MAY BE PRESENT.
OLIVER IGD Ltd
4a Pepper Rd, Stockport, England
EEx d IIC T6
IP66
Rating 6W Max
Sira 02ATEX1271X
Serial Number 102-xxxxx-2002
0518
CO2
0-5%
II 2 GD
6
Check Supply Voltage And Load
Resistance With Card Manufacturers
Instructions.
Note
The Tocsin 102 Must Be Earthed, If
necessary fit a brass earthing tab
washer between the locknut and
housing to bond to. Ensure the
junction box, cable and glands carry
appropriate certification for the area in
which they are fitted. Cable screens
IGD
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The PID Photo-Ionisation Detector
The Tocsin 102 PID detector measures volatile organic compounds (VOC’s) in air by photo
ionisation detection (PID), which is shown schematically below. Test gas (1) is presented to the
membrane filter at the top of the photo ionisation cell and freely diffuses into and out of the
underlying chamber formed by the filter, housing walls, and a UV lamp window. The lamp emits
photons(shown by arrows) of high energy UV light, transmitted through the window. Photo
ionisation occurs in the chamber when a photon is adsorbed by the molecule, generating two
electrically charged ions, one positively charged, X+, and one negatively charged Y- (2a). An
electric field, generated between the cathode and anode electrodes, attracts ions (2b). The
resulting current, which is proportional to the concentration of the VOC, is measured and used to
determine the gas concentration. The low range version of the Tocsin 102 PID (measuring at
ppb levels) includes a third fence electrode (patented) to ensure that the amplified current does
not include significant contributions due to other current sources such as water condensation on
the chamber walls.
Note that the Oliver IGD Tocsin 102 PID is available in high range and low range models. If
supplied as a stand alone unit then a standard linear 4-20mA output is provided along with a
diagnostic port. This can be used in conjunction with Oliver IGD configurator software for service
diagnostics and maintenance. This software can be used to set lamp duty cycles to extend lamp
life. as standard units will be shipped with a 50% duty cycle set at 10 seconds. note that the duty
cycle function is disabled once gas is detected and for 10 minutes after returning to zero. For full
details refer to the PID section of the configurator manual.
A full range of splash guards, calibration adaptors, duct adaptors, samplers and service tools are
available from Oliver IGD. In dirty environments always consider fitting splash guards to extend
service intervals.
Membrane Filter
PID housing
Test gas
1
Cathode
Fence electrode
2
Anode
Y
Lamp
window
X
2a
Photon
Lamp
body
To cathode
Y
Lamp
gas,
e.g. krypton
2b
-
+
X
To anode
What is a volatile organic compound (VOC)?
A volatile organic compound, or VOC, is a carboncontaining chemical, which is significantly or
completely vaporised at ambient temperatures.
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What volatile organic compounds (VOC’s) is sensed by PID?
Most VOC’s can be detected by PID. Notable exceptions are low molecular weight hydrocarbons.
Each VOC has a characteristic threshold energy of light (photon energy) which, when directed at
the VOC, causes it to fragment into ions. This is called the Ionisation Potential , or IP. VOC’s are
ionised (and hence detected) if light of photon energy greater than the IP interacts with the gas
sample. The peak photon energy generated in a detector depends on the PID lamp used: Xenon
= 9.6 eV, Deuterium = 10.2 eV, Krypton = 10.6 eV or Argon = 11.7 eV. Hence, the use of an argon
lamp leads to detection of the largest range of volatile compounds, while using a Xenon lamp can
increase selectivity. Lamps of a particular type
do not typically vary in spectral fingerprint, so
relative responses to a particular gas, e.g. benzene, to a particular lamp, e.g. krypton, does not
vary from lamp to lamp. However, the intensity of lamps does vary to some extent, leading to a
difference in absolute response to the calibration gas.
Sufficient volatility of a compound is also esse ntial for measurement by PID as with any other
detector. A fairly large molecule such as alpha pinene, (a constituent of turpentine), saturates in air
at about 5000 ppm at 20 oC; this is the maximum concentration at which the compound will usually
be detected. Some compounds, for example, machine oils and agrochemicals - generate only a
few ppm of vapour at ambient temperatures; it is more difficult to detect these compounds in air.
Which lamp is best?
The choice of lamp depends on target gases, selectivity requirements and lamp lifetime
considerations. Where possible the krypton lamp is used for the high sensitivities it delivers.
Xenon lamp (9.6 eV)
Many aromatics and unsaturated VOC’s compounds c ontaining at least 6 carbon atoms (‘C6’) or
more are detected. Sometimes it is an advantage to use the xenon lamp to ensure more selective
detection of such compounds.
Krypton lamp (10.6 eV)
Some C2, and most C3, C4+ VOC’s are detected. Exceptions usually contain chlorine, fluorine or
bromine. For guidance, you can expect the following to be detected with Krypton-PID:
•
•
•
•
•
•
All hydrocarbons, whose chemical names end in the letters
–ane, –ene or –yne, except
methane, ethane, propane, and acetylene, and also except if the name includes ‘ chloro’,
‘fluoro’ or ‘bromo’:
All alcohol’s, whose chemical names end in –ol, except methanol, or frequently if the name
includes ‘chloro’, ‘fluoro’ or ‘bromo’
All aldehydes, whose names end in aldehyde, except formaldehyde, or sometimes if the
name includes ‘chloro’, ‘fluoro’ or ‘bromo’
All ketones, whose chemical names end in
–one, except rarely if the name includes
‘chloro’, ‘fluoro’ or ‘bromo’
All esters, whose names end in –ate, except rarely if the name includes ‘ chloro’, ‘fluoro’ or
‘bromo’
All amines, sulfides
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Argon lamp (11.7 eV)
All VOC’s detectable with the kryton lamp, plus acetylene, methanol, formaldehyde and about 80%
of VOC’s whose chemical names include ‘ fluoro’, ‘chloro’ and ‘ bromo’. However, this lamp has a
very short lifetime because the UV window is made from Lithium Fluoride, which is prone to
degradation.
What is a response factor?
The sensitivity of PID varies according to the type of lamp used (krypton, argon or xenon) and the
VOC detected. A response factor is a number, which relates the PID response to a particular
VOC, to the PID response to the calibration gas, usually isobutylene. If the response of a PID to a
particular VOC were eight times smaller than it is for the same concentration of isobutylene, then
the response factor would be 8. Similarly, if the response factor for a particular VOC is 0.5, the
PID response is twice that for isobutylene at the same concentration.
Example:
•
•
•
•
•
A sensor is calibrated using isobutylene and found to have a sensitivity of 2-mV ppm -1.
If the sensor is exposed to 100-ppm isobutylene the output will be 200 mV.
Toluene is known to generate twice the response of isobutylene.
If the sensor is exposed to 100-ppm toluene the output will be 400 mV.
In order to correct the response it is multiplied by the response factor for toluene of 0.5.
If response factors are programmed into an instrument, you are able to specify a volatile
compound, and the instrument will internally compensate for the response factor corresponding to
that volatile, and display and record the corrected volatile concentration.‘
.
Are there other ways to measure VOC’s?
