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Certification Training APPLYING PESTICIDES CORRECTLY INTRODUCTION This booklet was prepared for Forest Service employees In the Southern Region to provide information on pests and their management for persons wanting to become certified pesticide applicators. This booklet will help toward that goal. The se3 f-study guide, “Safety Training for Forestry Herbicide Applicators,11 should be studied before starting this training; for a knowledge of the material in the applicator’s handbook is required as a foundation for understanding the data in this booklet. This is a self-study guide, that is, a true/false and multiple choice test follows each lesson. Answers to the test questions are provided immediately following each test. By taking the test after reading each lesson and then checking the answer, you will be reinforcing your knowledge These tests will not be graded. Their purpose is to of the text material. help you learn, therefore, there are not trick questions. You should, however, read each question carefully and select an answer with the same care to find the best answer. At the beginning of each lesson Is a list of terms you need to understand. The definitions of these terms are not provided there, but must be found in the glossary. This is another way to help you learn. If you write in your definition in pencil, then check the glossary and make any necessary corrections, you will be strengthening you understanding of these important words. Without a thorough understanding of these terms, you cannot fully canprehend the material In the rest of the lesson. Be sure you have mastered each lesson before you go on to the next one. you are doubtful about any points, go back and re-read the parts In question. Underline or make notes in the margins to help you find important facts. This Is your workbook. Use it to your advantage to become a more knowledgeable, safer, and a more efficient user of pesticides. If This guide, along with classroom instruction will give you the factual material you need to knaw to use pesticides correctly and to earn your certifjcation as a restricted-use pesticide applicator. Remember that you must exercise good judgement as well as possess factual Information to work with pesticides safely and effectively. - Remember, too, that you are a public servant, using your abilities to foster good forest management for the benefit of all citizens. Courtesy toward all members of the public, and a sincere effort toward understanding No matter their needs and wishes are as important aa technjcal competence. to the public you JUX the Forest Service. As you what your position, continue to study, you will be continuing a proud tradition of service to your cormnunity and to your Nation. ii . I Cerntification Training APPLYING PESTIClDES CORRECTLY CONTENTS PACE rt*c?fx!e . . . . . L(!:::.mrl 1 : Inl.~*oduc:I. ion Lesson 2: Toxicology I.t:s:;on 3: The Pestitr?de . . . Lo Pe::I,icide:: - Parks Label Votm~lations Lo:::;on Service 5: Pesticide Policy . Law::, . . Lesson 6 : u:t i tie PestA ad 7: Pe::tlci.de Ci11 J l)r*nl~.l on . Lt!:i:KJrl 8: Lctr.:;or, 9: Pl.ant . , l . . . . . . . l-1 . . . . . . 2-3. . . . . . . 3-.1 . . . 4-L and Forest . . . . . 5--l 5-l and Adjuvants Safe1 . . . . . . . Equipment . . . . . . . . y . (V3iqpn, c: AgenLs . . . . . . . . . . . . . . . . . . 10: Weeds - ‘lhc::; L~:::::cIII 11 : Vt~hebr~al O:.:;ilt’y . . a. l?cs::t :i . Snail:; .......... ................ iii i . . Pe::tti Lt~::orj Cl . A11p3icatJon . . . . Disea: . Regulations, . . . . cj des .[nver*tetwatc: . l-6 Lt : :mn 4 : Pestivlde Lc:won . and Slugs) . A. Peatioidss are ohmical subst5noes or biologioal organisrs used to oontml They are useful and neoe55ary tcols to uintain tba staadwd8 of pests. quality we have 0008 to exprot within our sooiety. They help the furor to produoe abundant, high quality produota, help to control diwases that have a direot influenoe on our health, and help protwt our home8, lawns, and Forest owner5 and sr5 ust oope with mny insoots and gardens. dibea858, wemls and other plant5 that oompate with desirable trees for food, water, and runlight. Those pwts are an ever-present problem from a tree’5 seedling stage through maturity. Yet pestloidea are not without disadvantages. They are expmaiveI and must be usad with aare to a85ure the safety of the u8w md the l aviroamnt. Poatloides lnolude: -- ohmiolls used to kU1 -- oh5aloa25 used to -- ohemioalr B. p55tr attraot uaod to rq@ato (iwludlng or repel plant pl&,s) pests, growth, md or to remove the leaver. rglllLS How well do you know 8ome of the term5 that are Important in the u5e of pestioides? Test your knowledge of them by writing down the definitions To oheok your an8uer8, refer to the glo88wy. for the term below. 1. Pestioid5 2. Inorganio 3. Organio 4. Systemic l-l 5. Phytotoxlcity 6. Adsorption c. - iQ&&&-s&&L~: speeds-up or otherwise plant growth. Here are some of the things you should know in order to choose the right pesticide and use it most effectively. Pesticides are chemicals used to destroy, prevent, repel, or control Seventeen of them are listed pests. They are used for the pests below. indicated. &asecti&&: . . icide: D_efoliant: Removes unwanted plant leaves without killing the whole plant immediately. as &&&@I&: Dries up plant stems, and insects, &&&r&i&: m: &&g&&&&: &i&&z &&&&: B: and snails. Nematodes. Repellent: Attrw: Pesticides Fungi. These are made from minerals. Minerals of past use are arsenic, oopper, boron, lead, mercury* sulfur, tin and zinc. Examples: lead arsenate, Bordeaux and Paris green. mixture, Bacteria. Plant. Rodents. Birds. Fish. Mollusks, such as slugs Synthetic B: weasels, and Pesticides can be grouped according to their chemical nature and how they work. Four groups of pesticides are reviewed in the following sections. Mites. Inorganic J&&&ig: leaves TEE NATURE OF PESTICIDES Insects &aricj&: Mites, ticks and spiders. m: stops, changes normal Vertebrate foxes, etc. Keeps pests Lures pests, Organic Pestioides such as These are often referred to as man-made pesticides. They contain carbon, and one or more other hydrogen, elements such as chlorine, phosphorus, Examples: 2,4-D, and nitrogen. atrazine, captan, parathion, and malathion. away. pest. l-3 . L m: Plan’zDerivad Pestiaides Kill pests by contact, a-: Substance circulated in an animal’s blood system or tranalocated within a plant. This category of chemicals is extracted or derived from plants or plant parts. Examples: rotenone, red squill, pyrethrins, strychnine and nicotine. Translocated herbicideg: Kill plants when absorbed by leaves, stems, or roots; they move throughout the plant. J&@&l&: are inhaled the pest. Gases that kill when they or otherwise absorhed by qotico8&g&&a : Prevent clotting of blood. normal &Q&Jy3: More toxic to some kinds plants or animals than to others. Nonseleative: animals. These include bacteria, fungi, animals and birds. None of these are manufactured . They are organisms that can be manipulated. n: their Toxic Affect to most plants pests of or by changing behavior. Stomach toxiu: swallowed. Kills when eaten or USING PESTICIDES Pesticide labels contain many terms that describe when and how to use the pesticide. You should know and understand these terms. They will help you get the best results from your pesticide without harming you or the environment . Terms that tell you when to use the pesticide product -- HOWPESTICIDES WORK Preemergence: Pesticides can also be grouped according to what they do. Read the label to find out what each pesticide will do. The major groups are -- Make pests unable crops or Preplant: Used before the crop is planted. Protectanta: Applied to plants, animals , structures, and products to prevent entry or damage by a pest. E!!?i& S$3LiJ&&&: produce offspring. Used before weeds emerge. to 1-3 Postemergence: Used after weeds have emerged. the crop or Dormant spray: ULIC~ while host is dcwnmr t . the: plant, Fol lar : plants. strip Band : Applied to a restricted over or along a crop row or on or around a structure. Basal : or just Applied to stems or trunks above, the ground. Broadoast: the entire Uniform applioation treated area. Craok and crevice: Applied in structures to cracks and crevices pest may live. - .- _. - I);rr’ctd Terms that tell you how to use the pesticide product -- Applied to the leaves In-furrow: Applied to, furrow in whfch a plant at, of or in, the is growing. Over-the-topi‘ Applied from above the growing crop (compare to sidedress and others). over Soil Applloation: Applied rather than to plants. where to the soil d Dip : Complete or partial immersion of a plant, animal, or object in diluted pesticide. Applied to a small spot: over an individual plant. area, such as at a Directed : Aiming the pesticide specific plant or a portion of a plant, animal, or structure. Soil lnoorporation: Use of tillage implements to mix the pesticide with the soil. Soil soil injection: surf ace. Applied beneath the The rate and time of application of pesticides are critical. Pesticides work best when applied at specific Using them before or after the times. Band l-4 also slow down or stop the activity some pesticides. Check the label. correct time reduces or even eliminates their effectiveness. Correot timing may help reduce damage to nontarget species. Light also affects the activity of some Some effects on the target pesticides. species may be sooner during sunlight, others sunlight may begin to break down the pesticide from exposed surfaces, reduoing activity, Because all these chemicals work in small amounts, be careful to treat only the intended target, and at the Avoid getting them on prescribed rate. anything else as a result of drift or of residue in application equipment or the soil. The ability of a pest to resist poIsionj.ng 1=acalled pesticide Consider this factor when resistance. planning pest control pr*ograms. Rarely does any pesticide kill all the target Each time a pesticide is used, pests. it selectively kills the most sensitive some avoid the pesticide, individuals; its others are able to withstand effects. Pests that are not destroyed pass along to their offspring the trait that allowed them to survive. FACTORS AFFECTING PESTICIDE ACTIVITY Soil. of M Organic matter in soils may limit some Soils with a high pesticide aotivity. organic matter content may need higher The soil rates for good control. texture may also affect the way Soils with fine pesticides work. particles (silts and clays) provide the They may need moat surface area. higher rates especially for the Coarser soils soil-applied pesticide. (sands) have less surface area. Use lower rates on them. Follow the label instructions. When we use one pesticide repeatedly in the same place, the insects there sometimes build up their resistance. Some pests have become practically immune to certain insecticides; however, most pesticide failure is not Make sure caused by pest resistance. you have: Soil moisture and rain affect the way some pesticides work, especially those applied to the soils (soil active). They also affect how long pesticides Most stay on the soil and plants. pesticides work best with moderate soil moisture. Excess rain oan oause some soluble pesticides to leaoh more through the soil. Moderate rain is good when pre-emergence pesticides are applied to the surface. They are the carried into the soil to the pests. However rain during or soon after over-the-top or foliar applications may wash pestloides off the leaves. -used the correct pesticide -used the correct dosage, and -applied the pesticide correctly. PLANT GROWTHREGULATORS, DESICCANTS, DEFOLIANTS, AND ANTITRANSPIRANTS Plant growth regulators, desiccants, defoliants, and antitranapiranta change normal plant processes. Work Humidity and temperature also affect Moat the way pesticides work. herbicides work best when plants are High relative humidity growing fast. and optimum temperatures usually contribute to this fast growth. High temperatures may reduce the activity of some pesticides. Low temperatures may Plant Growth Regulators All plant parts are made up of tiny cells that continually Plant growth multiply and grow. regulators speed up, slow down, or l-5 . otherwise affectkcell reproduction. growth Deslocants and and Defoliants Both materials are used to get rid of stems, and weeds. They are leaves, used on a limited basis to pretreat areas that are to be burned. l-h . SELF TEST AND ANSWERS L-7 1. Pesticides regulations, -- _I ---__ 2. If a. b. c. d. e. are chemicals used to control pests. which of the following are classed Chemicals used to Chemicals used to Chemicals used to Chemicals used to All of the above you wanted use a: Because of government as pesticides: attract or repel pests. regulate plant growth. remove plant leaves. coat plant leaves. to speed up or slow down the growth of seedlings you would -- . ..-. a. Plant growth regulator .___ b. Desiccant or defoliant __-- c. Both of these 3. Match the following: ___ ___ - a. b. c. d. Avicide Nematicide Pisoicide Predacide 4. A pesticide - ___ --- most likely to be used to kill crawling insects would be: a. A contact pesticide b. A stomach poison c. None of the above 5. A translocated -- 1. Controls nematodes. 2. Controls predators or other pest animals. 3. Controls fish. 4. Controls birds. herbicide: a. Stays in one part of the plant b. Moves throughout the plant c. None of the above 6. Match these: __ a. Attractant ---- b. Repel lant _.- c. Defoliant d. Plant growth 7. The activity -b. -_ __ regulator of a pesticide a. Moisture, humidity Texture of soil c. Temperature d. All of the above may be affected 1. Used to remove leaves from stems. 2. Changes the rate of plant growth. 3. Keeps pests away. 4. Lures pests. by: . 8. Match these: -_ ___ ----____ a. b. c. d. 8. 1. Makes pest unable to produce offspring. 2. Is absorbed on plant leaves and travels to other parts. 3. Gasses that kill. 4. Must be eaten to kill. 5. Kills when pest touohes it. Contact pesticide Stomach toxicant Translocated herbicides Fumigants Storilants 9. Match the following: -._^ -_ ____ ___ -- a. b. 0. d. e. f. Band Directed In-furrow Foliar Basal Spot treatment 1. Applied to the leaves of plants. 2. Applied in the furrow in which a plant is growing. 3. Applied to a stem of a plant at or around the ground line. 4. Applied to a small area. 5. Applied in a strip. 6. Aimed at part of plant or animal. 10. Match the following: 1. Use after orops and weeds have emerged. 2. Uee before crops or weeds have emerged. 3. Use before crop has been planted. a. Preplant ---- b. Pre-emergenoe -_- __ 0. Post-emergenae -- .-- 11. Injury to plants as a’result of a pesticide application is called: a. Morphosis __ b. Phytotoxicity c. Spondylitis --- ------ d. Photolysis --- 12. Soils with especially __ --- fine particles, when soil-active such as silts and olays, pesticides are used. may need ___- rates, a. lower b. higher c. same 13. Match the following: a. Adsorption _-_.-_ b. Absorption --. _.. c. organic --- 1. Chemicals held on the surface of soil particle. 2. Contains carbon. 3. Chemical taken into plants or animals. .L-9 . 1. e 7. d 11, b 2. 8 88, 5 12. b b. 3a. 4 b. 1 C* 3 2 d. 4. a 4 dc: : 8. 1 g:* 65 c: 2 d. 1 8. f. 3 4 5. b da. 4 10a. 3 b. 2 C* b* : 2 0. 1 d. l-20 13a. 1 b. 3 c. 2 . pee?' 1: LESSON 3 -0LOGY I-ON TO TOXICOLOGl A. JJTRODUCTIO~ Toxicology is the science that studies the harmful effects of chemicals. It is a young science compared to its parent discipline pharmacology, the science that studies &Q effects of chemicals , with particular emphasis on medicinal effects. B. TERMSYOU W TO UNDERSTAND How well do you know some of the terms that are important in the understanding and use of pesticides? Test your knowledge of them by writing down the definitions for the terms below. To check your answers, refer to the glossary. 1. Toxicology 2. Natural 3. Synthetic 4. Biochemical 5. Foreign Chemical 6. Sensitization Chemical Chemical 2-1 C. Under our laws, chemicals are categorized by use, not their toxicity. Chemicals associated with foods are regulated by food Laws, chemical.s used as drugs by drug laws, ,chemicals used 33 cosmetics by cosmetic laws, etc. For example, boric acid is regulated as a drug when used a3 an antiseptic eye wash, as a household product when used in laundry detergents, as an insecticide when used to kill roaches, as a herbicide when used to kill weeds, and as a flame rttardant when uved to fireproof fabrics. The toxicity of a chemical is totally independent of the category in which it is placed. DISCUSSIO& CHEMICALS- EVERYTHING Everything in our world is chemical. All matte; (everything) is composed of elements. An element may be representative of a single atom or of many of the same kind of atoms. About 90 kinds of stable elements are found in nature, and only about 15 other mostly unstable ones exist. The natural elements are the basic building blbcks for substances we come Jn contact with during everyday life. NATURALAND SYNTHETIC CHEMICALS Most of these ahemioals evoke a positive feeling about their use because they enhance, soothe, clean or All chemicals fall into two major categories: natural (made by natural processes) and synthetic (made by man). Many chemicals fall into both groups -- they are found in nature and they can be made (synthesized) in the However, some laboratory or factory. chemicals have not been made in the laboratory. A130 some synthetic chemicals are not found in nature. serve another nondestruotive purpose. In contrast, chemicals used as pesticides are more likely to be feared by the public. Fear probably arises because these chemicals are used to kjll their target (insects, rodents, weeds, etc.). Moreover, the news media give a tremendous amount of attention to the use and misuse of pesticides. Some people mistakenly believe that all pestici.Zes are very highly toxic chemicals. The fact is that many pesticides are no more toxic than some other chemicals that we use every day. A number of chemicals that are used as pesticides are also used for other purposes, such as drugs or Industrial chemicals. Boric acid is an example, as mentioned earlier. Chemicals that come from plants or animals are called biochemicals. They may also be produced in the lab or factory, and are then called synthetic, A chemical that is bjochembl benefiting one group of organisms may be foreign, not benefiting or deadly, to another group. For example, strychnine is a benefioial chemical in certain plants and a foreign and deadly chemical for Some people think that animals. natural chemicals are Itgood" and However, man-made chemicals are "bad". p3ants and animals are not hairned, or helped, on the basis of the chemical's origin -- nature or the laboratory. The laws and principle3 of toxicology and pharmacology apply equally to all chemical. 3 -- whether they are natural or synthetic, biochemical or foreign. ADVERSEEFFECTSOF CHEMICALS Chemicals may harm us in a number of djfferent ways. Some may explode, ignite, destroy tissue (if they are corrosive), or they may injure tissue because of their irritant properties. Some chemicals cause sensitization (allergic) reactions. Other chemicals muy have harmful toxic properties. Some chemicals possess only one harmful praoperty, and others two or more. USAGEOF CHEMICALS-THE BASIS OF REGULATION 2-2 HAZARDS AND TOXICITY The toxicity of a chemical refers to its ability to do systemic damage -this kind of damage takes place somewhere else in the body or a plant For other than the point of contact. example, when some chemicals are absorbed through the lungs, damage to If the the kidneys will result. chemical is eaten, damage to the liver The toxicity of chemicals may result. is the subject of this part of the study guide. The word “hazard” is commonly misused A hazard is much to mean ntoxicltyll. more complex -- it refers to the chance that a chemical will be harmful. A hazard is made up of two components: 1) the basjo ability of a chcsmlcal to do harm, and 21 the ease with which it may come in contact with the object of concern (e.g., people, trees, wildlife). 