PID's show excellent sensitivity, a large dynamic range and allow ppb-low ppm measurement of
VOC’s in a background of higher inorganic gas concentrations. But there are other technologies to
measure VOC’s:
Flame Ionisation Detectors (FID)
Very similar to PID’s, FID's are frequently used in laboratories for detecting VOC’s eluted from a
gas chromatograph. FID’s like PID’s are not selective, indeed all organic compounds including
methane are selected, and FID’s can be very sensitive and linear. But FID’s require a hydrogen
source, are bulky and more expensive. FID’s are
good in the lab or for fixed sites, but are not
currently a viable alternative in portable VOC monitoring.
Portable GC/MS
This traditional laboratory analytical instrument is seeing its way into the field with mixed results.
With micro machined silicon (MEMS), portable MS and portable GC may still become a real
alternative, but the cost is prohibitive. Sinc e GC/MS can only cycle through a measurement, it is
not a continuous monitor, but measures about once every few minutes. It does have the
advantage of being selective - it is not a broad band analyser. Size, cost, need for a vacuum pump
and maintenance requirements make this only an alternative when all else fails.
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Thermal Desorption or Tedlar sampling bags
For retrospective analysis of all VOC’s adsorbed in soil samples, other solids, liquids and gases,
the ASTM recommends using sorbent tubes or Tedlar sampling bags. Samples are then sent to
the lab for thermal desorption of the sorbent tubes and then analysis using GC/MS, traditionally.
This is the best technique when surveying a spec
ific problem, but clearly does not provide
protection in real time. Also, these are averaged measurements, expensive and not point/timespecific.
Electrochemical sensors
You can measure many VOC’s with electrochem ical cells, with resolution from 10 to 200 ppb.
These are low cost, low power, and compact sensors. Oliver IGD offers the ETO sensor for
VOC applications. Both PID’s and electrochemical cells are broad band sensors, but with a
different profile - PID’s will measure more VOC’s than the ETO, and with much greater
sensitivity. If you wish to measure a VOC with electrochemical cells, then you should optimise the
electrochemical sensor for the target VOC: each VOC will require a different ideal bias voltage for
best sensitivity. Not an easy task. Electrochemical cells respond in about 25 seconds, vs. 3-4
seconds for PID’s.
Metal Oxide Semiconductor sensors (MOS)
Metal oxide sensors will also measure VOC’s; they are compact, low cost and similar power to
PID’s. MOS sensors suffer from humidity sensitivity, non-linear response and long term drift. They
also respond to inorganic gases, so you should not use them if you are trying to measure low
concentrations of VOC’s where gases such as NO, NO2 or CO are present in higher
concentrations. Unfortunately, it is all too easy to get false positive and false negatives when using
MOS technology. If you want to use MOS, then request confirmation of long term stability, and
humidity sensitivity. If you want high sensitivit y, particularly to VOC’s not measured by PID ( i.e.
many CFC’s), but don’t care about accuracy and cross sensitivity, MOS sensors may provide a
possible solution.
Colorimetric (“Stain”) tubes
Well-established technology for sampling for specific VOC’s, colorimetric tubes have been around
for decades, supplied chiefly by Draeger or Ki ttegawa. They have the advantage of low one-off
cost and some specificity, but the disadvantages include disposal
of chemical waste (the
disposable tubes often contain toxic chemicals), poor accuracy, human interpretation of the colour
change, sampling problems and non-continuous measurements: they should not be used to
protect, only to qualitatively sample.
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Calibration Factors
Oliver IGD PID's are calibrated using isobutylene, but the PID is a broadband
VOC detector, with a sensitivity that differs for each VOC. If you know what VOC you are
measuring, then the table below will allow you to calculate the concentration for your specific
VOC. Remember, these are approximate values, so for best accuracy you should calibrate
with the relevant VOC.
The table includes six columns:
1
Gas/ VOC The most common name for the VOC. If you can not find the name of
your VOC of concern, then email us at
[email protected] and we will
help.
2
CAS No. You can find the VOC using the CAS No.: ask your supplier.
3
Formula To assist in identifying the VOC.
4
Relative Response/ Correction Factor (CF) also called the Response Factor
(RF). Multiply the displayed concentration by the Relative Response/ CF/ RF to
calculate the actual concentration of the VOC.
5
Relative sensitivity (%) This is the inverse of the correction factor, specifying
the percent response of the VOC, relative to isobutylene. If less than 100%, then
the VOC is less responsive than isobutyl ene; if the relative sensitivity is greater
than 100%, then the VOC is more re sponsive than isobutylene. Relative
sensitivity (%) is specified the same
way as cross-sensitivity for toxic gas
sensors.
6
Minimum Detection Level (MDL) Also called Minimum Detectable Quantity
(MDQ). Typical lowest concentration that can be detected. The PID-AH has
greater sensitivity than the PID-A1, so the MDL for the PID-AH will be much less
than the MDL for the PID-A1.
The Relative Response/ CF/ RF is measured in dry air; high humidity will reduce this factor by
30% to 50%, so the CF/ RF should be increased in high humidities.
VOC response
The PID can not measure all VOC’s or gases. Two types of VOC’s are not measured:
ZR: No response. The 10.6 eV lamp does not ionise the VOC and the VOC can not be
measured.
NV: The vapour pressure of the VOC at 20 °C is less than a few ppm, so this Semi-Volatile
Organic Compound (SVOC) can not be measured.
Occasionally you will be measuring a mixture of VOC’s. If the total concentration is within the
linear range of your PID, then it is reasonable to assume that the concentrations are additive
without interference between the different VOC’ s. Remember that if you are measuring a
combination of VOC’s, then accurate measur ement of one of these VOC’s will be difficult;
without careful data analysis, you will get only a CF averaged measurement *. Be cautious
when reporting actual VOC concentration if
you know that there may be several VOC’s
present.
Balance gas
The relative response is measured in laborat ory air, with 20.9% oxygen, balance nitrogen.
Some gases absorb UV light without causing any PID response ( e.g. methane, ethane). In
ambient atmospheres where these gases are present, the measured concentration of target
gas will be less than is actually present. Methane absorbs UV strongly, so for accurate
measurements in methane containing atmospheres, calibrate with a calibration gas containing
the expected methane concentration. 50% LE L methane reduces the reading by up to 50%.
Gases such as nitrogen and helium do not absorb UV and do not affect the relative response.
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The correction factor for a gas mix containing PID detectable gases A, B, C… with response
factors RF (A), RF (B), RF(C), in relative proportions a: b: c… is given by:
CF (mix) = 1 / [(a/CF (A) + b/CF (B) + c/CF(C)…]
Accuracy of the Table
This table is for indication only. Table accura cy is 1 to 2 digits only, so when calculating
concentration for a specific VOC, specify to 1 or 2 digits only.
For best accuracy, calibrate using the specific VOC.
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Gas/ VOC
Acetaldehyde
Acetic Acid
Acetic Anhydride
Acetone
Acetonitrile
Acetylene
Acrolein
Acrylic Acid
Acrylonitrile
Allyl alcohol
Allyl chloride
Ammonia
Amyl acetate, nAmyl alcohol
Aniline
Anisole
Arsine
Asphalt, petroleum fumes
Benzaldehyde
Benzene
Benzenethiol
Benzonitrile
Benzyl alcohol
Benzyl chloride
Benzyl formate
Biphenyl
Bis(2,3-epoxypropyl) ether
Boron trifluoride
Bromine
Bromine pentafluoride
Bromobenzene
Bromochloromethane
Bromoethane
Bromoethyl methyl ether, 2-
Bromoform
Bromopropane, 1Bromotrifluoromethane
Butadiene
Butadiene diepoxide, 1,3Butane, nButanol, 1Buten-3-ol, 1Butene, 1Butoxyethanol, 2Butyl acetate, nButyl acrylate, nButyl lactate
Butyl mercaptan
Butylamine, 2Butylamine, nCamphene
Carbon dioxide
CAS No.