2-3 A. JNTRODUCTIOI!J All effects of chemicals, whether they be beneficial, neutral, or harmful, depend on a number of conditions. For example, how much chemical one is exposed to, how often the exposure oocurs, how the chemical gets into the the kind (species) of animal or plant body (by mouth, skin, lungs, etc.), that is exposed. its age. sex* state of health and nutrition, and whether or not other chemicals are present that might alter the effect. B. TERMS YOU NEED TO Um How well do you know some of the terms that are important in the understanding and use of pesticides? Test your knowledge of them by writing down the definitions for the terms below. To check your answers* refer to the glossary. 1. Dose-Time Relationship 2. Acute Toxioity 3. Chronio 4. Antagonism 5. Adaptation ToxiolQ 2-5 t c* HOWMUCH - HOWOFTEN This combination of “how much” and “how oftentt is known as the dose-time relationship. The dose is the quantity of a chemical that a living creature gets at one exposure. Time refers to how often the exposure oocurs. The amount of chemical (dose) may be very large, such as when a chemiaal accidentally spills during transportation or during a work accident. The amount of ohemioal (dose) could also be very small, suoh as exposures to traoe amount of pesticide residues that may be in foods. Sometimes the exposure is only once s such as an accident. The exposure could also be repeated over and over again for long periods of time, as in residues In foods. There are many combinations of “how much” and “how often.” A person may be exposed only once to a fairly large amount of pesticide, at one extreme. Another person may have a lifetime exposure to very tiny amounts, at the other extreme. No one can study every possible combination of dose and time, so toxicologists study the effeots that occur at the two extremes. Then they judge what might happen with all the intermediate combinations of dose and time. Of all of the factors that influence toxicity, the &se-time relation&& has the greatest bear&g on whether or not a chemical will be harmful. the opposite -- acutely nontoxic and chronically toxic. However, most chemicals have some degree of both acute and chronic toxicities. Regardless of which group a chemical fits, it is extremely important to remember the exposure conditions. Every chemical is harmless under some exposure conditions. Conversely, under some oonditions the chemical is harmful. Later lessons will help to explain these conditions. ROUTE OF EXPOSURE The route of exposure refers to the plaoe through which a chemical enters the body. After the dose-time relationship, the route of exposure 3s l&,e most.ant facu :In determinf.ng whether or not a chemical will be harmful. Chemicals enter the body via three major places: mouth (oral), lungs (inhalation), and skin (dermal 1. Chemical:: can also be injected in the skin or jnto a vein. These routes are only used by physicians or in cases of drug abu::e. They are not usual pathways of exposure for the average person. Thus, they will not be considewd here. The toxic-lty of a chemical can vary greatly, depending upon Its pathway of entry into the body. Chemicals are absorbed to different degrees at the different routes; if a chemical can’t get into the body, it can’t do any harm! ure bv Moyth We may consume chemicals with our food or drink. This is called the oral (or ingestion) route. People who work with chemicals may mistakenly believe that Ingestion is not important -- they do not eat Lhe chemicals! However when people do not wash their hands after handling a chemical and before smoking or eating lunch, the chances are good that they will ingest some of the chemical. Because of the influence of “how much” and “how oftena, we must distinquish between acute and chronic toxicity. Acute toxicity refers to the effeots from a one-time exposure. Chronla toxicity refers to the effeats from long-term exposure. Acute toxiolty and chronic toxicity are the subjects of later parts in this study guide. As we will see, some chemicals may be acutely toxic and chronically nontoxic. And some chemioals are just 2-6 Ingested chemicals are absorbed primarily through the intestines. intestines are designed to absorb and sometimes cannot distinguish between foods and nonfoods. Only lungs permit greater absorption of chemicals than the intestines. skin more easily than solids, and oily liquids or oil-soluble liquids penetrate the akin more easily than watery ones. The foods the some MOVEMENTFROM POINT OF EXPOSURE The previous section presented the routes of exposure that affect Toxicity also depends on the toxicity. pathway a chemical takes after it enters the body. Most chemicals that reach the intestines are carried on to the liver before going to the rest of In contrast, chemicals that the body. enter through the lungs or the skin go directly to all parts of the body before eventually going to the liver. Some chemicals may get into our bodies through the lungs. We breathe in the chemical if it is mixed in the air around us. This is called the As a general rule, inhalation route. chemi.cals are absorbed to the greatest degree through the lungs. We are most likely to inhale volatile chemicals, -those which vaporize readily, or chemicals that create fine dust particles because they must be in the aill to be breathed into the lungs. The liver is the great processing plant of the body. It chemically changes If the many chemicals that enter it. chemical change converts the chemical into one that is less toxic, passage through the liver protects the body. In this case the chemical would be less toxic by the oral route than by the dermal or inhalation routes. (We can assume that the degree of absorption is the same for all three routes.) If the chemical changes in the liver to a more toxic form passage through the liver would be harmful. In this case, the oral toxicity would be greater than the dermal or inhalation toxicities. Lung surfaces are very# very thin membranes that offer a poor barrier against the entry of chemicals into the These membranes allow for easy body. passage of oxygen into the body. They also serve as an exit for carbon dioxide from the body. These membranes permit easy passage of most gases and You should be aware of one vapors. except ion -- pesticides of low volatility. Because of this low volatility most forestry used pesticides or the low amount of fine particles in the dry formulations, and the way our pesticides are applied. dertnal exposure is a greater risk than inhalation. In summary, the toxicity of chemicals can vary with the route of exposure: acute oral, acute inhalation, acute dermal, chronic oral, chronic inhalation, or chronic dermal Every chemical has six kinds toxicity. of toxicity1 Some chemicals can bc absorbed through the skin. This pathway is called the dermal route. The skin is the best barrier against the entry of chemicals into lhc body. One of the functions of the okin is to keep us from drying out. Because the skin forms a barrier against loss of liquids and solids, it also forms a barrier against cnfrv of If this were not liquids and solids. true when we go swimming we would fill up with water like a sponge. As a general rule, liquids penetrate the SPEC1ES A great deal l.r known about how toxicity varies with the kind of animal exposed. Most of this information All comes from experiments on animals. kinds of animals have been used in toxicity experiments: rats, mice, hamsters, guinea pigs, rabbits, dogs, miniature pigs, cats, chickens, monkeys, etc. The list of chemicals that have different toxicities for 2-7 NUTRITION different species is very long. And the ranking of species for their susceptibility to chemicals varies with chemicals. There is no one species for which all chemicals are most toxi.c, second most toxic, and so-forth down to least toxic. If there were9 chemicals could be tested more easily. Humans would then always fit at the same points in the list. Tests would involve only one animal species that was more susceptible than humans to the toxic effects of.chemicals. Instead, we must study each chemical in different species to obtain data that can be translated to humans. In the translation, we always 899ume that humans are more susceptible than animal 9 -- whiah is not generally true. Research indicates that nutrition plays an important role in whether or not A diet chemicals will be harmful. adequate in proteins and vitamins protects against the harmful effect:: of some chemicals. STATE OF HEALTH As with nutrition, physical and emotional good health appear to protect us, either directly or indirectly, against the harmful effects of However, we need more chemicals. At this research on this subject. time, one’s state of health has little practical application in the field of toxicology. AGE INDIVIDUAL Animal tests and our experience shows us that some chemicals are more toxic to infants than to adults. Conversely, some chemicals are less toxic to infants than to adults. These differences probably result from the way the liver processes ohemioals. Babies have immature livers. A baby’s liver cannot detoxify the chemioal &fiCielltly~ or at all. For example, if the adult liver converts a chemical to a less toxic form, then this chemical would be more toxic to infants, because the immature baby liver cannot make the chemical less toxic. The opposite would be true if the adult liver converted the chemical to a more toxic form. We know little about the effect of age on toxicity of chemicals. Therefore, we always assume that infants and the elderly are more susceptible than most adults to the adverse effects of chemicals. SUSCEPTIBILITY Some studies show that certain inherited traits affect one’s response to chemicals. For example, a person may suffer more adverse effects than do other people from certain chemicals or classes of chemicals. That person’s chemical genetics were responsible. Even among people who are apparently average, individual differences do exist. For this reason, the amounts of chemicals that aould be toxic are given as averages rather than absolute values. CHEMICAL COMBINATIONS Sometimes chemicals in combination are more -- or less -- harmful than either chemical alone. When they are more toxic the effect is called synergism. When they are less toxic the effect is called antagonism. Perhaps the best known synergistic effect is the great increase in the toxicity of some tranquilizers when taken with alcohol. Otherwise, little is known about these effects, ADAPTATION SEX Animal tests show that some chemicals have different toxicities for males and females. Some chemicals are more toxic to males and some are more toxic to females. We know almost nothing about whether this difference occurs in humans. Adaptation involves repeated exposures to smsll amounts of a chemical. A persor becomes tolerant to larger quantities of the chemical over a period of time. Otherwise the chemiaal would be harmful. 2-8 LESSON 2. TOXICOLOGY PART 3 - ACUTE TOXICITY A. LNTRODUCTION Acute toxicity is the ability of a chemical to harm a person, animal, or The harm that is done occurs someplace plant after only one short exposure. This djatant, or else than at the point of contact with the chemical. nearby site of damage distinguishes toxic from corrosive effects of chemicals. Corrosive chemicals will damage structures and tissues that they actually touch. In contrast, toxic chemicals do damage somewhere else in They might damage an organ* such as the liver or kidneys, or they the body. might upset some processes in your body, such as those that produce blood cells. Some chemicals are only corrosive, some art? only toxic, and a few others are both corrosive and toxic. B. TERMS YOU NEED TO UNDERSTAND How well do you know the terms that are important in the understanding use of pesticides? Test your knowledge of them by writing down the definitions for the terms below. To check your answers, refer to the glossary. 1. LD 50 2. LC 50 3. Poison 6. Mil.ligram (m&I 2-9 and 6. Kilogram 7. Meter 8. Liter C. (kg) toxicity. PISC~3axQti fnhaled A great deal is known about the acute toxicity of chemicals because this type of harm is fairly easy to study In the laboratory. We also, unfortunately, know a lot about acute toxicity in humans from accidental exposures and from suicides. ACUTEORAL TOXICITY dose will. kill all fumes oonoentration (LC). The acute LC 50 corresponds to the acute LD 50. Acute dermal a.nd inhalation toxicities of are much more important to you than are oral toxicities. You are more likely to get chemicals on your skin or inhale the vapors or dusts than to be exposed to them in your food or drinks. chem1cal.s The acute oral toxicity of chemicals is found by giving several groups of animals increasing doses of the chemical. Ideally, the smallest dose will kill none of the animals and the largest The amount of chemical is measured as a lethal Acute Dow-Mcmdiq (LD& Curve of the animals. The animals are observed for 14 days, during which time deaths are recorded. At the end of the test, the dose that would kill 50 percent of the animals is calculated. This dose is known as the LD 50. LD means "lethal dose" and the "50" pertains to 50 percent of the animals tested. ACUTEDERMALAND INHALATION TOXICITIES Acute dermal and inhalation toxioities are determined in a manner much like that for acute oral toxicity. However, the chemical doses are applied to the animals' skin or inhaled by them in special chambers. In this manner* the LD 50 13 obtained for acute dermal 2-10 CRITICAL MEASUREMENTS Oral and dermal LD 50 are measured in (mg) of chemical per kilogram (kg) of body weight of an animal (n&/kg). Three ways are used to ttxpres: inhalation LC 50: nlilligr-ams Although a chemical may be legally nontoxic, it could be harmful under some conditions. Treat all chemicals with care. mg-of chemical per; cubic meter (ma) of air (mg/mJ) -- mg of chemical per liter (L) of air (me/L) -- parts of chemical per million parts of air (ypm). -- Remember: we do not know the LD 50 or LC 50 of any chemical for w. These values are based on data from tests on animals. Obviously, such experiments may not be performed on humans. Instead, average lethal doses (ALD) for humans are estimated from data on animals and human experience. The smallest LD 50 obtained by animal tests is multiplied by the weight of the human, in kilograms (kg). A chemical with an oral LD 50 of 10 mg/kg would be calculated to have an oral ALD of 100 mg for a 10 kg (22 pound) child, and 700 mg for a 70 kg (154 pound) adult. Although ALDs are of some value in estimating actual toxicity in humans, our real interest is in what might be an LD 0 (total dose for no people) for humans. We do not want to permit exposures that will kill w humans, much less half of them! Oral LD 50 = 50 mg/kg or less Dermal LD 50 = 200 mg/kl: or less Inhalation LC 50 z 2 mg/L of dust Inhalation LC 50 = 200 ppm of gas or vapor Chemicals in a31 four groups above must carry a npoison11 warning on the label. ------ ._ Toxic Oral LD 50 q 50 to -- Dermal LD 50 = 200 -- Inhalation LC 50 = of dust -- Inhalation LC 50 = of gas or vapor -- 5,000 mg/kg to 2000 mg/kg 2 to 200 mg/L 20,000 of ppm Fortunately, in almost all cases of mild acute poisoning, and even in many cases of severe poisoning, if the person survives the first 24 to 48 hours, recovery is complete and health restored. All LD 50 and LC 50 readings higher than those above. Remember -- the higher the number, the more chemical required to injure or kill the victim. The lower the number, the less chemical required to injure or kill. 2-11 , PART 4.. A. CHRONIC TOa mODU= Chronic toxicity is the ability of a ohemical to harm to a person, plant or animal upon repeated exposure. These exposures take place over long periods -- perhaps even a lifetime. A:; with acute toxioity, the victim is harmed at a place other than the point of oontaot. B, TERMS YOU m TO UNDERS‘QQQ How well do you know some of the terms that are important in the understanding and use of pesticides? Test your knowledge of them by writing down the definitions for the terms below. To oheok your answers* refer to the glossary. 1. No-effect 2. Threshold 3. loo-Fold Level Margin-of-safety. 2-13 c- DISCUSSIQN Very little Is known about the chronio toxiaity of most of the ohemioals we work with, exoept for thoar that somehow get into our foods, Tests on chronic toxicity take a long time and The highest level of ohemlcal animals, exposure is one that will produce slgniflonnt adverse effeots in some or all af the animals. During the feodlng period arld at the end of the experimer t, the animal s are sub jeoted to many examinations and tests. are expensive. NO-EFFECT AND THRESHOLD EXPOSURESTO CHEMICALS FDA TESTING The Food and Drug Administration (FDA) requires testing of chemicals that may These come in oontaot with foods. chemioals must be given extensive tests for chronic oral toxioity. Three main groups of chemicals are involved. First are the additives *- food colorings, preservatives, emulsifiers, The second group consists of the etc. pestioides. The third group Involves chemicals that are not intended to be in oontaot with food, but whioh might For example, the oil get on some food. In maohines used to handle foods might get on some of the food. Suoh oils would be subjeot to testing for ohronic oral toxicity. Beoause of these tests, those of use who use pesticides in our work know more about their safety than do industrial workers who handle chemioals. EPA TESTING The Environmental Proteotion Agenoy (EPA) regulates all industrial and environmental chemloals, inoluding pesticides used in forestry. The chemicals are given several kinds of One type of test is given for tests. chronic toxicity. Other tests are given to see if the chemioal may cause reproduction defects, ohanges in genes, or cause oancer. Chronic toxicity studies require long-term or lifetime exposure of groups of animals to low levels of chemicals. As with acute toxicity tasting, the lowest level of ohemioal exposure is one that will produoe no detectable adverse effect in any of the 2-14 There is no neat expression like the LD 50 for acute toxicity that oan be applied to chronic toxicity. Instead, we use terms such as no-effect level and threshold. The no-Effect level is that exposure level that produces no chronic effeot in any of the test animal 9. The units of the no-effect level usually are part3 of chemical per million parts of food, water, or air (p1m). The threshold is the turning point between no-effect and effeot levels. Thresholds exist because, our bodies oan handle very small ohronio exposures of some potentially harmful chemioals. The body may eliminate the chemicals or aonvert them to a less harmful form before any harm occurs. As the exposure Increases, the body’s ability to handle the chemicals becomes Adverse effects then overwhelmed. begin to appear. Finally, at high enough ooncentration, severe illness or death occurs. The threshold concept shows the potential harm or safety of our exposure to trace amounts of industrial If there or environmental ahemioals. were no threshold3 -- level3 below whioh ohemioals would not be harmful -we could not tell what risks, if any, we faoed when we used a chemical. Despite the importance of the threshold ooncept, thresholds are not absolute values. They vary from species to species, and even among individuals within a species. Even though this is true, we may still use thresholds with a fair degree of confidence. assumed to be IO times more sensiti.ve ,than healthy adults. Thus, if the no-effect level of a pesticide was found to be 100 ppm, the maxinum amount of residue that could result in human food would be 1 ppm. Chronic adverse effects are dose-related; the greater the dose, the greater the effect. The adverse effects of chemicals are not random. They do not cause one set of symptoms in one person and an entirely different set in another. They may cause different sets of symptoms in different species, but within a species, their effects are predictable. MARGIN OF SAFETY Does a chronic toxicity test on an animal have the same results on a human? Rather than take a chance, we provide a loo-fold margin-of-safety. This margin assumes that we are lo-times more sensitive than animals to the chemical in question. For further safety, young, old, and ill people are 2-15 . iiiFsi& PART 5 W.WJS HUTA. Mutagenesis, teratogenea4s , and carcinogenesis are grouped together in this lesson because the latter two are related, at least in Home instances, to the former. Qenesis means “to give rise to”, muta means ttchangell, terato means “monster”, and carcino means “crab (cancer)“. Thus, mutagenesis meany to give rise to changes (mutations) in the genetic material of cells. Teratogeneaia means to give rise to monsters (deformed fetuses). Carcinogeneaia means to give rise to cancer. All three subjects are much too complex to cover in detail here. This lesson gives a brief overview of the relationship between chemicals and the “gensn. B. TERMS YOU NEED TO UNDERSTAND How well do you know some of the terms that are important in the understanding and use of pesticides? Test your knowledge of them by writing down the definitions for the terms below. To check your answers, refer to the glossary. 