75-07-0
64-17-7
108-24-7
67-64-1
75-05-8
74-86-2
107-02-8
79-10-7
107-13-1
107-18-6
107-05-1
7664-41-7
628-63-7
71-41-0
62-53-3
100-66-3
7784-42-1
8052-42-4
100-52-7
71-43-2
108-98-5
100-47-0
100-51-6
100-44-7
104-57-4
92-52-4
2238-07-5
7637 07 2
7726-95-6
7789-30-2
108-86-1
74-97-5
74-96-4
6482-24-2
75-25-2
106-94-5
75-63-8
106-99-0
1464-53-5
106-97-8
71-36-3
598-32-3
106-98-9
111-76-2
123-86-4
141-32-2
138-22-7
109-79-5
513-49-5
109-73-9
565-00-4
124-38-9
Formula
Relative
Relative
response sensitivity (%)
C2H4O
C2H4O2
C4H6O3
C3H6O
CH3CN
C2H2
C3H4O
C3H4O2
C3H3N
C3H6O
C3H5Cl
H3N
C7H14O2
C5H12O
C6H7N
C7H8O
AsH3
4.9
36.2
4.0
0.7
ZR
ZR
4.0
2.7
ZR
2.1
4.5
8.5
1.8
3.2
0.5
0.5
2.5
1.0
0.9
0.5
0.7
0.7
1.3
0.6
0.8
0.4
3.0
ZR
20.0
ZR
0.7
ZR
5.0
2.5
2.8
1.3
ZR
0.8
4.0
46.3
4.0
1.2
1.3
1.1
2.4
1.5
2.5
0.5
0.9
1.0
0.5
ZR
C7H6O
C6H6
C6H5SH
C7H5N
C7H8O
C7H7Cl
C8H8O2
C12H10
C6H10O3
BF3
Br2
BrF5
C6H5Br
CH2ClBr
C2H5Br
C3H7OBr
CHBr3
C3H7Br
CF3Br
C4H6
C4H6O2
C4H10
C4H10O
C4H8O
C4H8
C6H14O2
C6H12O2
C7H12O2
C7H14O3
C4H10S
C4H11N
C4H11N
C10H16
CO2
13
Typical MDL
Typical MDL
Low Range (ppb)
High Range (ppb)
21
3
25
140
25
180
20
5
480
3615
400
70
25
36
20
15
400
275
48
22
12
56
31
200
211
40
100
117
200
143
141
80
182
130
250
33
10
20
40
10
15
3
2
15
5
5
3
4
4
6
3
5
2
15
200
450
850
180
320
50
50
250
100
85
50
70
70
125
55
77
40
300
5
100
2000
143
4
70
20
40
36
77
25
15
15
7
500
250
280
130
120
25
2
25
87
77
91
41
67
40
185
111
100
222
4
20
230
20
6
7
6
10
8
15
3
5
5
2
80
400
4600
400
115
130
110
240
150
250
50
90
100
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Gas/ VOC
Carbon disulfide
Carbon monoxide
Carbon tetrabromide
Carbon tetrachloride
Carbonyl sulphide
Carvone, RChlorine
Chlorine dioxide
Chlorine trifluoride
CAS No.
75-15-0
630-08-0
558-13-4
56-23-5
463-58-1
6485-40-1
7782-50-5
10049-04-4
7790-91-2
Chloro-1,1,1,2-tetrafluoroethane
2837-89-0
Chloro-1,1,1-trifluoroethane, 275-88-7
Chloro-1,1,2,2-tetrafluoroethane
354-25-6
Chloro-1,1,2-trifluoroethane, 1421-04-5
Chloro-1,1-difluoroethane, 175-68-3
Chloro-1,1-difluoroethane, 175-68-3
Chloro-1,1-difluoroethane, 2338-65-8
Chloro-1,2,2-trifluoroethane
431-07-2
Chloro-1,3-butadiene, 2126-99-8
Chloro-1-fluoroethane, 1- 1615-75-4
Chloro-2-fluoroethane, 1762-50-5
Chloroacetaldehyde
107-20-0
Chlorobenzene
108-90-7
Chlorodifluoromethane
75-45-6
Chloroethane
75-00-3
Chloroethanol 2107-07-3
Chloroethyl methyl ether, 2627-42-9
Chlorofluoromethane
593-70-4
Chloroform
67-66-3
Chloromethane
74-87-3
Chloropentafluoroethane
76-15-3
Chlorotoluene, o95-49-8
Chlorotoluene, p108-41-8
Chlorotrifluoroethylene
79-38-9
Chlorotrifluoromethane
75-72-9
Citral
5392-40-5
Citronellol
26489-01-0
Cresol, m108-39-4
Cresol, o95-48-7
Cresol, p106-44-5
Crotonaldehyde
4170-30-3
Cumene
98-82-8
Cyanamide
420-04-2
Cyanogen bromide
506-68-3
Cyanogen chloride
506-77-4
Cyclohexane
110-82-7
Cyclohexanol
108-93-0
Cyclohexanone
108-94-1
Cyclohexene
110-83-8
Cyclohexylamine
108-91-8
Cyclopentane
287-92-3
Decane, n124-18-5
Diacetone alcohol
123-42-2
Dibenzoyl peroxide
94-36-0
Formula
IGD
Relative
Relative
response sensitivity (%)
CS2
1.4
71
CO
ZR
CBr4
3.0
33
CCl4
ZR
COS
ZR
C10H14O
1.0
100
Cl2
ZR
ClO2
1.0
100
ClF3
ZR
C2HClF4
ZR
C2H2ClF3
ZR
C2HClF4
ZR
C2H2ClF3
ZR
C2H3ClF2
ZR
C2H3ClF2
ZR
C2H3ClF2
ZR
C2H2ClF3
ZR
C4H5Cl
3.2
30
C2H4ClF
ZR
C2H4ClF
ZR
C2H3OCl
ZR
C6H5Cl
0.5
220
CHClF2
ZR
C2H5Cl
ZR
C2H5ClO
10.0
10
C3H7ClO
2.6
40
CH2ClF
ZR
CHCl3
ZR
CH3Cl
ZR
C2ClF5
ZR
C7H7Cl
0.5
220
C7H7Cl
0.5
200
C2ClF3
1.0
100
CClF3
ZR
C10H16O
1.0
100
C10H20O
1.0
100
C7H8O
1.1
95
C7H8O
1.1
95
C7H8O
1.1
95
C4H6O
1.0
100
C9H12
0.6
170
CH2N2
ZR
CNBr
ZR
CNCl
ZR
C6H12
1.3
77
C6H12O
2.9
34
C6H10O
1.1
91
C6H10
0.8
133
C6H13N
1.0
102
C5H10
4.0
25
C10H22
1.0
96
C6H12O2
0.8
125
C14H10O4
0.8
125
14
Typical MDL
Typical MDL
Low Range (ppb)
High Range (ppb)
7
140
15
300
5
100
5
100
16
320
2
50
50
13
1000
250
2
3
5
50
50
100
5
5
5
5
5
5
3
100
100
105
105
105
100
60
7
15
6
5
5
20
5
5
5
130
300
110
75
100
400
100
80
80
IGD
OLIVER
Gas/ VOC
CAS No.
Formula
Diborane
19287-45-7 B2H6
Dibromochloromethane
124-48-1 CHBr2Cl
Dibromodifluoromethane
75-61-6
CF2Br2
Dibromoethane 1,2106-93-4 C2H4Br2
Dibromotetrafluoroethane 124-73-2 C2F4Br2
, 1,2Dibutyl hydrogen
107-66-4 HC8H18
phosphate
PO4
Dichloro-1,1,1306-83-2 C2HCl2F3
trifluoroethane, 2,2Dichloro-1,11649-08-7 C2H2Cl2F2
difluoroethane, 1,2Dichloro-1,2,2354-23-4 C2HCl2F3
trifluoroethane, 1,2Dichloro-1,2631-06-1 C2H2Cl2F2
difluoroethane, 1,2Dichloro-1-fluoroethane, 1,1- 1717-00-6 C2H3Cl2F
Dichloro-1-fluoroethane, 1,1- 1717-00-6 C2H3Cl2F
Dichloro-1-fluoroethane, 1,2430-57-9 C2H3Cl2F
Dichloro-1-propene, 2,378-88-6
C3H4Cl2
C2H2Cl2F2
Dichloro-2,2,79-35-6
difluoroethane, 1,1Dichloroacetylene
7572-29-4 C2Cl2
Dichlorobenzene o95-50-1
C6H4Cl2
Dichlorodifluoromethane
75-71-8
CCl2F2
Dichloroethane 1,2107-06-2 C2H4Cl2
Dichloroethane, 1,175-34-3
C2H4Cl2
Dichloroethene, 1,175-35-4
C2H2Cl2
Dichloroethene, cis-1,2156-59-2 C2H2Cl2
Dichloroethene, trans-1,2540-59-0 C2H2Cl2
Dichloroethylene 1,2540-59-0 C2H2Cl2
Dichlorofluoromethane
75-43-4
CHFCl2
Dichloromethane
75-09-2
CH2Cl2
Dichloropropane, 1,278-87-5
C3H6Cl2
Dichlorotetrafluoroethane, 1,1374-07-2 C2Cl2F4
Dichlorotetrafluoroethane, 1,276-14-2
C2Cl2F4
Dicyclopentadiene
77-73-6
C10H12
Diesel Fuel
68334-30-5
Diethyl ether
60-29-7
C4H10O
Diethyl maleate
141-05-9 C8H12O4
Diethyl phthalate
84-66-2
C12H14O4
Diethyl sulphate
64-67-5
C4H10SO4
Diethyl sulphide
352-93-2 C4H10S
Diethylamine
109-89-7 C4H11N
Diethylaminoethanol, 2100-37-8 C6H15ON
Diethylaminopropylamine, 3104-78-9 C7H18N2
Difluoroethane, 1,175-37-6
C2H4F2
Difluoroethane, 1,2624-72-6 C2H4F2
Difluoromethane
75-10-5
CH2F2
Dihydrogen selenide
7783 07 5 H2Se
Dihydroxybenzene, 1,2
120-80-9 C6H6O2
Dihydroxybenzene, 1,3
108-46-3 C6H6O2
Diisobutylene
107-39-1 C8H16
Diisopropyl ether
108-20-3 C6H14O
Diisopropylamine
108-18-9 C6H15N
15
Relative
Relative
response sensitivity (%)
ZR
10.0
10
ZR
2.0
50
ZR
4.0
Typical MDL
Typical MDL
Low Range (ppb)
High Range (ppb)
50
1000
10
200
25
20
400
70
7
140
20
200
25
3
500
50
105
125
143
133
5
4
4
4
100
80
70
75
3
200
3900
110
130
110
50
100
33
180
100
40
100
5
4
4
10
5
15
3
5
15
5
90
75
90
200
100
300
50
100
270
100
100
100
100
156
150
140
5
5
5
3
3
4
100
100
100
60
70
70
ZR
ZR
ZR
ZR
ZR
ZR
ZR
1.4
ZR
5.0
0.5
ZR
ZR
ZR
1.0
0.8
0.7
0.8
ZR
39.0
ZR
ZR
ZR
0.9
0.8
0.9
2.0
1.0
3.0
0.6
1.0
2.7
1.0
ZR
ZR
ZR
1.0
1.0
1.0
0.6
0.7
0.7
OLIVER
Gas/ VOC
Diketene
Dimethoxymethane
Dimethyl cyclohexane, 1,2-
Dimethyl disulphide
Dimethyl ether
Dimethyl phthalate
Dimethyl sulphate
Dimethyl sulphide
Dimethylacetamide N,NDimethylamine
Dimethylaminoethanol
Dimethylaniline, NNDimethylbutyl acetate
Dimethylethylamine, NNDimethylformamide
Dimethylheptan-4-one, 2,6-
Dimethylhydrazine, 1,1Dinitrobenzene, mDinitrobenzene, oDinitrobenzene, pDinonyl phthalate
Dioxane 1,2Dioxane 1,4Dipentene
Diphenyl ether
Disulphur decafluoride
Disulphur dichloride
Di-tert-butyl-p-cresol
Divinylbenzene
Dodecanol
Enflurane
Epichlorohydrin
Epoxypropyl isopropyl ether, 2,3-
Ethane
Ethanol
Ethanolamine
Ethoxy-2-propanol, 1Ethoxyethanol, 2Ethoxyethyl acetate, 2Ethyl (S)-(-)-lactate
Ethyl acetate
Ethyl acrylate
Ethyl amine
Ethyl benzene
Ethyl butyrate
Ethyl chloroformate
Ethyl cyanoacrylate
Ethyl decanoate
Ethyl formate
Ethyl hexanoate
Ethyl hexanol, 2Ethyl hexyl acrylate, 2Ethyl mercaptan
CAS No.