1. Mut ageneais 2. Mutagen 3. Teratogenesis 4. Teratogen 5. Carcinogenesiv 2-17 6. Carcinogen 7. Benign 8. Malignant tumor tumor c. MUTAGENBSIS All living cells oontain a chemical called DNA. DNA carries a code that contains all of the messages that eaoh cell needs to reproduce Itself exactly. The DNA tells the cell that it is a rat cell, a dog cell, a human cell, a male or female cell, a kidney cell, a liver cell, etc. Mutations are changes in one or more messages in the DNA structure. Physical or chemical agents that give rise to mutations are called mutagens. A mutation may be so minor as to make almost no difference to the cell. The cell still fun&ions and reproduces as it was designed to do. At the other extreme, the mutation may be so severe that the cell dies and disappears. Some mutations are severe enough to change a cell’s identity, but do not kill the cell. Such cells might grow and proliferate as a tumor. In this event a cancer may result. A mutation may occur in a cell in the skin, kidney, liver, etc. Mutations can also occur in reproductive 0911s (eggs or sperm). A mutation in a body cell may cause a tumor, but it cannot be inherited. A mutation in a reproductive cell can be inherited if that cell unites with a counterpart and. 2-18 develops into a new individual. In that ease. the mutation will be inherited by all future progency. Depending upon the severity of the mutation it may not be detected, or a The malformed baby mleht reaul t. malformation may not interfere with the ability of the baby to live, or it may kill it bctfore it is born. Mutations are considered to an essential step leading to cancer. Mutations probably cause a small percent of fetal malformations. Ionizing radiations of natural origin are probably the single most important cause of Flutations. TERATGGENESIS Physical or chemical agents that cause fetal malformations are called teratogens. Teratogens may or may not be mutagens; they can also act in other ways to produce a malformed fetus. We do not know what percent of spontaneous abortions, stillbirths, and fetal abnormalities are due to teratogens. But beaause of the following oonsiderations we assume they are minor problems. Probably one of the major causes of fetal abnormalities is disease of the Other recognized causes are mother. heredity, diet, drug or alcohol abuse. c’ge of the mother, and natural smokinp;, very f3W radiation and x-rays. chemicals are known to be ter3tOgeniC for humans. malignant (cancerous) tumorv3 is not clear enough to judge whether a benign tumor will sometime become cancerous. . Few known human cancer agents exist compared to the large number of -e&a agents. Very conservative criteria are used by regulatory agencies in classing chemicals ac These criteria place agents of cancer. too many chemicals in the list of cancer agents according to many toxicologists. To cause a malformatjon, a teratogen reach the developing embryo during the critical stage of organ development, For the human, this period starts 2 weeks after conoeptioa and lasts about 10 to 12 weeks. The kind of malformation that results depends upon what stage of development the embryo is in when it is exposed. must THAT f@H DUE TO CHEMICALS CARCINOGENESIS Cancer is a much feared and dr?bated subject. There is no dispute about whether chemicals can cause cancers, but experts disagree about how many chemicals may cause cancer in humans. The experts also disagree on the percent of human cancers that are due to exposures to chemicals. Neither do they agree on the mechanism by whiah There is chemicals cause canoer. debate over whether or not there are safe levels of exposure to chemicals that may cause cancer. ER. ICALS, THAT CAN CA!,@UbCANC --- Mutagenesis is considered to be a basis step In the development of a cancer. Some fairly simple tests use single-celled organisms to determine whether a chemical could causfa mutations. Many chemicals have been shown to be mutagenic in these! tests. Regul a.tory agencies consider Khese chemicals to be possible causes of cancer in humans. Studies with animals are required to provide more firm evidence of the cancerous properties of these mutagens. About 15 years ago, a lot of publicity was given to a report that 80 to 90 percent of human cancers were due to environmental chemicals. This erroneous report was the result of a misinterpretation of ideas presented by Dr. John Higginson. His highly regarded thoughts proposed that 80 to 90 percent of cancers are due to environmental llfactorsl’. These factors include smoking habits, use of alcohol, exposure to sunlight, diet, natural radiation, and medical treatment. Dr. Higginson estimates that perhaps 2 to 6 percent of cancers are due to occupational exposures to chemicals. The most notable exposure involves asbestos. HOWDO CHEMICALS CAUSE CANCER? We know too little about how chemicals cause cancer. Chemicals vary greatly in their interactions with living organisms. A few chemicals appear to be able to cause cancer directly. They are called u v. The majority of chemical carcinogens seem to require some sort of chemical change before they can cause cancer. These chemicals are pr9carcinonena. Chemicals that are shown to cmse cancer in animals are consider-ed to be probable causes of human cancer. This rule is appled even if the chemical causes cancer in only one species of animal. Further, regulatory ; gencie:; do not distlnguiah between bet ign tumor3 and cancers that might be cau:.ed by chemicals.. Some scientist: claim that the distinction between tenign :frrd Some chemicals cannot cause cancer themselves, or be converted to cancer agents. However, they are able to increase the cancer-causing ability of other chemicals by some means. These (I . chemicals are called rocara 2-19 The distinction among these three groups of chemicals has only become evident in recent years. Therefore, much of the early data on cancer-causing chemicals does not reveal the group in which a chemical carcinogen, belongs : u pCpcarcinogin, or acarcinogen. GHPI;ICAL? T experimental methods are available prove or disprove absolutely either claim. to Despite the controversy about “safe” levels of exposure to carcinogens, no one argues with the fact that t.here are practical thresholds for carcinogens. The incidence of cancer caused by chemical: is dose-related. For example, the exposure may be so small as to reduce the incidence to one person In a trillion. In that case what practical significance would that exposure have in a world with a population of leso than a trillion? -- “Safe” levels are probably one of the most debated subjects among the experts. Many toxicologists consider that the cancer-causing ability of a chemical Is one aspect of its toxicityc and not some special effect that is separate and apart from its toxicity. Thus, they accept the idea of thresholds for cancerous effects just as there are thresholds for toxic effects. The length of time needed for a cancer to develop after exposure (the ,inductlon period) is also dose-related. For example, the exposure may be so small as to increase the induction period to 200 In that case* what practical years. significance would that period have when our average life span Is less than 100 years? Other scientists maintain that there are no thresholds for cancerous effects of chemicals, and that one molecule of a carcinogen could start a cancer. No 2-20 PART 6 - SOME -ION Many factors govern whether a chemical will produce adverse effects. Because of these factors, the toxicity of chemicals is a complicated subject. As one might expect, a number of wrong ideas have arisen about the toxic actlons of chemicals and the science that studies them. These misconceptions will be discussed briefly in this part of the lesson. YOU hlEFJ) , s How well do you know some of the terms that are important in the understanding and use of pesticides? Test your knowledge of them by writing down the definitions for the terms below. To oheck your answers, refer to the glossary. c. 1. Sufficient 2. BioacouRllation Challenge alcohol with every thirteenth 2-ounce highball or martini. For people with neither of these vices, there are many, SIJFFICUNT CHALLENGE many potentially harmful chemicals that in our foods. In the Some people mistakenly tt!ink that if a occur naturally course of a lifetime, we eat or drjnk chemical causes harm in irny quantity, it will cause harm in evvary quantity. many lethal. doses of many chemicals. The reason why 1his is nr>t so is There is no way we can avoid these exposures. However, they do us no harm explained in lesson 2, Part 2. Refer because we do not receive all these to Part 2 if you have any questions exposures in one dose. about the importance of the dose-time relationship in determinjng whether or Not only do small amounts of most not a chemical will be toxic. chemicals do us no harm, very tiny amounts may actually be beneficial. To illustrate: A lethal dose of The scientist who first wrote about caffeine is present in about 100 cups thiz revolutionary notjon, Dr. Henry of strong coffee. Thus, anyone who Smyth, call.ed the concept l@Sufficient drinks several cups of coffee a day Chal I.enge. I1 Dr. Smyth put into writing will get a lethal dose of caffeine what toxicologists have noted in their every month. A !.ctital dose of alcohol research -- the very smallest doses of is preuent in a fifth of hard liquor. forei.gn chemicals fed to animals often Thus, anyone who drinks cocktzilr; produced healthier, longer-lived regularly will get a leth31 dose of 2-21 J&WJssIo~ animals than the control animals. The tiny dose stimulated the body’s defense mechanisms. In turn, the body became stronger. equal rumber of marbles are being There is no change in the total added. number of marbles, but the marbles present in the box at any one time may not be the same ones that were present earlier, or that will. be present So it is with our bodies. later. Atoms and molecules constantly move in and out of the cells and tissues of our Although they are oonstantly bodies. moving in and out, the total numbers remain the same (within normal limits). The concept of sufficient challenge should not encourage anyone to be careless with chemicals. However, as Dr. Smyth stated, general recognition of this concept “would do much to alleviate the emotjonal revulsion whioh the thought of chemicals in dally life so often evokes.” If a chemical can be stored in our fat. liver, or bones, it will inorease only to a level that brings it Jnto equilibr+ium with the level of At this point, the amount exposure. zoing into storage equals the amount (The number of coming out of storage. marbles going in equals the number coming out. 1 TRANS-SCIENCE Some people expect science to find answers to all questions that can be Unfortunately, this is not asked. In the words of Dr. Alvin possible. Weinberg, “1 propose the term ttrans-scientific’ for [some] questions since” although they “can be stated in the language of science, they are unanswerable by science; they transcend science. When thu exposure level increases, the number of molecules going into Storage .increas+s over the number that are In this case, coming out of storage. the level of storage increases until a When the new equ i.librj.um is reached. exposur(? level decreases, the number of molecules going into storage is less In this than the number coming out. case9 the level of storage decreases until a new equilibrium is reached. If exposure terminates, all of the stored chemical is eliminated from the body. The Urn*? needed to reach equilibrium and the level of storage at equilibrium are different for each chemical. n For example, one may ask, “will chronic exposure to small amounts of some foreign chemical be harmful to me?” The answer cannot be given with a definite wyes” or “no.” The fact that toxicology cannot provide absolute answers to such questions should not be Toxioologists can cause for alarm. judge the possibilities and probabilities of harm resulting from These exposure to chemicals. judgments, coutbined with suitable margins of safety, have been proven to protect our health. Storage is considered to be a defense A storage depot mechanism of the body. During periods of serves as a buffer. increased exposure, the chemical is removed from circulation into the storage depot, where it does no harm. When ex:>osure ceases, the chemical moves ollt of the depot. and is The depot eliminated from the body. can be used for future storage, if Only when exposure is too necessary. high or prolonged with the storage site Then the amount of becomes saturated. circulating chemical becomes greater than the body can tolerate, and harm results. BIOACCUMULATION The idea that we store foreign chemicals in our bodies, and accumulate them indefinitely upon every exposure and to them is very frightening totally false. Our bodies are not inert objects like They function in a state stones. This state called dynamio equilibrium. can be likened to a of marble from which some marbles are constantly being removed while, at the same time, an 2-22 \ , SELF TEST AND ANSWERS 2-23 L&BON ,. Toxicology is the science that 7 - Pm-1 studies the a. medicinal effects of chemicals. b. harmful effects of chemicals. Q. beneficial effects of chemicals. ;‘. Living organisms can dlstlnguish between natural and synthetic chemicals. a. True b. False 3. The laws of toxicology 3 a. True b. False 4. Pesticide, encounter as a class, in our daily apply only to natural are more toxic lives. chemicals. than many of the other chemicals a. True b. False 5. The toxicity of a chemical bears no relation to how it a. True h. False 6. The most important component of chemical a. IIOU it is used and stored. b. how it is named. r. the warning statement on the label. 2-24 hazard cls is used. we 1. Of the many factors the most important a. b. c. d. 2. If that is: determine whether a chemical will be toxic, age state of health how much exposure and how often individual susceptibility a chemfcal fs acutely toxfc, It wfll also for people be chronically toxic: a. True b. False 3. The most chemicals common routes are: of exposure who work with num8rous a. oral and dermal b. dermal and lnhalatfon c. fnhalatfon and oral 4. After hr&3frp cwalsit or smoking k8us8t yeu sirouM always wwk y(wr hands before l atfng a. clean hands look better than dirty ones b. we mfght inhale any dfrt that may be on them c. we might contaminate our food or cigarettes 5. The poorert barrfrr a. the b. the c. the 6. Every chemfcal ti the antry of chemicals Into the body than the is offered intestfnes lungs skin has f 1 kind, s of acute toxfcfty. a. two b. three c. four d. six 7. When two indivldual chemicals toxfcltfes, In combination the effect are more Is known a. addftfve b. synergism c. antagonism 2-25 harmful as: sum of the by: LESSON 2 SELF 1. P&j.?&& Toxic chemicals cause damage at the point where they touch the body, whereas corrosive chemicals do damage at a site removed from the point of contact,: P. Trut? b. False 2. Chr*onic! tcJxic:.i t.y is much easier to study In the laboratory than Is acute toxicity: a. True b. False 3. An oral LD 50 tells us something about how toxic a chemical is when: a. inhaled b. absorbed by the skin c. taken in food or drink 4. The greater the LD 50, the greater the acute toxicity: a. True b. False 5. 6. A chemical with lethal dose for an oral LD 50 of 20 rag/kg would probably a 100 kg man of: a. b. c. d. 20 mg 200 mg 2,000 nlg 20,000 mg If a person suffers a mild never fully recover: viii.1 accidental poisoning, a. True b. False 2-26 have an average the chances are that he gFSSON 7 - PART 4. SELF TEST 1. We know less acute effects about chronic, because: adverse effects of chemicals a. They are not ils impOrtant a3 WUtC effects. b. WC do not know how to study them. C. They are extremely difficult and expensive 2. than we do about to perform. People who work with pesticides have less information about the toxicjty the chemicals they work with than do workers in general industry. of a. True b. False 3. The term LD 50 applies to both acute and chronic toxicity: a. True b. False 4. Thresholds are absolute directly to man: values determined in animals that can be applied a. True b. Fnl.se 5. Tf ti uo-effect level of a chemical in food is determined to be 700 m&kg of to be in human food would be no more food (700 ppm), the amount permitted than: a. b. c. d. 6. 7 ppm 1 PPO 100 Pm> ,., (, 700 p#Ul. Chronicc adverse a. b. c. d. e. ,‘!yi.’ t effects of chemicals are: dose-related predictable both a and b only a only b 2-27 1. The common connection is: among mutagenesisc teratogenesis, and oarcinogenesis a. Cancer b. Chemicals c. MutaLion 2. Quite a few pesticides are known human aaroinogens: a. True b. False 3. Only a small chemicals: fraction of human cancers are due to exposure a. True b. False 4. Few chemicals appear cancer Ulmotly: to muse a. True b. False 5. The existence of thresholds for carcinogens a. A subject on which all soie&ists b. A proven fact c. A subject that is much debate gglree 2-28 is: to envjronmental 1. A chemical that is toxic under some aonditions under some other conditions: is not necessarily toxic a. True h. False 2. Because of sufficient chal.leBgs ithe theory that trace chernjcals may be bsnefioi,al) &ged# not have to be very ourselves uhea we haW&e pc&w&MUy toxic chemicals: amounts of foreign careful to protect il. True b. False 3. Scjence is capkble of: a. answering aryr quwation that ciao be asked of it. b. Givirq a definite @yes~ w *ue@ to any question asked of it. C. answering PCMBSqueationa and -king judgments about others. 