674-82-8
109-87-5
583-57-3
624-92-0
115-10-6
131-11-3
77-78-1
75-18-3
127-19-5
124-40-3
108-01-0
121-69-7
108-84-9
598-56-1
68-12-2
108-83-8
57-14-7
99-65-0
528-29-0
100-25-4
84-76-4
123-91-1
138-86-3
101-84-8
5714-22-7
10025-67-9
2409-55-4
1321-74-0
112-53-8
13838-16-9
106-89-8
4016-14-2
74-84-0
64-17-5
141-43-5
1569-02-4
110-80-5
111-15-9
97-64-3
141-78-6
140-88-5
75-04-7
100-41-4
105-54-4
541-41-3
7085-85-0
110-38-3
109-94-4
123-66-0
105-76-7
103-11-7
75-08-1
Formula
C4H4O2
C3H8O2
C8H16
C2H6S2
C2H6O
C10H10O4
C2H6O4S
C2H6S
C4H9NO
C2H7N
C4H11NO
C8H11N
C8H16O2
C4H11N
C3H7NO
C9H18O
C2H8N2
C6H4N2O4
C6H4N2O4
C6H4N2O4
C26H42O4
C4H8O2
C4H8O2
C10H16
C12H10O
S2F10
S2Cl2
C11H16O
C10H10
C12H26O
C4H2F5ClO
C3H5ClO
C6H12O2
C2H6
C2H6O
C2H7NO
C5H10O2
C4H10O2
C6H12O3
C5H10O3
C4H8O2
C5H8O2
C2H7N
C8H10
C6H12O2
C3H5O2Cl
C6H7O2N
C12H24O2
C3H6O2
C8H16O2
C8H18O
C11H20O2
C2H6S
16
IGD
Relative
Relative
response sensitivity (%)
2.2
45
1.4
71
1.1
95
0.2
435
1.3
80
1.0
100
ZR
0.5
200
1.3
75
1.4
70
1.5
70
0.6
167
1.6
60
0.8
125
0.9
110
0.8
125
1.0
100
3.0
33
ZR
5.0
20
1.0
100
1.5
67
1.5
67
0.9
110
0.8
125
ZR
3.0
33
1.0
100
0.4
250
0.9
110
ZR
8.0
15
1.1
90
ZR
8.7
10
3.0
33
2.0
50
29.8
3
3.0
33
3.0
33
3.6
28
2.0
50
1.0
100
0.5
185
1.0
105
80
1
1.5
67
1.8
56
30
3
2.6
38
1.5
67
1.0
100
0.7
145
Typical MDL
Typical MDL
Low Range (ppb)
High Range (ppb)
11
7
5
1
7
5
220
140
105
23
130
100
3
7
7
8
3
8
4
5
4
5
15
50
130
140
150
60
160
80
90
80
100
300
25
5
8
8
5
4
500
100
150
150
90
80
15
5
2
5
300
100
40
90
40
5
800
110
45
15
10
150
15
15
20
10
5
3
5
400
8
10
150
15
8
5
3
870
300
200
3000
300
300
360
200
100
50
100
8300
150
180
3000
260
150
100
70
IGD
OLIVER
Gas/ VOC
Ethyl octanoate
Ethylene
Ethylene dinitrate
Ethylene glycol
Ethylene oxide
Ferrocene
Fluorine
Fluoroethane
Fluoromethane
Formaldehyde
Formamide
Formic acid
Furfural
Furfuryl alcohol
Gasoline vapors
Gasoline vapors
Gasoline vapors 92 octane
Germane
Glutaraldehyde
Halothane
Helium
Heptan-2-one
Heptan-3-one
Heptane nHexachloroethane
Hexafluoroethane
Hexamethyldisilazane,
1,1,1,3,3,3-.
Hexamethyldisiloxane.
Hexan-2-one
Hexane nHexene, 1Hydrazine
Hydrazoic acid
Hydrogen
Hydrogen bromide
Hydrogen chloride
Hydrogen cyanide
Hydrogen fluoride
Hydrogen peroxide
Hydrogen sulfide
Hydroquinone
Hydroxypropyl acrylate 2-
Iminodi(ethylamine) 2,2Iminodiethanol 2,2'Indene
Iodine
Iodoform
Iodomethane
Isoamyl acetate
Isobutane
Isobutanol
Isobutyl acetate
CAS No.
106-32-1
74-85-1
628-96-6
107-21-1
75-21-8
102-54-5
7782-41-4
353-33-6
593-53-3
50-00-0
75-12-7
64-18-6
98-01-1
98-00-0
8006-61-9
8006-61-9
8006-61-9
7782-65-2
111-30-8
151-67-7
110-43-0
106-35-4
142-82-5
67-72-1
76-16-4
999-97-3
107-46-0
591-78-6
110-54-3
592-41-6
302-01-2
7782-79-8
1333-74-0
10035-10-6
7647-01-0
74-90-8
7664-39-3
7722-84-1
7783-06-4
123-31-9
999-61-1
111-40-0
111-42-2
95-13-6
7553-56-2
75-47-8
74-88-4
123-92-2
75-28-5
78-83-1
110-19-0
Formula
Relative
Relative
response sensitivity (%)
C10H20O2
2.3
40
C2H4
8.0
13
C2H4O6N2
ZR
C2H6O2
20.0
5
C2H4O
15.0
7
C10H10Fe
0.8
125
F2
ZR
C2H5F
ZR
CH3F
ZR
CH2O
ZR
CH3ON
2.0
50
CH2O2
ZR
C5H4O2
1.4
70
C5H6O2
2.0
50
1.1
95
0.8
125
0.8
125
GeH4
10.0
10
C5H8O2
0.9
111
CF3CHBrCl
ZR
He
ZR
C7H14O
0.7
140
C7H14O
0.8
133
C7H16
2.1
50
C2Cl6
ZR
C2F6
ZR
C6H19NSi2
1.0
100
C6H18OSi2
C6H12O
C6H14
C6H12
H4N2
HN3
H2
HBr
HCl
HCN
HF
H2O2
H2S
C6H6O2
C6H10O3
C4H13N3
C4H11NO2
C9H8
I2
CHI3
CH3I
C7H14O2
C4H10
C4H10O
C6H12O2
17
0.3
0.8
4.2
0.9
3.0
ZR
ZR
ZR
ZR
ZR
ZR
4.0
4.0
0.8
1.5
0.9
1.6
0.5
0.2
1.5
0.4
1.6
8.0
3.5
2.3
Typical MDL
Typical MDL
Low Range (ppb)
High Range (ppb)
12
40
230
800
100
75
4
2000
1500
80
10
200
7
10
5
4
4
50
5
140
200
105
80
80
1000
90
4
4
10
70
75
200
5
100
350
125
25
110
33
1
4
20
5
15
30
80
420
90
300
25
25
125
67
110
60
220
667
67
250
60
15
30
45
20
20
4
8
5
8
2
1
8
2
8
40
20
10
400
400
80
150
90
160
50
15
150
40
160
800
350
230
IGD
OLIVER
Gas/ VOC
Isobutyl acrylate
Isobutylene
Isobutyraldehyde
Isocyanates, all
Isodecanol
Isoflurane
Isononanol
Isooctane
Isooctanol
Isopentane
Isophorone
Isoprene
Isopropanol
Isopropyl acetate
Isopropyl chloroformate
Jet Fuel JP-4
Jet Fuel JP-5
Jet Fuel JP-8
Kerosene
Ketene
Liquefied petroleum gas
Maleic anhydride
Mercaptoacetic acid
Mercury
Mercury alkyls
Mesitylene
Methacrylic acid
Methacrylonitrile
Methane
Methanol
Methoxyethanol, 2Methoxyethoxyethanol, 2Methoxymethylethoxy-2propanol
Methoxypropan-2-ol
Methoxypropyl acetate
Methyl acetate
Methyl acrylate
Methyl bromide
Methyl cyanoacrylate
Methyl ethyl ketone
Methyl ethyl ketone peroxides
Methyl formate
Methyl isobutyl ketone
Methyl isocyanate
Methyl isothiocyanate
Methyl mercaptan
Methyl methacrylate
Methyl propyl ketone
Methyl salicylate
Methyl sulphide
Methyl t-butyl ether
Methyl-2-propen-1-ol, 2-
CAS No.