4. lf a chemical life. 1s stored in your body, it stays there for the rest of your a. True b. Fal se This lesson has been based on the book The Dose Makes the Poison by M. Alice You will expand your knowledge and increase your understanding Ottobonf, M.D. of thlr leema by ncrdlng her beok. 2-29 ::3. b” b 1. c 1. 2. b 2. b 4. b t: 0: ; B b 65: :: 7. b 1. c 1. c 1. a 2. b 3. b 4. b 2. b 2. b :: t: : 5. c 65: : if I A. UCTIM Pesticide labels have been called the most expensive literature printed. The research and development that lead to the wording on a label cost millions of dollars and require years of testing. The combined knowledge of many scientists -- including toxioologistsl chemists, pathologists, universities, and government -pharmacologists, and others in industry, has been used to develop Information found on eaoh pesticide label. TO UND- B. How well do you know some of the terms that are important in the use of pesticides? Test your knowledge of them by writing down the definitions for the terms below. To oheok your answers, refer to the glossary. 1. Label 2. Signal Words 3. Trade Name 4. Cdolencnn’N8me 5. Chemical Name 3-1 6. Vol.atility 7. Low-Volatile (pesticide) c. DISCUSSION Each time you buy a pestloide, you al80 reoeive instruotions to tell you how to Those instructions are the use It. What is labeling? What is a labeling. label? These words seem alike but they do not mean the same thing. Labeling is all the information that you reoeive from the oompany or it8 agent about the product. Labeling inoludes ruoh things 88: - The label on the produot Brochures, Flyers, and Other information handed out by the suppliers. The label is the information printed or attached to the oontalner of This label does many pestioidee. thirqs: - ‘l’o the manufacturer, label is a nlioense sell". on - The label is a way to tell u8ers about speoial safety measure8 needed. Some labels are easy to understand. Others are oomplioated. But &l label8 will tell you how to use the product The seotion below will explain correctly. most of the item8 that must be on a label. PARTS OF THE LABEL Tru Eaoh company has brand names or trade names for its products. The brand or trade name Is the one used in advertisements. The brand name shows up plainly on the front panel of the 1abel . It is the most identifiable name for the produot. Many pestioides have complex chemical have been given names. Some pestloides another name to make them easier to identify. These are oalled oommon carbaryl is the names. For instanoe, oommon name for l-naphthyl-N-methylcarbamate (ohemical The same pestioide may be name). formulated or dlatributed by more than one oompanyI and sold under several brand names. The same oommon or chemical name appearing on all of them. the to - To the State or Federal Government, the label is a way to oontrol the di8tributlonr storageS sale. user and disposal of the produot . - To the buyer or u8er, the lab.1 is a main source of frots on how to use the product oorrectly and legally. of FB Different types of pesticide formulations (such as liquids, wettable powders, and dusts) require different method8 of handlily. The label will 3-2 tell you wh8t typo of formulation the The 8~e perticide p8okuo oont8in8. uy be rv8ilable in more th8t one fomul8tien. Ivery peatioido lab01 mrt in the produot. The amount 8otivo ingredient ir given peroeat8ge by weight Or 88 gallon of conoentr8te. The ingredient c8n be liatod by chemic8l name or it8 aoron i-i-t8 inert the 18b.1 nod U8t Ehow 8otivr ftr either MM. Oh, nmo4c but perout the of oontentr. The not much i8 l xpro88e4 Unit8 Of The name di8tributor Anyone l in oate8t8 Iyyber th Wllt8ilMr. in gallonr, tell8 yeu qu8rt8, or other W8WO. 8ddrO88 of the m8ker or m8t rpp08r on tho 18bOl. then oont8ot the manufaoturor 8nd 08n Toxief Highly ty toxio Hederrtely Lou t*xioity have on a the question produot. Ts 40 their job, moot pesticides must pest, whether it be control the W-get imeot, plant, animal, etc. By their n8ture, postioides are toxic by varying dogreos to on0 or more pests. Therofore, some lnry 8180 be hazardous to pooplo. You can 8eouro information on the toxioity of 8 produot by reading the rignal word 8nd looking at the symbol on the label. how 0811 be Thi8 if they informtion A registration number must be on every pesticide label. Thi8 nuaber ahows that the produot ha8 been regi8tered with the Federal Qoverrment. The number u8u8lly 8pperr8 on the front panel of the l&be1 and will bo written as “EPA Regirtrrtion Ho. 00008. The l &.rblirhment numbor tell8 what factory mde the ohuical. This number does not h8ve 60 be on the 18bel, but will be 8meuhere on each oontaiaer. li8t what ir of l aoh 8a 8 pOUrrd8 per not k their or’distributor or wrnt more C8togory toxlr I Category c8tagwy 3-3 II III Or8l LD 50 O-50 mg/kg Ranges 50-500 w/kc 500.5000 @kg All produots must bear the statemoat @Keep out of ret&oh of ohildrwP. these effects, the label environmental precautions should read and follow. contain8 that you Here are some examples: Symbols are good ways to oatoh a person’s eye. This is why a skull and crossbones symbol is used on all highly toxic materials along with the signal word DANGER and the word POISON. Pay attention to the symbol on the label. It is there to remind you of the contents. - "This product is toxio to bees exposed to direot treatment or to residues on oropsn. - “Do not contaminate water when cleaning equipment or when disposing of wastes”. - wDo not apply where runoff likely to occur”. Public laws require that all pesticide product8 meeting the criteria of Toxicity Category I shall bear on the front panel the signal word “Danger”. In addition, If the product was assigned to Toxioity Category I on the basis of its oral, inhalation or dermal toxicity (as distinot from skin and eye local effects) the word WPoieon” shall appear in red on a background of distinctly contrasting color and the skull and crossbones shall appear In Immediate proximity to the word apoi80n~. Labels may also contain broader warnings against harming birds, and wildlife. Phyrioal The label will tell you emergency first aid measures. It will also tell you what types of exposure require medical attention. ,,, ,, The pesticide label and safety data sheet are the most important information you can take to the physician when you think someone may have been injured by a pesticide, Animals) This section of the label will tell you the way8 in which the product may be dangerous to man and animals. It will also indicate other special steps you should trike to avoid injury, such as the kind of protective equipment needed. Statement of Use Classifioation Every pesticide label must show whether the contents are for general use or restricted use. General use pesticides are very unlikely to harm the applicator or the environment when used as directed on the label. If the product Is highly toxic. this section will inform m of the proper treatment for possible injury. Ba8ards tools. However can cause To help avoid Hazards Statement of Praotical Treatment Ra8ards to Humans (and Domestio Pesticides are useful wrong or careless use undesirable effects. and Chemioal fish This section of the label will tell you of any speoial fire, explosion, or chemical hazards of the product. The Velpar L label is an example of a label that ha8 wDARGBRwon it, but is not in Toxicity Category I. Environmental is Restricted potential use pesticides oarry the to harm the applicator and the environment even when direoted on the label. The label on these 3-4 products will say: nRestrioted use besticide for retail sale to and application only by certified applicators or persons under their direct supervi.siorP. The restricted use statement must be at the top of the front panel of the label. to use a product in a manner inconsistent with its labeling. Do not use the product on a site which is not listed on the label. Do not use it at more than the recommended rate. Y The instructions on how to use the pesticides are the best way you can find out the right way to apply the product. The use Instructions will tell - the pests for which the product is registered to control (Labels use common names for pests. Knowing the names of the pests will aid in choosing the correct pesticide. 1 - The crop, animal, or other item on which the product can be used. - Whether the product ia for general or restricted use, - In what form the product is to be applied, - How much to use* where the pesticide ehould be applied, and when it should be applied. This section of the label will remind you that it is a violation of Federal law you -- Statfjag& An area that has been treated with one of the more toxic pesticides may have a set period of time after treatment before allowing re-entry. If required for the product, this section of the pesticide label will tell you how much time must pass before the treated area is safe for entry by a person without protective clothing. of ADDlioator If required for the product, this seotion of the label will limit use to certain categories of commercial applicators. Every pesticide should be stored and disposed of This section of correctly. the label will tell you how to store and dispose of the product and empty containers. (See the self study guide for safety training of on-the-ground herbicide applicators for further discussion on this topic 1. 1 RESTRICTED USE PESTICIDE FOR RETAIL CERTIFIED SALE TO AHO APPLMZATORS APPLICATION OR DIRECT PERSONS ONLY UNDER 1 BY THEIR SUPERVISION *DE PEST+ a INSECTICIDE EMULSIFIABLE WNCENTRATE INERT TOTAL INrBEaNTs: .._.. _,. ___..._.. .._.._ lQOO% w b DIRECTIONS FOR USE I I STATEMENT OF PRACTICAL SEE SIDE PANEL PRECAUTIONARY FOR TREATMENT ADDITIONAL STATEMENTS EPA EST. NO. 00475 EPA REGiSlRATiON NO. 135742 NET CONTENTS ONE GALLON I I DIRECTIONS FOR CONTINUED USE SELf TEST AND ANSWERS 3-7 . 1. When you buy a pestioide, you will reoelvo iostruotions The80 inatruotions will be found on: be uwd. _ __ - a. b. o. d. The label l ttaohed to thr oontainor. Broohuree and flyorr put out by the mmufaoturer. Printrd information handed out by your doelor. All of the above. 2. The most important L_ - a. b. o. d. a. b. o. d. 1, fill on a label number on this a. The name of the faotory b. That FDA has registered a. That EPA ha8 re&rtered 7. The EPA establishment z by different names: in the following: mat . label . $8 . . am oontain: Ths oorurr(=‘of inert ingredients The names of the inert ingredient8 The names of the aotfve iugredlent(r) a and c above 6. The EPA regirtration - may be oalled produot m8e 8houn on thir label ir oomon rime for the aotive ingredient ohemioal me ia . pound8 of aotive ingredient8 are name and addresr of the maautacturer .,__..,, 0.. b. c. d. is to - safety equipment equipment label applioation equipment of pe8tioidO8 5. The PngredXsnt statement _I -- to do before usin# a pertioide Comaon Chemioal Trade Roth a and b 4. Using Exhibit The The The The The things Check and test all Calibrate the spray Read the pertiolde Clean the pestioide 3. ALotive ingredients - on how It should and their tell8 you: that made the ohemioal the produot the produot number on a produot: a. The faotory that made the produot b. That EPA ham regirtered the produot o. That the produot oan be legally sold pweent. . 8. Match the following: 1. Moderately toxio 2. Highly toxio 3. Low order of toxicity A. CAUTIOH B. UARNINU C, DANQER 9. Every pestiaide label must aontaln the word(s): __ a. VAUTION” b. “DANGER--POISON” o. “KEEP OUT OF REACHOF CHILDREN” ___ d. “WARNINO” 10. A label may have “DANQERwprinted on it, without orossbones, and have a low order of toxioity. - the skull and a. True b. False 11. Aooording to Exhibit - a. Low - b. Moderate o. High 1, DEPESTOhas which order of toxicity: 12. Assume that you or someone you’re working with is suspected of having The first source of information and been injured by a pesticide. instruotlons for first aid should oome from: -- __ _13. a. A oounty agent b. The pestlolde label o. A referenoe book on poisons d. The looal pestloide dealer For everyooe~s safety handle pesticides: a. __ b. __- o. . ---._ d. 14. with regulations, by your salesperson at the time of purohase. In the same way your frimd or oo-worker does. In the same way that has always worked for you. According to the labeling. use pestioide oan only be legally used by: a. A oertlfied applloator, or someone he/she b. A professional pert oontrol operator o. Either of the above is supervising 15. The most important information you oan give a phy8iCiaZl suspected of having been injured by a pestioide is: __ __ you should As lnstruoted A restrioted __ .-__ and to keep In line when a person is a. How long the person has been exposed b. What first aid you have applied a. The label, and the safety data sheet of the suspeoted pestioide. 3-9 1. d 8r. 3 b. I 0. 2 C 9. c d 10. a ?rodwt rime ir DopWo. camlotl MIW is PestofY. Chalarl rime is (trisrlioylic-2, !s4tobloromrlwrk), PowId of@ 4itWw~-**Nme ahd Mdnn of mmufa&rer is AZ Otmnhal8, Ino. chamity, ninne8ota 55885. . 11. c 12. b 13. d 5. 6. 0 7. a 15. 0 The active ingredients in a pesticide are the ohemicals that control the target pest. Pesticides are rarely made up only of active ingredients. Usually a pesticide is diluted in water or a petroleum solvent with other chemiaals being added before the product Is offered for sale. These other chemioals may include surfactants , wetting agents, spreaders, stiokers, extenders, dlluents, etc. They usually make the produot safer, easier to apply, more convenient to handle, and more aocurate to measure. This combination of aotive and inert (inaotive) ingredients is aalled a pesticide formulation. Some formulations are ready to apply. Others must be further diluted with water or a petroleum solvent by the user before they are applied. How well do you know some of the terms that are important in the use of pecticides? Test your knowledge of them by writing down the definitions the terms below. To oheck your answers* refer to the glossary. 1. Formulation 2. Adjuvant 3. Surfactant 4. Solution 4-l for 5. Suspension 6. Synergism 7. Emu1sion 8. Invert 9. Absorption emulsion 10. Adsorption 11. Compatible C.DfSCUSSIOIP TYPBS OF FORMiLATI010 Pesticides are often sold in several different kinds of formulations. You should ohoosb the formulation that will be In making your choice, beat for each ude. ooneidar : .- the plqt, a&ml, or area to be treated ‘0% )titectedr - 4~&;rren4Mn equipment available and boat m&h4 fo-r the @jab, L-7 - hazard of drlf t or runoff. - safety to applicator, and other humans and pets likely to be exposed, - habits or growth patterns of the peat, - co&a, and - type of environment in which the application is to be made. The most common typea of liquid and dry formulations are desoribed in the following The abbreviations are included mations. beoause the labels and labeling may refer to the formulations in this way. Flowables Emulsifiable (EC or E) Some aotive ingredients can be made only as These a solid, or a semi-solid. ingredient8 are finely ground and put into a liquid along with other substances that make the mixture form a suepension. This suspension is a flowable solid. Flowables can be mixed with water. They seldom clog spray nozzles. They need only moderate agitation in the spray tank. Conoentrates An emulsifiable concentrate can be mixed with water to form an emulsion. Diluted EC’s usually need a small amount of agitation in the spray tank. Solutions (S) Formulations of these pesticides oontain the active ingredient and one or more additives. When mixed with water, the pesticide formulation forma a solution that will not settle out or separate. Solutions may be used in about any type of sprayer. Ultra (F or L) ktro8018 (A) iierosola or “bug bombs” are usually pressurized can8 that aontaln a small amount of pesticide that is driven through a emall nozzle under pressure from an inert gas. AerO8018 are often used as household peBtiOide8. AerO8018 can poee a hazard when transported during hot weather. Low Volume (ULV) Conoentratee ULV concentrate aolutlona o0ntaj.n 8 or more pounda of active ingredient per gallon. The solution may be close to 100 peraent ULV concentrates are act lve ingredient. designed to be used aa is or to be diluted with only small quantities of speoifled solvents. Low Volume (LV) Conoentratea These formulations usually contain less than 2 pounds of active ingredient per Many of them are solutions in gallon. highly refined oils. Generally no further The label will give diiution is needed. you directions for uae. Liquif ied Ga8 Some fumigant8 are gases that become liquid when placed under pressure. The pressure in the container may be either high or low, 4-3 depending on the produot. Some nematioides, in8OOtiOide8, fUngiOid88~ rodentloides are formulated this way. These formulation8 are applied by: - injecting them direotly - releasing them under tarps, - releasing them into greenhouse. into may be adsorbed to the granule, or only coat the OUtSide or both. Granular formulations are safer to apply than EC's or dusts. Granular formulations, like dusts, should alw8ys be used dry. not mixed with water. and the soil, or a structure suoh as a Some other eotive ingredient8 r80ain liquid in an ordinary oontalnerr but turn into a gas as they are applied. Powders (UP or W) Wettable These formulations, are dry, finely ground and look like a dust. But, unlike dusts. WPts are made to mix with water. Host wettable powders are much more oonoentrated Wettable powder8 form a than dusts. suspension rather than a true solution when added to water. Continuous agitation is needed in the spray tank to maintain the suspension. bust (D) Host dust oontain: - an fOr0ulatlOn8 ingredient, adAVe are reedy plU8 - a very fine or powdered, dry, substanoe 8UOh a8 tal0, Clay, or voloanio ash. The amount ranges from Ingredients particles. A dust can areas. Oranules t0 use and Inert nut hulls, Soluble Powder8 (SP) Soluble powder8 also are dry formulations. But when they are added to water, the SP for08 a true solution. Agitation in the spray tank may be needed to get them to fully di8SOlVe. After that, no more agitation is needed. of aotive ingredient ueurlly All the 1 to 10 percent. are ground into fine, uniform &lSt tiWEiy8 0U8t be USed dry. easily drift into nontarget (0) Granular foMwlatlon8 are made by applying a liquid for0uletlon of the aotlve ingredient to ooarse pertloles (granules) Granule8 are muoh of borne porous ataterial. larger then dust partioles. The pe8tiOide Baits A bait peats. I I (B) is a formulation that Pesticide inoorporeted attraots in the bait kills the peat formulation. control rodent amount of active formulations is than 5 percent. which eats the Baits are generally used to and inseot pests. The ingredient in moat bait quite low, usually less An adjuvant Is a substance added to a pesticide formulation, or tank mixture to Increase the effectiveness of the active Moat pesticide formulations ingredient. Some product labels contain additives. recommend that adjuvanta not be used. Caution must be taken; lndiacrjminatly adding adjuvants may decrease the Some effectiveness of the pesticide. common adjuvanta and their effeota on pesticide formulations are: more than one Mix two or more pesticides together only if they are compatible, one does not affect the properties of the other. Some different pesticides are formulated together by the manufacturer. Also, some pesticide labels list other pesticides with Other labels whioh they are oompatlble. may state that you should not mix the produot with certain peatioidea. allow petroleum-baaed to mix with water to form ooncentratea (EC’s); It is very important not to Indiscriminately mix pesticides. The material should always be mixed for specific-use reasons, and only then when compatibility has been determined. - Invert emulsifiers allow water-baaed pesticides to mix with petroleum carriers to form a mixture oontaining a water-soluble pesticide dispersed in oil; It is also important to check for compatibility of the pesticide with the spray tank and application components. A pesticide may react with incompatible application equipment, oausing excesslvo oorrosion, dangerous gaaear etc. through of a of coated and; COMPATIBILITy - Drift retardants (thickeners) reduoe drift by increasing the droplet size. They can also help reduce foeming; reduce phytotoxicity on a plant; - Spreaders help form uniformly, layers over the treated area, An adjuvant usually contains of the above additives. - Buffers are used when mixing pesticides of different acidity or alkalinity; - Softeners pesticide on the - Wetting agents reduce the surface tension of pesticide mixtures to Increase surface They are also used in mixing spread. wettable powders with water to increase their adherance to a treated surface. - Anti-foaming agents which reduce the foaming of spray mixtures that may result from vigorous agitation; - Penetranta help get a pesticide the outer surface to the inside target pest; help keep pesticides area; - Surfactanta inoreaae the emulsifying, dispersing, spreading and wetting properties of a pesticide product. Enhanoea the combining of liquids with different properties, such as water and oil. ADJUVANTS- ADDITIVES - Bmulsifiera pesticides emulsifiable - Stickers treated a 4-5 SELF TEST AND ANSWERS 4-7 1. Which of these pestiside with water: - formulations would form a true solution when mixed a. Wettable Powders b. Emulsifiable cower&rates c. &l&ions 2. When two or more pestieldes can be mired together and one does not affect the properties of the other, they are s&d to be: L ___ a. Synergistio b. ComIUme&tary 0. Phytotoxic d. Compatible 3. Match the followdlpg: I_ a. Suepenaion _I_ b. golutlon c. Emulsion d. Invert emulsion: 4. Dusts drift -a. - formulations: ~5 xxx?times added4 to pesti&des a. Red,uce foamfng b. Reduce di-if’t: Aid in penetration d,. All of these 6. Liquefied _ __ less than granule True b. Falao 5. Adjuvants I_ -0. _ 1,. The Ingredients will not 8bt.tle aut . 