Formula
106-63-8
115-11-7
78-84-2
C7H12O2
C4H8
C4H8O
25339-17-7
26675-46-7
2452-97-9
565-75-3
26952-21-6
78-78-4
78-59-1
78-79-5
67-63-0
108-21-4
108-23-6
C10H22O
C3H2ClF5O
C9H20O
C8H18
C8H18O
C5H12
C9H14O
C5H8
C3H8O
C5H10O2
C4H7O2Cl
8008-20-6
463-51-4
68476-85-7
108-31-6
68-11-1
7439-97-6
C4H2O3
C2H4O2S
Hg
108-67-8
79-41-4
126-98-7
74-82-8
67-56-1
109-86-4
111-77-3
34590-94-8
C9H12
C4H6O2
C4H5N
CH4
CH4O
C3H8O2
C5H12O3
C7H16O3
C2H2O
107-98-2 C4H10O2
108-65-6 C6H12O3
79-20-9
C3H6O2
96-33-3
C4H6O2
74-83-9
CH3Br
137-05-3 C5H5O2N
78-93-3
C4H8O
1338-23-4 C8H18O2
107-31-3 C2H4O2
108-10-1 C6H12O
624-83-9 C2H3NO
556-61-6 C2H3NS
74-93-1
CH4S
80-62-6
C5H8O2
107-87-9 C5H10O
119-36-8 C8H8O3
75-18-3
C2H6S
1634-04-4 C5H12O
51-42-8
C4H8O
18
Relative
Relative
response sensitivity (%)
1.3
80
1.0
100
1.2
80
NV
0.9
110
ZR
1.5
67
1.1
90
1.7
60
6.0
20
0.8
133
0.7
140
4.4
20
2.2
50
1.6
60
0.8
133
0.7
150
0.7
150
0.8
120
3.0
33
ZR
2.0
50
1.0
100
NV
NV
0.3
300
2.3
40
5.0
20
ZR
200
1
2.7
40
1.4
70
1.3
80
3.0
1.2
5.2
3.4
1.9
5.0
0.8
0.8
ZR
0.8
ZR
0.6
0.7
1.6
0.8
1.2
0.5
0.8
1.1
Typical MDL
Typical MDL
Low Range (ppb)
High Range (ppb)
7
5
6
130
100
120
5
90
8
5
9
30
4
3
22
10
8
4
3
3
4
15
150
100
170
600
75
70
440
220
160
75
60
60
90
300
10
5
200
100
2
12
25
30
230
500
1000
15
7
7
20000
270
140
130
33
80
20
30
50
20
130
125
15
6
25
17
10
25
4
4
300
120
500
340
190
500
80
80
125
4
80
167
140
60
130
80
200
125
90
3
4
8
4
6
3
4
5
60
70
160
80
120
50
80
100
IGD
OLIVER
Gas/ VOC
Methyl-2-pyrrolidinone, NMethyl-4,6-dinitrophenol, 2Methyl-5-hepten-2-one, 6-
Methylamine
Methylbutan-1-ol, 3Methylcyclohexane
Methylcyclohexanol, 4Methylcyclohexanone 2Methylheptan-3-one, 5Methylhexan-2-one, 5Methylhydrazine
Methyl-N-2,4, 6tetranitroaniline, NMethylpent-3-en-2-one, 4-
Methylpentan-2-ol, 4Methylpentane-2,4-diol, 2-
Methylpropan-2-ol, 2Methylstyrene
Mineral oil
Mineral spirits
Naphthalene
Nitric oxide
Nitroaniline 4Nitrobenzene
Nitroethane
Nitrogen dioxide
Nitrogen trichloride
Nitrogen trifluoride
Nitromethane
Nitropropane, 1Nitropropane, 2Nitrous oxide
Nonane, nNorbornadiene, 2,5Octachloronaphthalene
Octane, nOctene, 1Oxalic acid
Oxalonitrile
Oxydiethanol 2,2Oxygen
Ozone
Paraffin wax, fume
Paraffins, normal
Pentacarbonyl iron
Pentachloroethane
Pentachlorofluoroethane
Pentafluoroethane
Pentan-2-one
Pentan-3-one
Pentandione, 2,4Pentane, nPeracetic acid
CAS No.
872-50-4
534-52-1
110-93-0
74-89-5
123-51-3
108-87-2
589-91-3
583-60-8
541-85-5
110-12-3
60-34-4
479-45-8
141-79-7
108-11-2
107-41-5
75-65-0
25013-15-4
8042-47-5
64475-85-0
91-20-3
10102-43-9
100-01-6
98-95-3
79-24-3
10102-44-0
10025-85-1
7783-54-2
75-52-5
108-03-2
79-46-9
10024-97-2
111-84-2
121-46-0
2234-13-1
111-65-9
111-66-0
144-62-7
460-19-5
111-46-6
Formula
Relative
Relative
response sensitivity (%)
C5H9NO
0.9
110
C7H6N2O5
3.0
33
C8H14O
0.8
125
CH5N
1.4
70
C5H12O
3.4
30
C7H14
1.1
90
C7H14O
2.4
40
C7H12O
1.0
100
C8H16O
0.8
133
C7H14O
0.8
133
CH6N2
1.3
80
C7H5N5O8
3.0
33
C6H10O
C6H14O
C6H14O2
C4H10O
C9H10
C10H8
NO
C6H6N2O2
C6H5NO2
C2H5NO2
NO2
NCl3
NF3
CH3NO2
C3H7NO2
C3H7NO2
N2O
C9H20
C7H8
C10Cl8
C8H18
C8H16
C2H2O4
C2N2
C4H10O3
O2
10028-15-6 O3
8002-74-2
64771-72-8
13463-40-6 FeC5O5
76-01-7
C2HCl5
354-56-3 C2Cl5F
354-33-6 C2HF5
107-87-9 C5H10O
96-22-0
C5H10O
123-54-6 C5H8O2
109-66-0 C5H12
79-21-0
C2H4O3
19
0.7
2.8
4.0
3.5
0.5
0.8
0.8
0.4
8.0
0.8
1.7
ZR
10.0
1.0
ZR
ZR
ZR
ZR
ZR
1.3
0.6
1.0
1.6
0.7
ZR
ZR
4.0
ZR
ZR
1.0
1.0
1.0
ZR
ZR
ZR
0.8
0.8
0.8
7.9
2.0
Typical MDL
Typical MDL
Low Range (ppb)
High Range (ppb)
5
15
4
7
17
6
12
5
4
4
7
15
90
300
80
140
340
110
240
100
75
75
130
300
140
40
25
30
200
125
125
230
15
125
60
4
14
20
18
3
4
4
2
40
4
10
70
280
400
350
50
80
80
45
800
80
170
10
100
50
5
1000
100
80
167
100
60
140
6
3
5
8
3
130
60
100
160
70
25
20
400
100
105
100
5
5
5
100
100
100
125
125
133
15
50
4
4
4
40
10
80
80
75
800
200
IGD
OLIVER
Gas/ VOC
Perchloryl fluoride
Perfluoropropane
Petroleum ether
Phenol
Phenyl propene, 2Phenyl-2,3-epoxypropyl ether
Phenylenediamine, pPhosgene
Phosphine
Picoline, 3Pinene, alpha
Pinene, beta
Piperidine
Piperylene
Prop-2-yn-1-ol
Propan-1-ol
Propane
Propane-1,2-diol, total
Propene
Propionaldehyde
Propionic acid
Propyl acetate, nPropylene dinitrate
Propylene oxide
Propyleneimine
Pyridine
Pyridylamine 2Silane
Sodium fluoroacetate
Styrene
Sulphur dioxide
Sulphur hexafluoride
Sulphur tetrafluoride
Sulphuric acid
Sulphuryl fluoride
Terphenyls
Terpinolene
Tert-butanol
Tetrabromoethane, 1,1,2,2-
Tetracarbonylnickel
Tetrachloro-1,2difluoroethane, 1,1,2,2Tetrachloro-1fluoroethane, 1,1,2,2Tetrachloro-2,2difluoroethane, 1,1,1,2Tetrachloro-2fluoroethane, 1,1,1,2Tetrachloroethane, 1,1,1,2Tetrachloroethane, 1,1,2,2-
Tetrachloroethylene
Tetrachloronaphthalenes,
all isomers
Tetraethyl orthosilicate
Tetraethyllead
CAS No.