2. Suspenrion of water in oil. 3.. Suspension of oil: in water 4. Particles mixed (dispersed) in a l&quid. a. b. o. gases are used as: hUUi&lIktS Sprays Plowablea 4-8, to: 7. Whioh of these must be agitated 8, Which picture as applied? a. - b. shows an emulsion? OIL DROPLETS - b. a. 9. Match the following: __ - a. Baits b. Dusts c. Granulea - d. 8. f. g. 10. Most dust application. - 1. Dry formulation that dissolves in water. 2. Forms a suspension in water 3. Attraots pests. 4. Coarse particles. 5. Fine powders applied dry. 6. When two pesticides are mixed together their aotivity is greater than the sum of the two. 7. Aids in mixing oil and water. Soluble powders Wettable powders Surfactant Synergistio and granular formulations are to be mixed with a. True b. False 4-9 water prior to 1. c? 6. a 2. d 7. a 3a. 4 b. 1 c* 3 d. 2 8. b 9a. b. 0. tl. 3 5 4 4. b 5. d 1 2 F: 7 s. 6 lo. 4-10 b A. INTRODUCTIOll Without pestloides, we would not have the food , fiber, and the quality of life we have some to expeot. Beoause pestioides oan be dangerous if used improperly, Congress has pa88ed laws affeoting pestiolds use. These laws try to balance the need for pestioides against the need to protect people and the environment from their misuse. You, B. m Servioe employee , need to be familiar as well as Forest Servioe polioy regarding as a Forest regulations, YOU m with these laws and pestioide use. TO UND- How well do you know some of the terms that are important in the use of pesticides? Test your knowledge of them by writing down the definitions for the terms below, To oheok your answers, refer to the glossary. 1. Restrioted-use 2. Certified 3. Residue 4. Toleranoe 5. Suspended 6. Canoelled Pestioide applioator 5-l The law dpaa allow C. The FEDERAL INSECTICIDE FUNGICIDE, AND AODENTICIDE ACT (FIFRA), as amended is the law, that regulates the registration, manufacture, transportation, and use of pestioides. FIFRA was substantially amended In 1974 the user in and 1978. The law affects many ways. Most importantly, FIFRA provides chat -- all pestioides must be Used only as directed on the label. - all pestiaide uses must be classified as wrestriotedn or “general”. - persons who buy or use restriated-use pestloldes llrust be as oompetent pestioide certified appllaators or must be direotly supervised by a oertified appliaator. - persons who do not obey the law will be subjeot to penalties (fines and jail terms 1. - apply a pesticide pest on the labeling appliaation is animal, or site listed. any target you to -against not listed if the to a orop, that is t - use any equipment or method of applloation that Is not prohibited by the labeling. - mix a pesticide or pest&idea with a fertilizer if the mixture is not prohibited by the label lng. - mix two or more oompatable pestioides if all the dosages are at or below the reoonunended rate. The Environmental Proteotion Agenay (EPA) administers FIFRA and by regulation has set minimum standards of competenoe for users of restrioted use The Forest Servioe, in pesticides. certain oategories, and the States have developed their own plans for oertifioation of oompetenoy that meets A person who wishes EPA’s standards. to beoome oertlfled by a Federal or State agenoy should know the information In the following seotions. EPA direots that pesticides irill be alassified as nrestrlotedn or “general n. Many times, all the uses of a particular formulation are olasslfied as restrioted or all of them are classified ae general. SometlmeBc however, oertaln uses of a formulation are restrioted and other usea of the .Bame produot are not. For example, TORDON101 Is restrioted; TORDON101R In these oases the is not restrioted. direotlons for use for the two olasslf ioations must be olearly separate from one another. A pesticide (or some of its uses) be olacrsified as “general useN if not likely to harm humans or the environment when used as directed the label. A pesticide may not be used in any manner whioh is not permitted by the You must use the pesticide 1abel ing. otly on the plants, animals, or sites specified in the directions for use. You may not use higher dosages, higher concentrations, or more frequent applioations than speolfied. You must follow directions for use, safety, mixing, diluting, storage, and disposal -- a8 well a8 restriotions on re-entry and days to harvest, slaughter, and grazing. will it is on A pestioide (or some of its uses) will be olassified as Westrioted use” if it could cause human injury or environmental damage if not applied by oompetent persons (oertlfied applioators) who have demonstrated the ability through testing to use the8e pestioides safely and effeotively. 5-2 must be recertified at set periods. Check with your State or Agency to determine the requirements you need to meet. Classification of pesticides and pesticide uses may be based on -- the potential for injury of humans, - the type of formulationc - the way the pesticide is used, - the place in whioh the pesticide used, and - the potential for harm In the environment. Many adjoining States have developed agreements to allow certification in one State to be acoepted in the nearby States or throughout a region. The Forest Service has developed reciprocal agreements with many States. is Certified pestioide applicators fall applicators into two groups -- private The and oommercial applioators. differenoes are disoussed In the following sections. When a pestioide is restrioted. the label will read sRestricted Use Pesticide” on a prominent part of the When a pestioide is front panel. olassifled for general use, the words “General Classlf iaations will appear immediately below the heading nDireotions for We”. PRIVATE APPLICATORS Private applioatora are persons who use or supervise the use of -ted us!!! g&&Qim in produoing an agrioultural oommodlty on property owned or rented by themselves or their employer, or on the property of another person with Examples of whom they trade servioes. private applioators are farmers, ranohers, florioulturiats, and Private applicators are orchardists. trained or tested in the safe use and handling of peatioides and pest control praotices assooiated with agricultural operations. many NOTE: Although EPA has olaseified pesticide produots and uses, a few pestioides have not yet been In these instances, you olassified. should pay close attention to the signal words and human and environmental hazard statements on eaoh produo t . Persons who are not certified pestioide applicators may not purohase or use restricted use pesticides unless they are direotly supervised by a oertified applicator. COMMERCIAL APPLICATORS Commeroial are persons who for hire on property other than their own, and government workers (For example, Forest Service employees) who apply pesticides Commeraial appllootors on their jobs. are trained and tested in the general areas of safe use and handling of They then receive training pesticides. and testing in one or more specifio uses, inoluding -ude rertrioted Certffioation requires training and testing for oompetenoy in the aafe and effeotive handling and use of these pestioides. The State or Federal agency may oonduot the training and tests for certification. The State may impose stricter standards than those required by FIFRA. EPA requires each State and Federal agencies with oertification plan to maintain a program to assure that certified applicators have ourrent oertification, This oertification is not like a dootorls or plumber’s lioense that is good for the holder’s entire oareer. A oertified applloator applioators I) agrioultural pest oontrol (plant animal 1 forest pest control ornamental and turf pest oontrol right-of-way pest control seed treatment aquatio pest aontrol 5-3 or - industrial, institutional, structural, and health-related pest control, - regulatory pest control, and - demonstration and researoh pest control. registered this way. Look for the official EPA registration number (whioh must appear on the label) to be sure you are buying an approved product. (known as SLN or 24(o) registrations) are beooming more oommon. They allow a State, under some oonditions, to register w for a Federally-registered peetioide. These registrations often inolude additional applioation sites or pe8ts, as well as alternate oontrol teohniques beyond those listed on the Federaly-registered Several States have different or additional oategories for oommeroial applioatorr. f’or example, These oategorlor aerial applioation inolude, or wood preservation. It is illegal to apply a restrlotd-us6 pestioide in a category are ~QR aertified. in whioh you label. PEUALTIES The manufacturer must provide supplemental labeling for eaoh 24(o) registration. Users must have a copy in their possession of the 24(o) label in order to legally apply the pestiaide for the purpose shown on that label. These registrations are legal only in the State or local area speoified in the labeling. If you violate the law or regulations enacted under FIFRA, you are subjeot to The fine oan be as civil penalties. much as $5,000 for each offense ($1,000 for private applloators). Some violations of the law may also subject you to criminal penalties. These oan be as much as $25,000 or 1 year in prison, or both, for commercial Therefore, to use a applicators. pesticide in a manner inoonslstent with its labeling is a violation of federal law, state law, and Forest Servloe policy. are used when an emergenoy pest situation arises for whloh no pestloide is registered. If both Federal and 24(o) registrations would take too long to 18sue, an emergenoy registration oan be used, known as Qeotlon 18 exomptionan. Striot controls and reoord keeping are required for all theue emergenoy u8cm. The agenoy that has granted the emergenoy exemption will supply you with the neaessary rates, safety preoautlons, and other vital information. RBQISTRATION Every pesticide that is bought, sold, or used in the United States muat, by law, be registered by EPA. EPA approves not only the produot itself, but also eaoh separate use for whioh the produot is Intended, as well as the product label. You are responsible for applying only those pesticides that are registered. You may encounter registration -- three major types RESIDUES AND TaLERANCES The pesticide that remains In or on food or feed is oalled a residue. Residues that remain in food or feed at harvest or slaughter are oarefully monitored to avoid hazards to people and domestio animals that will eat these produots. of - Federal registration - special looal-needs registration - emergenoy exemptions from registration. v . Most pestioide EPA sets residue m in parts per million (ppm) for all orop and animal produots intended for food or feed. A toleranoe is the max.Smum are the ma uses are 5-4 Anyone who ships peetioides amount of peetioide residue that may remain on or in treated crops and animals that are to be sold for food or These toleranoes are determined by extensive testing. To ensure safety, the levels usually are set at least 100 times lower than the amount known to be harzardoua. If the residue exceeds the tolerence, the food or feed may not be marketed or sold. feed States between -- - The pesticides muat be in their Each package must original paokagea. meet DOT standards. - The vehicle must have a correct sign. - Manufacturers must put the correct warning signs on each package. - The peatloides may not be 8hQqmd in the same vehlole with food prOduOt8. I DOT must be contaoted immediately if the vehicle is involved in an aocident: l The Food and Drug Admlnietration (FDA~ monitors food and feed for toleranoe FDA sets tolerances for violation8. residues resulting from pestioldes applied to food or feed after harvest. This agency may condemn and 3eixe any products exceeding the toleranoes and may proseoute violators. The Meat Inspection Division U.S. Department of Apioulture monitora pestloide toleranoee animala and animal products. must know that 8) ;Lf 8omeone is b) if someone is badly enough or c) if damage is of the (USDA) in killed injured to go to a hospital, more than - DOT must be contacted if spill during shipment. The 1958 Food Additives Amendment to the Food, Drug and Coemetlc Act include8 a part called the Delaney Clause. This clause requires that be chemicals used as food additives considered aa human carainogens If they produce oancer in any animal apeolea, at any level of exposure. It must be stressed that the Delaney Clause applie8 only to food additives. During these past 25 year& it has never been extended to any of the many other chemloals in our environment primarily beoauee of objeotiona from the soientifio oommunity. With few exceptions, toxioologiata rejeOt the concept of the Delaney Clause beoause It excludes the exeroise of aoientlfic judgment in the evaluation of researoh data. $50,000. there is a State and local laws may require additional precaution8 for the transport of pesticide products. Application of pesticides from airplanes is regulated by the Federal Aviation Administration (FAA) and may FAA also be regulated by your State. ability of judges both the flying pilot8 and the safety of the aircraft. FM rules say that an aerial applloator may not apply any pesticide exoept as the label directs, In addition to the laws and regulations that you or a pesticide applicator have to abide by, there is Forest Servioe polioy that must be followed. The policy is contained in Forest Service Manual 2150 (FSM 2150) Pesticide-Use Management and Coordination. You should now review the section of the Forest Service Manual, OTHER REOULATIONS Shipment of pesticides and other dangerous aubstanoes across State lines is regulated by the U.S. Department of Transportation (DOT). DOT issues the rule8 for hauling the8e materiala, 5-5 SELF TEST AND ANSWERS 5-7 1. Matoh the followingl: - a. b. a. d. Residue Canoelled prrtioidr Certified applioator Suspended perticride 1. rerrtrioted-we 2. 3. b. 2. A11 pea$ioidee for --a. -b. - 3. 4. nest be olapsified Peatiolde No longer Wo longer and labeled the we of pertloidea left on orop legal to u8e registered ior uee by the maINAfa&kWer general use restrioted we o. either Applloators who violate 1 a. b, - o. both a and b fines jail FXFRA may be subjoot to 3- terms Matoh the Isllowing: - a. DOT b. BPA E o. 24(o) - d. tol@ranor - l . USDA - f. FDA g. lhuergenoy exemption from registrqtion FAA mh, 1. 2, 3, 4, 5. 6. 7. 8, 5. Can use or eupervire It is Forest Servioe poliqy that pestioides label. - The amount of pestioide residue allowed on farm produots and oonsidered safe. Setr rerrfdue t~J.ermoee Sppoial looal-needs registrations Used when an emeqewy pest situation ariecbe 4’~ which no pestioide is regirrtered. Monitor8 food and feed t’or peatioide f+ler+r-ioe viqiatipps. Monitors peatiolde toleranoee In anlmale and animal produots Regulates shipment of’ peetlcides Rquletea aerial applioatlon a. True b. False 5-8 be used aa directed on the 6. Training ___ 7. for certifioation may be conduoted by -- a. State agencies b. Federal agencies o. Both of these USDA Forest Service employees who apply of their job are considered -__ I_ -- 8. and testing restrioted-use pest&ides as part a. private applioators b. oommeroial applioators 0. nonoomrneroial applioators Servioe Manual -- polioy Forest on the use of pesticides is in Forest Servioe a. 3450 b. 1950 o. 2150 9. A reoord of the applioation maintained for -- of reetrioted use pestioides shall be a. one year b. two years --- o. three 10. The direot years applioaiton a. Regional b. Forest o. Forest 11. When a pestioide of a pesticide to water is to be approved by -- Forester Supervisor Pestioide ooordlnator treated area is posted the sign should a. the name and address of the manufacturer b. the name of the pesticide only o. the name of the pesticide, date of application, for additional information. 5-9 indicate -- and who to contact , , la. 2 5. a b. 4 1 6. a 7. b 8. o 9. b do: 3 2. cl 3. c 7 b. 2 0. 3 d. 1 4a. or 6 f. 5 g. 4 h. 8 5-10 10. a 11. 0 I- , A. There are many reasons for using pestioides safely, but the primary ones are to proteot yourself and other people from Injury, and to avoid harming the environment. Most pestioide aooidents knowledge about handling result from oareless praotioes and applying pestloldes safely. or lack of B. How well do you know some of the terms that are Important in the use of pesticides? Test your knowledge of them by writing down the definitions for the terms below. To oheok your answers, refer to the glossary. 1. Penetration 2. Ingested 3. Contaminate 4. Organophosphates 5. Carbamtes 6. Organochlorines 6-l c. DISCUSSION HOWPESTICIDES CAN HARM US Pesticides can cause injury. They are toxic, especially the insecticides, and Manuf z:?‘turers find out rodenticides. how toxic a pesticide 1s by testing it on animals, The product 9s hazard -the danger that It will Injure someone -- depends on the toxicity of the active Ingredient plus the degree of exposure to the product during use. Most pesticides can cause injury if However every registered misused. pesticide can be used safely with Children under 10 are the proper care. victims of at least half of the accidental pesticide related deaths in If pesticides were this country. always stored and used correctly, children and adults should never be injured. Many pesticides can enter the body through the skin. You may get more Into your body this way than you would by accidentally swallowing or inhaling while working. You can help prevent accidents with pesticides by aai:‘lg and storing pesticides a%;ay .?,“~a children and other untrained per 5,tns. Always take care to follow dirsc+.lonu when using a pesticide. Products for re:,tricted use need They should be handled specia.: care. The only 0. certified applicators. label iu ya.:: guide. SYMPTOMSOF PESTICIDE POISONING You should know what can be caused by the also should know the which eaoh pesticide Look for pesticide two kinds illness. kind of sickness You pesticides. conditions under may make you sick. of clues to Some clues are feelings that only the person who has been injured can notice -- such as These feelings are nausea or headache. signs that are as important as any You should know what visible clue. your own feelings might mean and what signs to look for In your co-workers and others who may have been exposed. All pesticides in the same chemical group cause the same kind of illness. The effects may be mjld or severe, depending on the pesticide and the However, the pattern amount absorbed. of illness caused by one type of pesticide is generally consistent. Of court-38 l every one who has some of these signs and symptoms has not always been Other kinds of injured by a pesticide. sickness may cause similar signs and Headache and a feeling of symptoms, being unwell, for example, may signal the start of many kinds of illness. The pattern of symptoms will make it possible to tell one kind of illness from another. Get medical advice quickly if you or any of your fellow workers have unusual If you or unexplained symptoms. suspect a person has signs or symptoms of a pesticide illness, do not leave Do not let yourself that person alone. or anyone else get dangerously sick before going to a physician. Take the container (or the label) of the pesticide to the physician along with the safety data sheet if available. These pesticides injure the nervous The signs and symptoms go system. They usually occur in through stages. this order -Mild - Symptoms fatigue headache dizziness blurred vision too much sweating salivation and - dizziness - nausea and vomiting - stomach cramps or diarrhea Moderate With more severe illnesses, convulsions They may even appear without follow. the warning symptoms. A coma may follow the convulsions. The person also may be unusually excited or irritable. Symptoms - unable to walk weakness cheat discomfort muscle twitches pupil of the eye becomes smaller - earlier symptoms that become more severe The signs and symptom5 of akin include -- Severe Symptoms - redness - burning, - blisters - unoonaciousneaa - pupil of the eye becomes very small - muscle twitches - secretions of mouth and nose - breathing difficulty - death, if not treated Other signs include - Illness may be delayed for a few hours. However, if the signs or symptoms start more than 12 hours after you were exposed to the pesticide, you probably have some other illness, Check with your physician to be sure. CarbW The only carbamatea likely to make you dll on the job act almost like the organo- phosphates. They produoe the same signs and symptoms. However, the injury they oauae can be corrected more easily by a physloian. For this reason* most oarbamates are safer than organophoaphates. The label will warn you of the danger. - and symptoms of poisoning headache nausea stomach ache restlessness hot feeling flushed skin sweating deep and fast breathing fast heart beat fever, ashen color collapse, and coma Too much exposure to these compounds may make a person seem drunk. The signs and symptoms are -- and symptoms of poisoning headacv nausea vomiting general discomfort, and Severe poisoning usually runs a rapid course. One usually dies or la almost well within 24 to 48 hours. Not many organochlorlnea (chlorinated hydrocarbons) have injured the user. Early signs include -- exposure and 6-3 poor coordination slurring word5 confusion, and sl cepl ness Repeated exposure to the fumigant, methyl bromide, has caused permanent internal injury without early sign: or symptoms of poisoning. You can ab:-orb a fatal dose of it before symptoms appear. INORGANIC PESTICIDES Large, single doses pesticides that are mouth or through the vomiting and stomach and symptoms depend which the pesticide - Rinse your mouth with plenty of water - Go (or be taken) to a physician, especially if you swallowed the pesticide. - It is sometimes dangerous to cause vomiting; follow label directions. of most inorganic taken fn either by skin cause pain. The signs on the mineral from is made. PLANT-DERIVED PESTICIDES If a pesticide Is splashed Into the eyes, wash it out Smmediately with an eyewash bottle for about 10 to 15 minutes. (See the application label and safety data sheet for more information.) Some plant-derived pesticides are very Teohnical (undiluted) pyrethrum toxic. some may cause allergic reaations. rotenone dusts Irritate the respiratory Nicotine Is a very fast-acting, traot. toxic substance. Some other plant-derived pesticides are strychnine, rotenone, and red squlll. PROTECTING TOUR BODY Pesticides oan enter the body in many ways. The main onea are -- FIRST AID PROCEDURES - getting the pesticide skin, - inhaling it, and - swallowing it. Read the directions in the *Statement of Practical Treatment” on eaoh label. These instructions can save your life and the lives of fellow employees. on your To prevent this contact, you must wear the recommended protective clothing and The pesticide label will tell equipment. you the kind of protection you need. Remember to bathe when you finish working with pesticides or pesticide-contaminated Any time you spill a pesticide equipment. on yourself, wash immediately. PROTECTIVE CLOTHING If you get a pesticide on your akin, remove the pesticide as quickly as possible. Remove all contaminated clothing. Prompt washing may prevent sickness even when the spill is very large. Don’t forget your hair and fingernails. Water-wettable powders or suspensions are easy to remove with plain water. So are most emulsifiable concentrates and emulsions. Solutions of pesticides in petroleum oil or other solvents are harder to remove without soap Detergents work better or a detergent. than soap. If you inhale immediately. a pestlolde, If you splash or swallow it a pesticide -- get to fresh into air your mouth 6-4 Bpdv Co~%l&x Any time you handle wear at least -- pesticides, you should - a long-sleeved shirt and long-legged trousers, or - a long-sleeved coverall type garment. This clothing should be made of closely When handling very toxic woven fabric. materlala, you also should wear a liquid-proof raincoat or apron. Wear trousers outside of the boots to keep pesticides from getting inside. away. If they get wet with highly toxic pesticides, destroy them. They are difficult to get clean by normal methods. Do not store or wash contaminated clothing with the family laundry. Wash hats, gloves, and boots daily, inside and out. Hang them to dry. Test gloves for laak:. by filling them with water and gently squeezing. Gloves When you handle highly toxic pesticides, Wash your goggles and face shields at least wear liquid-proof neoprene gloves. Always once a day. Elastic fabric headbands often read the label for specific instructions. absorb pesticjdes and are difficult to However, be aware that some fumigants are clean. readily absorbed by neoprene. The label RESPIRATORY PROTECTIVE DEVICES should tell you when and what kinds of . gloves to use. They should be long enough tract -- the lungs and to protect the wrist. Gloves should not be The respiratory other parts of the breathing system -- i..q lined with a fabric. Sleeves should be much more absorbent than the skin. You outside of the gloves to keep pesticides must wear an approved respirator when the from running down the sleeves and into the label directs you to do so. gloves. Hats Wear something to protect your head. Headgear should not have a cloth or leather These sweatbands are difficult sweatband. to clean if chemicals get on them. Plastic hard-hats with plastic sweatbands are good. Boots For highly toxic materials, wear unlined neoprene boots. However, some fumigants are readily absorbed by neoprene boots. Follow the label instruotions. Goggles Cartridge Cart&&e or Faoe Shield Wear goggles or a face shield when the label recommends that you do so, or if there is a ohance of getting pesticides in Your eyes will absorb some your eyes. pesticides. Follow the label instructions. Care of Clothing Wear clean clothing get wet with spray, Respirator daily. Jf your clothes change them right 6..-5 Res.p.Lrator You should wear this kind of respirator when you are exposed to an intermittent conoentratjon of highly toxic pestlr:.lde:j, or as recommended by the label. The inhaled air comes through both a filter pad and a cartridge made to absorb pesticide vapors. Most harmful vapors, gases, a!rd particles are removed. These half-face masks cover the mouth and nose. To cover the eyes also, use a mask that is combined with goggles or wear separate goggles. - when thn label directs of this equipment. the use Clean air is pumped through face mask. a hose to the Canister RespiZtor -. You should wear this kind of respirator when you are exposed to a aontinous concentration of highly toxic pesticides, or as the label directs. Self-contained Breathing Self Breathina The canister has longer-lasting absorbing material and filters than does a cartridge respirator. Gas masks usually protect the face better than cartridge types of masks. Neither kind will protect you during fumigation or when the oxygen supply is low, Apparatus Contained You should wear this kind of respirator under the same conditions as the supplied It does about the same air respirator. thing. The differences la that you carry cyclinderv of air or oxygen with you, This lets you move usually on your back. more freely and over a wider area than you can with a supplied air respirator. Specific types of cartridges and canisters protect against specific gasses and Be sure you choose one made for vapors. the pesticide you are using. Use only those approved by the National Institute for Occupational Safety and Health (NIOSH), or the Mining Enforcement and Safety Adminlsration (MESA). Supplied Air Respirator You may use this kind of respirator when mixing or applying highly toxic pesticides -- The respirator must fit the Long sideburns, a beard, or prevent a good seal. Read manufacturer’s instructions care of any respirator and you use it. - when the oxygen supply is low, - when you are exposed in enclosed areas, as in fumigation, or When applying pesticides, change filters, cartridges, and canisters if you have trouble breathing, or if you smell Remove and discard filters, pesticides. 6-6 face well. glasses may the on the use and Its parts before ,I’ cartridges and canisters after use. Then wash the face piece with detergent and water, rinse It, and dry it wj th a clean Store it in a clean, dry place away cloth. from pesticides. The useful life of a cartridge or canister depends on the amount of absorbent materials, the concentration of contaminants in the sir, the breathing rate of the wearer, and the temperature and humidity. Follow the manufacturers recommendation. If you have trouble breathing while wearing to a respiratory device, see your physician find out whether you have a respiratory problem. PROTECTINQ THE ENVIRONMENT The environment Is our surroundings and its many forms of life. Water, air, 8011, plants, and wildlife are important parts of our environment. Because pesticides can be pollutants, you must use them correctly to YOU prevent harm to the environment. should be aware of how pestlclde contamination can affect our natural resources. By knowing and following good application practices, the applicator and the environment can be protected. Using pesticides directed on the animals, leave the environment Pesticides can used with care. can occur. in a way other than as label can injure plants and Illegal residues, and damage In many other ways. oause harm if not chosen and Here are some ways damage Runoff from sprayed fields, especially those treated with insecticides, can kill fish in a nearby stream or pond. Life in streams can be harmed by careless tank filling, draining and improper container disposal. In addition to harming the environment, these misuses can result In lawsuits, fines, and loss of certification. If more than one pesticide will control your target pest, choose the one that is the least hazardous to the environment and most useful for your situation. Persistence Not all pesticides act the same after apply them. Most are in one of these groups : you two Pesticides that break down quickly, remain on the target or in the environment only a short time before being changed into harmless products. Pesticides that break down slowly may stay in the environment without change for. a These are called persistent long time. Most of them are not broken pesticides. down easily by micro-organisms, and are only slightly soluble in water. Some persistent herbicides can injure future crops planted during the next year. However these pesticides seem to be of little hazard to the environment beyond the treated soil. Pesticides become a problem when they move Problems may arise when a off target, pesticide -Do not let a pesticide contact anything except the target area. Drift from herbicides can kill nearby crops and You may kll ! bees and I andscape plants. other pollinators wit11 Insecticides if you treat a crop while they are working In a field. Or you could kill parasites and predators that help control hatemful insects. 6-.7 drifts out of the target area as a mist or dust, moves onto the aoil through runoff or erosion, leaches through the soil, is carried off as residues in crops and livestock, or evaporates and moves with air currents. Pesticides also may reaoh water This happens because of indireotly. erosion, runoff, and leaching. Peeti&&g Persistent pesticides may limit future planting. You can plant only crops whioh the pestlaide will not kill or contaminate. 1 Even pesticides directed at plants or animals can move to the soil. They may be washed or brushed off. They may be worked Into the soil with dead plant parts. Pesticides can help the environment when Most importantly, they can used correctly. help produce better quality and higher yields of food, fiber, and timber. Pest&&&g Mists and fine they may drift sprays should onto nontarget be avoided areas. Weigh carefully the advantages disadvantages of each pesticide Choose the pesticide that will damage while giving good control. of the job carefully eaoh-part beginning to end. as Water can be polluted if you use the wrong peaticjde or apply it carelessly, resulting in possible damage to fish and aquatio ljfe. Pestiaides 8 result alao of -- can reach water directly USQ and u3e. do the least Plan from USE m as Read, study, and oomplete the Forest Serviae Self Study Quide for Safety Training of on-the-ground Herbicide Applioators. Read the sections drifts, spills, applioatlon to waterways (ditches and streams), and incorrect disposal methods. on -- and Registration - Mixing and Applying -Transportation - Storage and Spills - Labelling 6-8 SELF TEST AND ANSWERS 6-9 1. A pesticide applicator his/her body through-a. - pe8tiCide8 require -- a. General applicators b. Applicators who have 10 hours of pe8tiCide c. Certified applicators 3. If someone is taken pesticider the pe8tiCide -a. -0. true b. false doesn't to a physician label should injury by a matter on your skin, you should Wa8h the a. within 1 hour after you were exposed a8 soon as you complete the application c. immediately at your normal. bathing time 5. Select the fcllcwing with organophosphate __ ___ __ _I_ ___ ___ training, because of possible accompany her/him. 4. If you spill a conoentrated pe8tiOide exposed area with soap and water -__ -b. __ -d. more of most peatlcldes Skin b. Mouth 0. Nose 2, Restricted-use __ __ - has a chance of getting a. b. 0. d. e. f. signs and 8ymptoms you would expect illness -- blurred vision constricticr? of the pupil in the eye blisters secretions from mouth and nose flushed skin muscle twitches .- 6-10 . to be associated into 6. The signs and symptoms of most are similar to those of organophosphates, but the injury can be corrected more easily by a physician. __ - a. b. c. d. organochlorines fumigants Pentachlorophenols carbamates 7. The best headgear __ _- a. b. c. d. to wear when applying a. b. c. d. a. b. o. d. would be good outerwear highly toxic, pestioides for -- toxic pestioides, gloves should not neoprene rubber with ootton lining cotton neoprene rubber without lining any of the above gloves and boots, a. outside each b. inside each c. either way 11. The cartridge or oanister often as the manufacturer chemical. __ work, be made from -- 10. To prevent a pestioide from getting into an applioator’s shirt sleeves and trousers should be worn -__ ___ pesticide Knit shirt Denim pants Wool shirt Cotton work clothes 9. For most highly I_ __ - is -- Redman cap Hard hat Cotton cap Summer straw hat 0. Which of these materials involving oonoentrated, __ __ - pesticides on pesticide reoommends, a. True b. False 6-11 respirators should be changed as or when the applicator smells the 12, When applyi a pesticide in an area where oxygen are used, whjoh of these devices can best proteot - a. -- The respirator you use __ - or both of these 13. a. MESA b. NIOSH c. either 14. Respirators -b. - should should be fitted a. fresh air leaks UP. a finger can fit indioate it is c. there is a tight a. true b. false should 16. Pesticides __ - - for that pesticide c. by -- -- the mask so the faoe shield will not fog between thr faoe and the edge of the mask to not too tight. seal betw%en the q a8k and the face. abrasions, protect them during applioation, be of no concern should not be transported inside -- a. open truck beds or open trailers b. passenger vehicles c. either a or b 17. If an employee you should -- - agenoies. 80 that 15. If you have any cuts and skin or do not apply peatioides. -0. b. be approved In around is low or where fumigants the wearer -- spills a large amount of a pesticide on hlmeelf, a. Immediately rush the person to a physician. b. Immediately remove the contaminated olothing and wash off the pesticide, begin flushing out the eyes, take the person to the physician. c. Not be concerned l G-12 18. If the sump inside should -- a pesticide - a. rinsed b. rinsed c. rinsed - contains a liquid, you container that has held a liquid shall be -- three times. two time::. one time. After exposure to an organophosate pesticide, which affects the nervous system, you would expert signs and symptoms to appear withi.n-a. h. -.-- -- c. - -... d. 21. building a. not be concerned for that is what it was designed to hold. b. wait until it has evaporated out, then check for leaks. c. Remove the liquid and treat it as a pestioide, then check the sump for possible leaks. 19. An empty pesticide 20. storage 12 13 25 31 hours to 24 to 30 to 36 Organophosphate .--------- a. b. C. d. or less hours hours hours and carbamate Disrupting Disrupting Inhihiting All of the insecticides kill the growth hormone balance. chi.tin synthesis cholinesterase above 6-13 insects by-- 1. a 11. ‘a. 2. c 12. b 3. a 13. c 4. c 14, c 5. a, b, 6. d 7. b 8. b, 15. dr f 16. b 17. b 18. c d 19. a 9. 