Formula
Relative
Relative
response sensitivity (%)
7616-94-6 Cl03F
ZR
76-19-7
C3F8
ZR
0.9
110
108-95-2 C6H6O
1.2
85
98-83-9
C9H10
0.4
230
122-60-1 C9H10O2
0.8
125
106-50-3 C6H8N2
0.6
167
75-44-5
COCl2
ZR
7803-51-2 PH3
2.0
50
108-99-6 C6H7N
0.9
110
80-56-8
C10H16
0.3
315
127-91-3 C10H16
0.3
315
110-89-4 C5H11N
0.9
110
504-60-9 C5H8
0.7
150
107-19-7 C3H4O
1.3
80
71-23-8
C3H8O
4.8
20
74-98-6
C3H8
ZR
57-55-6
C3H8O2
10.0
10
115-07-1 C3H6
1.4
70
123-38-6 C3H6O
1.7
60
79-09-4
C3H6O2
8.0
15
109-60-4 C5H10O2
2.5
40
6423-43-4 C3H6N2O6
ZR
75-56-9
C3H6O
7.0
15
75-55-8
C3H7N
1.3
80
110-86-1 C5H5N
0.8
133
504-29-0 C5H6N2
0.8
125
7803-62-5 SiH4
ZR
C2H2O2FNa
62-74-8
ZR
100-42-5 C8H8
0.4
230
7446-09-5 SO2
ZR
2551-62-4 SF6
ZR
7783-60-0 SF4
ZR
7664-93-9 H2SO4
ZR
2699-79-8 SO2F2
ZR
C18H14
0.6
167
586-62-9 C10H16
0.5
210
75-65-0
C4H10O
2.6
40
79-27-6
C2H2Br4
2.0
50
13463-39-3 NiC4O4
1.0
100
76-12-0
C2Cl4F2
ZR
354-14-3
C2HCl4F
ZR
76-11-9
C2Cl4F2
ZR
354-11-0
C2HCl4F
ZR
630-20-6
79-34-5
127-18-4
20020-02-4
C2H2Cl4
C2H2Cl4
C2Cl4
C10H4Cl4
ZR
ZR
0.7
1.0
78-10-4
78-00-2
C8H20O4Si
2.0
ZR
C8H20Pb
20
Typical MDL
Typical MDL
Low Range (ppb)
High Range (ppb)
5
6
2
4
3
90
120
45
80
60
10
5
2
2
5
3
7
25
200
90
30
30
90
67
130
480
50
7
8
40
13
1000
140
169
800
250
35
7
4
4
700
130
75
80
2
50
3
2
15
10
5
60
50
260
200
100
140
100
4
5
70
100
50
10
200
IGD
OLIVER
Gas/ VOC
Tetrafluoroethane, 1,1,1,2Tetrafluoroethane, 1,1,2,2-
Tetrafluoroethylene
Tetrafluoromethane
Tetrahydrofuran
Tetramethyl orthosilicate
Tetramethyl succinonitrile
Therminol
Thionyl chloride
Toluene
Toluene-2,4-diisocyanate
Toluenesulphonyl
chloride, pToluidine, oTributyl phosphate
Tributylamine
Trichloro-1,1difluoroethane, 1,2,2Trichloro-1,2difluoroethane, 1,1,2Trichloro-2,2difluoroethane, 1,1,1Trichloro-2-fluoroethane, 1,1,2-
Trichlorobenzene 1,2,4Trichloroethane, 1,1,1Trichloroethane, 1,1,2Trichloroethylene
Trichlorofluoromethane
Trichloronitromethane
Trichlorophenoxyacetic
acid, 2,4,5Trichloropropane 1,2,3Trichlorotrifluoroethane, 1,1,1Trichlorotrifluoroethane, 1,1,2-
Triethylamine
Trifluoroethane, 1,1,1Trifluoroethane, 1,1,2Trifluoroethanol, 2,2,2Trifluoromethane
Trimethylamine
Trimethylbenzene mixtures
Trimethylbenzene, 1,3,5Trinitrotoluene 2,4,6Turpentine
TVOC
Undecane, nVinyl acetate
Vinyl bromide
Vinyl chloride
Vinyl-2-pyrrolidinone, 1Xylene mixed isomers
CAS No.
Formula
Relative
Relative
response sensitivity (%)
811-97-2 C2H2F4
ZR
359-35-3 C2H2F4
ZR
116-14-3 C2F4
1.0
100
75-73-0
CF4
ZR
109-99-9 C4H8O
1.6
65
681-84-5 C4H12O4Si
ZR
3333-52-6 C8H12N2
1.0
100
1.0
100
7719-09-7 SOCl2
ZR
108-88-3 C7H8
0.5
200
584-84-9 C9H6N2O2
1.6
60
98-59-9
C7H7SO2
3.0
33
Cl
95-53-4
C7H9N
0.5
200
126-73-8 C12H27O4P
5.0
20
102-82-9 C12H27N
1.0
100
354-21-2 C2HCl3F2
ZR
354-15-4
C2HCl3F2
ZR
354-12-1
C2HCl3F2
ZR
359-28-4
120-82-1
71-55-6
79-00-5
79-01-6
75-69-4
76-06-2
93-76-5
C2H2Cl3F
C6H3Cl3
C2H3Cl3
C2H3Cl3
C2HCl3
CCl3F
CCl3NO2
C8H5O3Cl
3
96-18-4
C3H5Cl3
354-58-5 C2Cl3F3
76-13-1
C2Cl3F3
121-44-8 C6H15N
420-46-2 C2H3F3
430-66-0 C2H3F3
75-89-8
C2H3F3O
75-46-7
CHF3
53-50-3
C3H9N
C9H12
108-67-8 C9H12
118-96-7 C7H5N3O6
8006-64-2 C10H16
ZR
0.6
ZR
ZR
0.7
ZR
ZR
1.0
1120-21-4 C11H24
108-05-2 C4H6O2
593-60-2 C2H3Br
75-01-4
C2H3Cl
88-12-0
C6H9NO
1330-20-7 C8H10
ZR
ZR
ZR
0.9
ZR
ZR
ZR
ZR
0.5
0.3
0.3
ZR
0.6
1.0
0.9
1.1
1.0
2.1
0.9
0.4
21
Typical MDL
Typical MDL
Low Range (ppb)
High Range (ppb)
5
100
8
150
5
5
100
100
3
8
15
50
160
300
3
25
5
50
500
100
180
3
50
150
3
65
100
5
100
110
5
90
200
300
300
3
2
2
50
35
35
167
100
110
90
100
50
110
230
3
5
5
6
5
10
5
2
60
100
100
110
100
200
90
40
OLIVER
Gas/ VOC
Xylene, mXylene, oXylene, pXylidine, all
CAS No.
108-38-3
95-47-6
106-42-3
1300-73-8
Formula
C8H10
C8H10
C8H10
C8H11N
22
IGD
Relative
Relative
response sensitivity (%)
0.4
230
0.6
167
0.6
180
0.7
140
Typical MDL
Typical MDL
Low Range (ppb)
High Range (ppb)
2
3
3
4
50
60
50
70
OLIVER
IGD
Maintenence
The electronics in the PID detector element and Tocsin 102PID are not accessible, being designed to
be maintenance-free. Periodic sensor maintenance is required for the electrode stack
and lamp.
When does my PID require maintenance?
Your PID lamp will need cleaning from time to time. How
often? This depends on the environment you are measuring. If
you are measuring indoor air quality with the low range, where
the VOC concentrations are low and there are few particulates,
then a monthly or even less frequent calibration may be
adequate. However, if you are measuring high VOC
concentrations with the highrange and particulates are present in
high concentrations, then check calibration frequently and when
the PID has lost sensitivity, change the stack as explained
below.
You can tell when the PID needs cleaning:
• If the baseline is climbing after you zero the PID, then the electrode stack needs
replacing.
• If the PID becomes sensitive to humidity, then the electrode stack needs
replacing.
• If the baseline is unstable or shifts when you move the PID, then the electrode
stack needs replacing.
• If sensitivity has dropped too much (note the change required when checking
calibration), then the lamp needs cleaning.
When do I clean the PID lamp?
Cleaning of the PID lamp is recommended as a first action when presented with a PID
that needs cleaning. Use the procedure described below. It is recommended that a cell
be recalibrated after cleaning a lamp, especially if the cell has been used for a few
months since the sensor was last used.
When do I replace the PID electrode stack?
The PID electrode stack can last the lifetime of the PID if used in clean environments, or
may only last a month if used in heavily contaminated sites. The electrode stack is a
disposable item, so always hold a spare electrode stack if you are working in a dirty
environment. If the cell shows signs of contamination after the lamp window has been
cleaned, or is known to have been subjected to severe contamination, then it should be
replaced. Instructions for replacing the electrode stack are below. It is recommended
that the PID be recalibrated after replacing the electrode stack.
23
OLIVER
IGD
When do I replace the PID lamp?
A PID lamp will last a long time, typically a few thousand hours. Lamps are warranted
for six months; replacement bulbs are available and are not expensive to replace. The
sensitivity of the PID is approximately in direct proportion to the lamp light intensity, so
as the bulb ages and loses intensity; the response to a particular, low gas concentration
becomes noisier. Note the PC configurator software allows for lamp duty cycles to extend
lamp life, this software can also be used for calibration and diagnostics
Removing the electrode stack and lamp (with unit powered down)
Always use the Electrode Stack Removal Tool; any other tools may damage
your PID and invalidate your warranty
a. Gently remove the sensor from equipment.
b. Place the PID, pellet side down, onto a clean surface.
c. Locate electrode stack removal tool into the two slots on the sides of the PID
and squeeze together until electrode stack and lamp are released.
d. Lift carefully the PID body away from the pellet and lamp.
e. Occasionally the lamp may be temporarily lodged in the cell and will need to
be freed carefully with tweezers.
f. Occasionally the small spring behind the lamp will come out when the lamp is
removed from the sensor. Simply replace it into the sensor house.
Cleaning the PID Lamp
Inspection of the lamp may reveal a layer of contamination on the
detection window that presents itself as a 'blue hue.' To check for
contamination, hold the lamp in front of a light source and look
across the window surface
Only clean the lamp using our recommended lamp cleaning kit
and detailed instructions. To avoid contaminating the sensor and
affecting accuracy, do not touch the lamp window with bare fingers.
You may touch the body of the lamp with clean fingers.
PID lamp cleaning kit PID-CK
The vial of cleaning compound contains alumina (CAS Number 1344-28-1) as a very fine
powder. A full material safety data sheet MSDS is available on request
Key safety issues are identified below:
Hazard identification:
May cause irritation of respiratory tract and eyes.
Storage:
•
Keep container closed to prevent water adsorption and contamination.
Handling:
•
•
•
•
Do not breathe in the powder. Avoid contact with skin, eyes and clothing
Wear suitable protective clothing
Follow industrial hygiene practices: Wash face and hands thoroughly with soap
and water after use and before eating, drinking, smoking or applying cosmetics.
The powder carries a TVL(TWA) limit of 10 mg/m 3
24
OLIVER
IGD
Use of PID lamp cleaning kit 5981601
1. Open the container of alumina polishing compound.
With a clean cotton bud, collect a small amount of the
powder.
2. Use this cotton bud to polish the PID lamp window. Use
a circular action, applying light pressure to clean the
lamp window. Do not touch the lamp window with
fingers.
3. Continue polishing until an audible “squeaking” is made
by the cotton bud moving over the window surface.
(usually within 15 seconds)
4. Remove the residual powder from the lamp window with a clean cotton bud. Care
must be taken not to touch the tips of cotton buds that are to be used to clean the
lamps as this may contaminate them with finger oil.
5. Ensure the lamp is completely dry and any visible signs of contamination are
removed before refitting.
Discarding the PID electrode stack
Discard the contaminated electrode stack. The electrode stack does not have any toxic
components, but if it has been contaminated by toxic materials, then show due care
when disposing.
Re-fitting the PID electrode stack and lamp
Warning! Never refit a damaged lamp
1.
2.
3.
4.
Place the lamp inside the O-ring seal in the pellet as
illustrated. Twisting the lamp slightly during insertion will
help to ensure the lamp window is snug against the
pellet’s front electrode. The lamp should be freely
supported by the O-ring.
Continuing to hold the pellet between forefinger and
thumb, carefully insert the lamp into recess in the sensor
ensuring that the lamp remains in position. Press the
pellet firmly, to ensure that the pellet wing clips are
engaged, and the top faces of the pellet and sensor house are flush.
Refit the sensor into the sensing equipment.
Re-calibrate the gas detector in accordance with manufacturer’s instructions.
Ordering spare components
If you need spare components, then quote the order code below:
10.6eV lamp
5921401
Electrode stack
5921901
Electrode stack removal tool 5981801
Lamp cleaning kit
5981601
Lamp spring
5981701
25
IGD
OLIVER
Accessories and Complementary Products
145.0
126.0
COVERSECURINGSCREW
M20x1.5
128.5
25.0
EEXd Junction Boxes Ref 5045802
40.0
Tocsin 903 Single Channel EEXd Controller with Display.
Refer to seperate data sheet for full option list and part
numbers.
128.0
Ø7.0
Basic unit with 4-20mA Output
Options for:
Relay Alarm Outputs
Addressable Interface
HART Interface
Ø110
EXTERNALEARTH
40.0
GASDETECTOR
Pitot Duct Adaptor P/N5139002
Dynamic Duct Adaptor P/N5999201
Type 4 Duct Adaptor P/N5133701
Type 3 Duct Adaptor P/N5133801
Splash/Dust Guard P/N401451
Calibration Gas Adaptor P/N401101
26