0 ao,a 10. a Xl,C a 6-14 -DE A. APPJJCATIONEQUIPMENT. AND C-RATION JJJTRODUCTIO~ The equipment you use You must first select to suit your needs -you use hand-carried, B. TERMSYOU NEEI). is important to the success of any pest control job. the &gi& equipment. Then you must use it correctly and take good care of it. These rules apply whether tractormounted, or aircraft-mounted equipment. UNDERSTARQ How well do you know some of the terms that are important in the use of pesticides? Test your knowledge of them by writing down the definitions for the terms below. To oheck your answers, refer to the glossary. 1. g. p.m. 2. p.s.i. 3. Orifice 4. g.p.a. 5. Coverage 6. Swath 7-1 7. Drift 8. Volatility 9. Inversion 10. Residual 11. Corrosive pesticide choosing, applioation ,c. IlISCUSSION using, and oaring equipment. for DRIFT Many factors affect the ability of a pesticide applioator to effectively plaoe the pesticide on target, with minimal movement of the spray or dry materials off target. Drift is influenced by many factors, of whioh the equipment and application methods are key factors. Spray pressure, nozzle and spray tip design and size directly Influence drift. Some of the other factors influenoing drift are wind speed, temperature, humidity, height of spray release, volatility of the pestlolde. We would expect spray drift to etc. lnorease as the size of the spray droplets decrease, temperature inoreaaes, wind speed inoreases, and spray height increases. APPLICATION EQUIPMENT The following sections discuss some of the things you should know when i . 7-2 Hand sprayers are used to apply pesticides for small jobs. You oan use them In areas where a power unit Is The advantages of hand not practical. sprayers Include their low cost, simple oonstruction and ease of use. Pressure- These sprayers deliver undiluted pesticides to the target. Drift can be a problem because the droplets are usually very small. - These devices are often called hydraulic sprayers. They are designed to deliver large volumes at a high pressure (50+ psi.). They are generally used to spray fruits. vegetables, trees, landscape plants, Applications usually and livestock. are made at a high volume (100 or more gallons per acre). The high pressure reduces the droplet size, resulting in increased drift possibilities. Low-Mwure w. -- Over 7,000 airplane3 are used to apply pesticides in the United States eaoh year. Aerial application is fast, convenient and fairly economical. Airplanes can be used over areas that oannot be traversed by ground equipment. However, airplanes usually cannot efficiently treat small areaa* and are limited by power lines, highly populated areasc and adverse weather conditions. Some of the pestioidee released from airoraft may drift, whioh can pose a problem in or near populated areae. The larger uses are in agrioulture, and right-of-way work. L3.wuwz &&&gntera. -- Helioopter application ooata are usually more than for airplanes. However, heliooptera offer certain advantages: They can operate without an airport, are leas affected by weather conditions, offer leas drift potential, high accuracy in the placement of the chemical and work much faster than ground methods. These sprayers are designed to deliver low to moderate volumes at 15 to 50 Moat of them are used on fields, psi. forest areas, pastures and fenoe rows. The low pressure oan reduce drift possibilities by producing large spray droplets. SPRAYER PARTS Tanks Tanks should have large openings for easy filling and oleaning. The tank should be made of oorroaion-resistant material such aa stainless steel or glass-reinforced plastic. The tank should have a good drain. The outlets should be sized to the pump capacity. All tanks should have a gauge to show the liquid level. aat SPravers These units uae’a high speed, fan-driven airatresm to break the nozzle output into fine drops, whioh move with the airstream to the target. The air is directed to either one or both aides as the sprayer movea forward. These sprayers are used on landscape plants, fruits, vegetables, and seed orchards. Flush out the tank, pump, linea, and nozzles after each day’s use, and after 7-3 each separate pesticide use. If switching to another pesticide where contamination must be prevented, wash out the tank with detergent and water two or three times and then flush with water. Some herbicides, such as 2.4-D. After using them, are hard to remove. follow the special cleaning procedures noted on the pesticide label. Sprw tanks should be equipped with agitation By pass agitation is mechanisms. usually sufficient for solutionsc 8oluable powders, and emulsifiable For invert emulsions concentrates. mechanical agitation is required, Jet or mechanical agitation is needed for wettable powers. Roller #Pump Plrton These pumps provide low to moderate volume8 of spray at a high pressure. They are self-priming. If you need Ir6 pressures# piston pumps are more likely than other pumps to do consistant work over a long period of time. The pump is the heart of a spraying Pumps should resist oorrosion Unit. Three kinds of pumps are and abrasion. most often used with sprayers, and are debribed below. Centrifugal These spray of tea claim Pump Pump pumps provide a high volume of They are not at a low pressure. Some newer models self priming. priming ability. CAUTION DO NOT OPERATE PUMPS WHENTANK IS DRY. Strainers (Filters 1 Proper filtering of the pesticide protects the working parts of the spray unit and prevents clogging of spray tips. Roller Clean strainers after each use. Replace them if they show signs of Strainers are your best defense wear. against nozzle or pump wear and nozzle Use nozzle screens as large clogging. Screen as the nozzle sizes permit. openings should be less than nozzle openings. Pump Roller and gear pumps provide a volume of spray at a low to They are moderate pressure. Powder self-priming in most equipment. formulations should not be used In gear pumps. moderate J-4 Strainer Control Valves These valves should be chosen in a size They that does not restrict flow. should be easy for you to reach. On-off action should be quick and positive. Pressure Pressure Fkgulators Gauge These gauges serve a3 the pressure They monitor for the spraying job. must be accurate and should be designed to function over only the range needed Check frequently for for your work. accuraoy . Hoses Select synthetic rubber or plastic hoses that have a burst strength greater that the peak operating pressures of the pumping system being The hose must be able to resist used. damage from solvent3 present in Suction hose3 must resist pesticides. collapse; they should be larger than Replace hoses at the pressure hoses. first sign of wear. Pressure Gage NOZZLES The nozzle is one of the most important part3 of a sprayer. The nozzle helps control the rate, droplet size, uniformity, coverage, and safety of the pesticide application. Nozzle performanoe is the key to effective and Hose Pressure Regulators The pressure regulator should have a working range that is about the same as the range of pressure you plan to u3e. efficient performanoe of the entire sprayer systm. Eight kinds of nozzles are dluouauad in the followlr@ sections. 7-5 Streglpl These nozzles are used in handguns to spray a distant target. They are also used to treat cracks and orevioee fn buildings. Other uses Include thinline basal application and soil-active herbicide spot application. E.&at Fan There are three nozzles : types of flat fan .The regular flat fan nozzle makes a narrow, oval pattern, with lighter edges. This nozzle Is used for broadcast spraying, usually with an overlap of 30 to 50 percent for even distribution. ‘The even flat fan nozzle produoes a This uniform pattern across its width. nozzle is used for band spraying and treating other surfaces. ‘The flooding nozzle makes a wide-angle flat spray pattorn. This nozzle works at lower pressures than the other flat The flooding nozzle has a fan nozzles. fairly uniform I~attern across Its width. There are two nozzles : The whirl chamber. circular with or no spray in cone nozzle is foliage. types of hollow cone core and disk, and the The spray pattern is tapered edges and little The hollow the oenter. used mostly for spraying This nozzle produces a ciroular pattern. The spray Is fairly well distributed throughout The solid oone nozzle spraying foliage. the pattern. is also used for Offset These nozzles lack the uniformity of the flat fan, but can provide reasonably uniform coverage over wide areas. They are often used to control weeds along roadsides, ditchbanks, and in some forestry ground sprayers. There are many specialized spray nozzles and tips. For aerial applications there are the &&&QQ, plow hro& Valve nozzles, !zF- . T Broadas!i This nozzle forms a wide, flat, fan pattern. Broadcast nozzles are used on boomless sprayers and to extend the effective swath width when attaohed to the end of a boom. Atomizing &out No&.e Tin mbers Nozzle tip numbers are somewhat uniform among the various manufacturers. Generally, the first two numbers refer to the angle of spray discharge for numbem) refer flat tips. The last to the gallons per minute of the nozzle t.~;b~~,#O&i. For example, nozzle tip a nozzle tip with a 75 degree: angle discharge and delivering of 0.058 gpm at 40 psi. The decimal point is placed by counting three figures from the left to the right, i.e. a Tee Jet 6005 tip delivers 0.5 One exception to the above is for em angles 100 degrees or more. Nozzle This nozzle oreatets a fine mist from liquid pesticides. Atomizing nozzles are used indoors in special. Fine spray droplets are situations. created so drift oan easily beoome a problem. Other nozzles and their uses are described in spray equipment catalogs. You can get nozzles in many materials. All the materials should resist abrasion and corrosion for planned ter Ncgzleg are used either with a boom or at the end of booms to extend the effective swath width. One type is simply a large flooding deflector nozzle that will spread spray droplets over a wide swath. Cluster nozzles are a combination of a oenter-discharge and two or more off-center disoharge fan nozzles. The spray droplets vary in size from very small to very large, so drifting can be a problem. Some of these nozzles use only off-center tips, which produce rather large droplets, so drift problems are less. The main feature0 of applioations. five materials are discussed in the following sections. Brass : -Inexpensive -Wears quickly from abrasion -Probably the best material for limited use -Works well for most forest pesticide uses 7-7 Stainless steel: -- This equipment dry uniform particles to soil or water. This equipment is available in three types -- hand, ground or aerial applicators. Granule.aDDlioatom. aPPlleS coarse, -Fairly expensive -Will not corrode -Resists abrasions, SSPeCially if it Is hardened & n. --These sprayers are often called mist blowers. They are characterized by high velocities and a somewhat lower water volume than conventional air-blast sprayers. Extreme caution must be taken to avoid drift. LOW-Y- Plastic : -Inexpensive -Resists corrosion and abrasion -Can swell when exposed FlrJmo peotioide solvent0 to m m ~PTB~BTS. This equipment applies the chemical Extreme caution oonoentrate directly. must be taken to avoid drift. Aluminum: -Resists some corrosive materials -1s easily corroded by some fertilizers -Wears rather quickly from abrasion. Tungston carbide and ceramic: -Highly resistant and corrosion -Expensive to abrasion Some other equipment includes wiper applioators, roller applicators, etc. These types of equipment are continually increasing in use as viable applioation methods. SOIL FUMIGATION EQUIPMENT The equipment needed for applying aoil fumigants depends on the kind of fumigant being used. There are two kinds of fumigants: Nozzles must be kept in good working condition for aocurate application. 1. OPERATION AND MAINTENANCE Always read and follow the operator’s manuals for all spray equipment. The manuals will tell you exactly how to use and care for each piece of the After each user clean and equipment. Clean the rinse out the entire system. Wear nozzle tips and strainers. appropriate protective clothing and use suitable materials while cleaning or making repairs. - Soil variety fumigant inches covers in the OTHER TYPES OF EQUIPMENT Fonrters, mist bloW8r9. and aerosol watorg. -- These devices break the pesticide liquid into very small droplets. The large number of particles is visible as a cloud of Extreme caution must be taken as fog. aerosols, mists, and fogs easily drift from target areas, often for miles. Low-pressure (low-volatility) liquid fumigants. These fumigants usually use the soil itself, or water, to keep the fumigant from vaporizing and moving off target too quickly. Some of the methods used are: injection. -- This method uses a of devices to insert the into the a011 (usually 6 deep or mo1.e). The device then the area with soil again to seal fumigant. - Soil incorporation. -- This method is used to apply low-volatity fumigants. The fumigant usually is sprayed onto the soil surface. The area is immediately cultivated, usually to a depth of 5 inches or leas. 2. 7-8 Highly volatile fumigants. These ohemlcals remain as liquids only when placed under pressure. Effective application of highly volatile fumigants depends on tightly the soil with tarps, plastic similar covers. clean, and in good working conditior,. There are many kinds of application equipment, all differing in details of However, if you understand operation. the basics of calibration, you can apply this knowledge in any situation. Also, always read the equipment manufacturer’s instruction3 before beginning calibration. sealing film, or There are two major methods of using vapor-proof tarps: - Tarp supported off the ground and sealed around the edges; a fumigant is put under the tarp. Calibration is not a difficult process. Almost everyone can do the simple arithmetic without any problems. You can do the job even faster if you have a pocket calculator. - Tarp applied to the soil by the injection chisel applicator immediately after the fumigant Is injected. Rate Highly volatile fumigants must be handled in closed, preosurized containers or tanks, and extreme care must be taken during application to ensure safety for the workers. To determine the pumping rate of your sprayer, fill the tank to a known level with water. Set the spray pressure at and allow the unit the deoired level, to spray for a few minute3 to remove all air from the system. Then check the pressure again while the unit is spraying. Collect the spray in a bucket or drum for about 5 minute3 or refill the tank to the original level, measuring the gallons required. The reason for timing this step at 5 minute3 or more is to get a more exact measurement then you would get by trying to measure for only 1 minute. Divide the gallons collected (or used to refill the tank) by 5 minutes to determine the pumping rate. SEED TREATERS Seed treaters are used to coat seeds with a pesticide. The three basic type3 of commercial seed treaters are: 1. Dust treaters 2. Slurry treaters 3. Liquid treaters CALIBRATION Calibration is the p!*ocess of measuring and adjuuting your equipment to apply the dcuired rate of pesticide. Proper culibratlon 1: II~~~LI:w~, but too often iu neglected or done in haste. If too much pesticide is applied, the labeled amount may be exceeded. The result is excessive costs, illegal residues, possible danger to the workers and the envilaonment, and lawsuit3 or fines. At the other extreme, too little pesticide can result in inadequate control, and the added covt of having to re-do the job. Only by correct calibration can you safely and consiotently get the best results. Example : r m 5 minutes = 4 gallon3 minute per You may also determine the rate for each spray trip by following the above method. Field Spraver Calibration If you know the pumping rate, speed and width of the spray equipment, then the rate per acre is easily determined. Before you begin any calibration procedurea, carefully check all the equipment to be sure all components are One method of calibration is ohown below, but there are many others. The 7-9 facts are: . you must know for this -- 1 acre = 43,560 ..I The distanoe the sprayer 1 minute at an established -- The width -- The rate square or method feet. ., in spaed. UK&$ of the spray. Example #la of the spray. The spray tank holds 200 gallons and you wish to apply 1 gallon of formulated product on each acre. You have already determined that the sprayer applies 20 gallons per acre. First, find the number of aores one Divide 200 gallons tank will spray. (oapaoity of tank) by 20 gallons per dlore, Example Xl Suppose the width of the spray is 20 feet, and the distance oovered la 440 feet in 1 minute, and the spray rate iS 4 gallons each minute. Figure the area the sprayer covered 1 minute (distance x spray width). 440 feet per minute x 20 feet 8,800 square feet per minute. in 20 gallons a = 10 acres swam 8,800 = about feet square 5 minutes Der acre feet per minute Let’s, suppose the formulated product contains 4 pounds aotive ingredient per gallon and you want to apply 2 pounds Again a of votive Ingredient per aore. tankful covers 10 acres. per acre how much pesticide tQ put in ‘, You know now how many gallons, o@’ &jr&$’ per acre your equipment can apply,’ determine how +#4h’ ,I; (20). Next, pesticide to put into the tank to &ppi$ the correct rate of material. Flora 8re two more facts you need to know: ’ -- How many gallons the sprayer tank holds. -- The amount of formul.ation to be used per acre. per tank. Example #I b Then, figure the amount of spray per 4 gallons per minute x 5 minutes acre: per acre = 20 gallons per aore. Determine the tank: Der tij& per aore Then find the total amount of formulated produot to be added to the tank by multiplying 1 gallon per acre times 10 aores per tank = 10 gallons. Then calculate how many minutes it Divide would take to spray 1 acre. 43.560 square feet per acre by 8,800 square feet per minute. !.%560 -- The amount of aotive Ingredient per gallon of formulation and the amount of active ingredient to be applied per acre. : ,, , : First, determine how much formulated product is in 1 quart. We know there i$ 4 pounds of active ingredient in 1 @lion and 4 quarts in 1 gallon; therefore, there are 4 pounds in 4 quarts, so there is 1 pound in each quart. ‘. ~ i.\ < *, *i I 1i.‘,~,.<, ‘, : ‘. ,, ,. xi’;4,,+a‘.. ,, ; ,., =- 2 quarts r,’ :‘, ---i-$% .’ ,_ j .‘I’, mouse you want to apply 2 pounds of :‘-.:“!4Otive ingredient (2 quarts) per acre, *ltiply 2 quarts times IO acres per ,, ful. r.& quarts x 10 acres per tankful = 20 quarts or 5 gallons per tankful to achieve 2 pounds of active ingredients per acre. can increase ma. 2 In this example, active ingredient wettable powder, double (4 pounds) 2 pounds of active Changing -- if the 2 pounds of were a 50 - percent then you wouid have to the product to apply ingredient per acre. the Delivery Rate If the sprayer delivers more (or less) than the desired rate per acre, you can change the rate by basically three methods : from 20 gpa to 40 Change the speed of the sprayer. A slower speed means more spray A faster speed will be delivered. means less spray will be delivered. If the speed is doubled, the spray rate per acre is cut in half, or if the speed is decreased by one-half, the rate per acre will be doubled. Example Traotor speed decreases from 4 mph to 2 mph, so the rate per acre can be increased from 20 gpa to 40 ma. Change the pump pressure. Lower pressure* of course, means less spray volume, and higher pressure This means more spray delivered. method will change the spray tip pattern, which includes the spray The pressure must be width. increased 4 times to double the output, or decreased 4 times to cut the output in half. Change the larger the more spray course1 the less spray nozzle spray tips. The hole in the tip, the delivered and, of smaller the hole, the delivered. Calibrate a granular the same procedure, granules. Example If the pressure increased from 20 psi to 80 psi, the spray volume 7-11 applicator with but weigh the SELF TEST AND ANSWERS 7-13 LEssoN Self-Test 1. You would expeot spray drift a. b. c, d. The The The The 2. The higher ---- ..-- _ __ - a. b. c. d. wind wind wind wind the sprayer inoreases deoreases increases decreases pressure and and and and when which oondition spray spray spray spray droplet droplet droplet droplet. size size size size exists? increases increases decreases decreases -- The larger the droplet size The smaller the droplet size Droplet size remains the same Output is reduoed 3. In terms of drift pressure. - speed speed speed spped to be greater oontrol, nozzle tips are as important as the spraying a. True b. False 4. When selecting - a. b. o. d. a pump, you should oonsider The The The All -- ability of the pump to resist corrosion and excess wear range of operating pressure for your work capacity, in gallons per minute or per hour. of the above 5. Match these: I_ - a. Piston pump b. Roller pump c. Centrifugal pump 1. Moderate volume at low to moderate pressure 2. High volume at low pressure 3, #f&h pressure. 6. The pressure - - of a spraying pressure in a system. unit is -- a. Pump b. nozzle 0. regulator d. In-line strainer 8. Which of these nozzles spraying? ___ the required a. False b. True 7. The heart - guage maintains would be used in overlapping a. even flat fan b. regular flat fan - 7-14 groups for broadoast c. full cone solld stream d. 9. Hatch the following: - & #a 1. Evan flat fan 2. Hollow cone 3. Broadcast Y 4. Solid -tb -I:e - #c .) 1’ ? - stream 5. Regular flat fan 6. Solid oone 7. Flooding nozzle #d .._ +F---#fit 7-15 10. There are type8 of flat several makes a flat Which picture oval pattern shows this --11. Which nozzle II_ - light regular t’lrrt The regular flat fan nozzle edges. pattern’? a -b type would be more accu 8.it.e !?or aiming at distant targets? a. Solid strea b. Flat fan c. Cone 12. When choosing __ ___ fan nozzles. with a. b. 0. d. nozzle n,nt~rial you shc.tilG consider -- Abrasion Corrosion cost All of the above 13. Match these: __ _____ .___ -- 14. a. b. c. d. e. Brass Stainless steel Plastic Aluminum Tungston carbide and cermic 1. Can swell when exposed to some 531 verltx rL. gc,t u* t .Yil&i for extensive 1’“. :”,: it qs abrasion ,i,*!.+. .)..I: for limited 3. 2; US&, y ?*“:‘aa3 forestry applications. 4. Corroti;d b J *dame fertilizers 5. Ex;. raoL v4 Nozzle tip numbers are fairly standard among the different manufacturers. The first two numbers refer to the angle of ‘:pray dircharge. The last number@ refer to the gallons per minute that can ;‘1,2 :: ; IL -&I? I;he nozzle at 40 psi. A nozzle tip with this number, 630082, means ---- a. A nozzle tip b. A nozzle tip .0082 gallons c. A nozzle tip .82 gallons d. A nozzle tip 0.082 gallons with with a 82 degree a 63 degree ang1.e of fan d-‘scharge angle of fan discharge with a 6.3 degree angle of fan discharge per minute. with a 63 degreo angle of fan discharge per minute. 7-16 delivering and delivering and delivering tip 15. A nozzle -- a. b. o. d. with number produaes a. b. c. d. Change Change Change All of 18. You aan double --- -- large spray droplets, so drift should not be of a. True b. False 17. Whioh of the following __ L - 350150. 150 degree angle of discharge 35 degree angle of discharge and dellveringQ.150 g.p.m. 35 degree angle of discharge and delivering 15 g.p.m. 35 degree angle of discharge and delivering 1.5 g.p.m. 16. A mist blower aoncern. ___ _- tip will ahange pestialde appliaatlon rates? sprayer pressure. in spray tip size. in applicator speed, the above. the sprayer output by: a. Cutting sprayer pressure in half. 2 times. b. Inareaslng sprayer pressure a. Inareasing sprayer prossure 4 times. 19. A sprayer is calibrated miles per hour. 4 were slowed to 2 miles a. b. ---.-_ - c. 7.5 30 20 to apply 15 gallons per aare (gpa) What would be the appliaatiod rate per hour? at a speed of if the sprayer gpa. gpa. gpa. 20. A sprayer is calibrated lo apply 15 gallons per aare at a pressure of 20 What is thu pressure required to lnoreaee the output to 30 gallons per pd. acre without a ohange In speed, or spray tip siee, -- ___ 21. a. 40 psi. 10 psi. a. 80 psi. b. The spray direotions required 8 gallons of a herbiaide spray solution. If you only wanted to mix 50 gallons how many gallons of the herbialde would be needed? __ a. 2 gallons. b. 3 gallons. c. 4 gallons. 7-17 for a 200 gallon of the spray solution, 22. You want to apply 1 l/2 gallons of a pesticide per acre in 25 gallons of water. How many gallons of the pestioide would you need for 30 acres? ___ __ __ 50 gallons. b. 45 gallons. 0. 15 gallona. a. 23. The spray rate 200 feet in 2 -c. is 3 gpmc the epray width is 40 feet, and the sprayer What is the spray rate in gallons per acre? minutes. a. 40. b. 20. 33. i-18 travels 1. c 2. b 3. a 4. d 5a. b. 3 1 2 f. g* 3 7 10. a 11. a 12. d 6. a 13a. 3 b. 2 1 dc: 4 e. 5 7. a 14. d 8. b 15. b 9a. 4 16. b b. C. 5 1 d. e. 2 6 C. 17. d 18. c 19. b 20. c 21. a 22. b 23. c TE PESU PB!JQS”. Sti&XL$ AND SLUQS) The most important So the first step to control. step in solving any problem is to understand in your job is to recognize the invertebrate the cause. pest you need There are hundreds of thousands of different kinds of insects, mites, spiders, ticks, snails and slugs, but only about 100 species that do muoh aids, pictures , and publications help to identify damage. Identification these pests. B. m YOU m TO UNDEBQTJfl How well do you know some of the terms that are important in the use of pesticides? Test your knowledge of them by writing down the definitions the terms below. To check your answers, refer to the glossary. 1. Larva 2. Pupa 3. Nymph 4. Metamorphosis 8-1 for . 6. Acaricide 7. Miticide 8. Mollusciclde 9. Threshold c. - flowers, and, - oarry plant disease agents. INSECTS The plants can be damaged, weakened, or This causes reduced yields and killed. lowered quality. Even after harvest, insects may continue their damage in the stored or processed products. Insects also feed on and In man and other animal 9. Some of these pests spread diseases which have killed millions of people and animals. ANTE Not all insects are pests. Some help us by doing suoh things as pollinating plants or feeding on other insects that are pests. Insects thrive in more environmente than They live any other group of animals. on the earth’s surface within the soil and in water. They survive In deserts, rain forests, hot springs, snow fields, and dark caves. Many types of insects affect crops. They cause damage in a variety of ways. They may: - feed on leaves, tunnel or bore in stems, feed on and tunnel in roots, feed on and in seeds and nuts, - suck the sap from leaves, stems, roots, fruits, and 8-2 Inseots have two things in common--they have slir jointed legs and three body region3 - head, thorax and abdomen. How from another? can you tell one insect The most important parts to look at are the wings and mouth. Some insects have no wings. Others have two OF four. The wings vary in shape, size, thiokness, and s tt-uc ture. Insects with ohewing mouth-parts have toothed jaws that bite and tear the food. Insects with piercirg-sucking mouth-parts have a long “beak” which they force into a plant or animal to suck out fluids or blood. The marks left by insect, feeding, and the resulting damage to plants and animals, often provide reliable clues that help identify the pest. A specialist in this field should be consulted if you need help to identify an insect or insect-related problem. You may be able to secure this assistance from your Region’s Forest Pest Management (FPM) staff, State Forester’s (FPM) staff, extension or Farm Bureau specialists, colleges, etc. Almost all insects change in shape, form, and size during their lives. change is called metamorphosis. Some insects change only develop. The adult lays develop into nymphs. of wings is leathery. - Chewing mouthparts - Young and adults look alike, but the young lack developed wings. - Grasshoppers usually feed on plant leaves and stems. - Crickets are found in the field or indoors. They eat almost anything made from plants. - Cockroaches often live in restaurants, houses, stores and offices. They eat the same foods aa people. This in size as they eggs, which A nymph, which looks like a tiny adult, hatches from the egg and goes wingless through several molts before becoming an adult. Some insects change form slightly. Their nymphs, which have no wings, go through several growing stages. They then change into winged adults. Other insects change completely. They ’ go through four stages. The larva hatches from an egg. It Is a worm, caterpillar, grub, or maggot. This is the stage in which these insects grow the most and often do the most damage. Whtrn ft11 1-gt’r)wn, thcr 1arva chtrnges jnto Lhlr~.lrlg 1h.l :4 r%KiLlng cL&ge 11, il pup1. The adult stage changes into the adult. usually has wings. True Bugs - Some have wings; some do not. The top pair of wings is part leathery and part transparent. - Piercing-sucking mouthparts. - Young and adults look alike, but the young lack developed wings. - Suck the juice from plants, and blood from man and animals. - Reduce the vitality and yield of plants and animals, and may carry plant and animal disease agents. Here are the insect groups that include many of the insects that humans consider pests. You should study the characteristics of each group. -1 Termites - Swarming termites have four wings of equal size and shape; other termite.’ are white and have no wing3. - Chewing mouthparts. - Young and adults look alike. - Usually feed on wood products such as fence posts, timbers, and flooring. - Damage to the wood in homes and other strut tures is common. _ -* ? Grasshoppers, crickets - Some have wings; fully developed and cockroaches some do not have The top pair wir4;s. 8-3 and in some cases, produots. / Aphids, Leafhoppers, Scale Insects Bees, Wasps, Ants and Sawflies Flies - Adults usually - animal Spittlebugs, and and Mosquitoes - Adults have only two wings (other winged insects have four). - Mouthparts of adults are piercing-sucking, but may be slightly modified for sponging, rasping, or cutting. - Young (except mosquitoes) are maggot::. - Head of young usually not well-defined; mouthparts are small, dark, and hooklike. - Young mosquitoes live in water. - They have a well-developed head, with chewiN: mouth-parts. Beetles - and - Some have wings; some do not. - Piercing-suoking mouthparts. - Young of aphids, leafhoppers, and spittlebugs look like the adults. - Adult scale insects are scale-covered and stay in one place on the plant. - Nymphs may damage leaves, stems, roots, fruit, and cloth. - Suok the juices from plants. - Reduce the vitality and yield of plants. - Some carry plant disease agents. - Most adults have a narrow waist; sawflies are an exception. - Some have four wings; some have none. - Chewing mouthparts. - Most young are wormlike, with no legs. The young of sawflies look like caterpillars. - Young are usually found in nests made of soil, mud, paper or wax. - Painful stings from many adults make some of these a pest. Other3 may damage wood products. - animals have two top wings that are hard and shiny; the bottom wing3 are transparent. Chewing mouthpartn Young are grubs or worms Some young have no legs; others have SiX. Young and adults are found on plants, in soil, and in wood buildings. Both the adult and larval stages may damage stored food products, plants, 8-4 . . - Maggots usually feed on plant seedlings and roots, in organic matter, in water, and in other damp places. - Some maggots feed on animals. - Some adults carry disease agents. Mites Adults and nymphs have eight legs; larvae have six, Very small--about the size of the period at the end of this sentence. No wings Injury they cause usually is noticed before the mites are found. Sucking mouthparts. Soft-bodied. Some mites make thin webs on plantz. When present on plants in large numbers, their feeding turns foliage and buds whitish, reddish, or brown. Some may scar fruit. On animals, they cause severe skin irritation, redness, scabs, scaliness. Chiggers (also called red bugs) arc, mites that attack humans. Moths and Butterflies - Most adults have four large wings with many scales that rub off easily. - Most moths are dull brown; butterflies are brightly colored. - Mouthparts of some adults are lacking or are a coiled tube used for sucking. - Larvae are caterpillars, usually with six joined legs and 10 soft, fleshy parts that look like fat legs. - Larvae have chewing mouth-parts. - Larval stages may damage leaves, stems, tubers, fruit, and cloth. MITES, TICKS and SPIDERS WFaw e Mites, ticks and spiders rival the insects in number of species and in the variety of places they live. They live on the ground in ( terrestrl al 1, in the water (aquatic), the soil, and in organic debris, where they usually outnumber other arthropods. Many mites and ticks are parasitic, at least during part. of their lives; others are free They are annoying pests and some 1!virg. Spiders rarely bite transmit diseases. people, but a few are very poisonous. Ticks - Adults and nymphs have eight legs, larvae have six. - Leathery or soft body (sometimes colored) without a distinct head. - Piercing-sucking mouthparts with which they firmly attach themselves to the host animal. - Parasitic on animals, including humans. - Must have blood to complete thejr ljfe cycle. - Some carry disease agents to humans and animals . Mites, ticks and spiders are closely related to insects. The main differences are that the adults have &gU jointed legs instead of six and have two body regions. They do not have wings. The two body regions of spiders are separated by a slender stalk, unlike ticks. 8-5 Spiders - Eight legs. - Biting mouthparts. - Vary in length from a fraction of an inch to 5 or 6 Inches. - Useful because they eat lnseots, but their webs and exoretions may be a nuisance. - Blaok widow and brown recluse spider bites are dangerous to humans. SNAlLS AND SLUGS Qgg~n Featureg Snails have a hard shell, shell. Snails and slugs mouthparts. slugs have no have rasping Snails and slugs are members of a large group of animals called mollusks. They are among the most familiar invertebrate animal 9. They live in a large variety of habitats. They have invaded marine water, fresh water and land habitats. They serve as food for many other animals, including humans. Some land snails and slugs do extensive damage to crops and ornamental plants. Slugs attack both the aerial and underground portions of plants. They are pests in lawns, landscape plantings, and greenhouses. 8-6 SELF TEST AND ANSWERS a-7 . 1. Adult mites, = 1 tfoks and spiders have - a. Thrm pair al win&a. b. Four body rggiorts, c. Eight joint&i le&s. d. Noneof the above. 2. Insects differ from othm l nlml6 in - 1 - a. Swklnpl, ohawing, b. Six jofnted legi. o. ‘No body $eotiOm, d. Wo wings. tha follawlng charroterirtio - or biting muthpartr. 3. a3 Legd and antmn& 4‘ Ihsects grar the moat during whidh eWg@of thqir life crYoh-- I a. Larval -b. Pupal -0. Egs ii d. Adult 5. Snail8 anU &lugs cab be distlr@WW z 6. a. b. 0. d. = - brie another WWse - slugs have ILishell Md -i&r d6nft. Slugs and snails ibaa nostiy 611in#e&& Snrila are a mmber of the in0lWk graup of andmlr; SnUa have a shell and aluas dWt. Mites, tib<s, and spiders llirr, -- fm a. on the ground, and in ground b. ih the mter c. in o anio debris d. All o 7 the above sluga are not, , , . 7. One of the organisms z __ 8. and six jointed legs -- Sawflies Spider Mite Tick Ticks have -__ __ -. - 9. a. b. c. d. below has three body regions a. b. c. d. Suoking mouthparts Rasping mouthparts Chewing mouthparts Sponging mouthparts If you have trouble __ ---. es___ a. b. c. d. identifying an inseat, you should -- Apply a pesticide that is reoommended for a similar Seek the help of an expert. Ignore the problem as it will probably go away. None of the above 10. One of the following is t& an inseot relative pest. -- __ a. Ticks --- b. Sluga --_ o, Spiders __ d. Mites 11. An insect ahanges its -ohange is oalled __ --.- a. b. o. d. form when it develops Cyolloal alteration Trammutation Metabolic growth Metamorphoeia 12. A stage in which inoeotP usually do the moat damage -- . . U. Pupa --- b. Larva or nymph --co aa __ d. None of the above 13. An inseotls __ __ a. b. c. d. from an egg to an adult. Head, Head, Head, Head, three body regions thorax wings, wings, thorax and and and and are -- antennae legs abdomen abdomen 8-9 This 14. The larval stage for moths and buttwflicsa Sa oalled -- __ a. Caterpillars -_ b. Clusters __ c. Flyers -- d. Nymphs 15. Match the following: -b. ---- a. Acariaide Wwh c. Metamorphosis d. Pupa 1. Insect looks like an adult, but the win&s are not fully developed 2. Stage between the larvae and adult 3, Used to kill mites and ticks 4. An inasot change In shape, form, and size 3-10 JINSWERS- LESSON 8 1. 9. b 2. 10. b 3. 11. d 4. 12. b 5. 13. d 6. 14. a 7. 15a. b. 0. d. 3 1 4 2 8. a 8-11 A. - A plant disease is a condition in which a plant (host) and a disease-causing agent interact over time to the detriment of the host. This process may kill the plant; the plant may survive in a diseased condition; or the plant may recover. Biological agents (pathogens) that cause plant disease are of primary interest to pesticide applicators because these agents often oan be controlled with pesticides. Pathogens include: - fungi bacteria viruses and mycoplasmas, nematodes. and Parasitic seed plants are sometimes considered pathogens because of the type of injurious response they evoke from the host plant. How well do you know some of the terms that are important in the use of pesticides? Test your knowledge of them by writing down the definitions to the glossary. for the terms below. To oheok your answersr refer j” 1. Pathogen 2. Infection 3. Fungicide 9-1 ~~ 4. Fungicide 5. Host 6. Nemeticide 7. Vector . I . " . I. *bI.. 9-2 .I...... a*#..* PI.",. Three things are required before a parasitic disease can develop -COMMONFEATURES OF PLANT DISEASES Plant diseases are often two groups -- nonparasitic parasitic based on their divided and oause. into - a susceptible host plant, - a parasitic agent, and - an environment favorable to develop. for parasites ADULT BARK These diseases are caused by non-living agents. One-time damage, i.e., lighting, may injure a tree. Although such damage is not a real disease, injuries of this type are inclrided here. Other examples include: - nutri.ent deficiency, - extreme cold or heat, - toxic chemicals (air pollutants, some pesticides, salts, too muoh fertilizer), - mechaniaal injury, and - lack of, or too much, water. These diseases cannot one plant to another. EUROPEAN BEETLE FUNGUS 6 SPORES BARK BEETLE EGGS LAID IN DEAD YING ELM WOOD be passed from Pathogens that cause plant djseaeea are parasitic -- they live and feed on or in host plants, deriving nourishment and often protection from the host They can move or be moved from plant. one plant to another. The moat common oauuea of parafljtic dieeilsea are -fungi, bacteria, viruses, mycoplaamas, nematodes. THROUGH WAIER CONDUClfNG SYSTEM AN0 KliLS 1REE ’ EMERGING BEETLE PICKS UP FUNGAL DUTCH - ELM SPREADS SPOFES and Insects can cause symptoms similar to those of a prasitic disease, as can a few seed-producing plants and some microbes. 9-3 ELY Di8EAlE - Dl8LAIE CYCLE Fungi Fungi are plants that laok green color (ohlorophyll). They cannot make their own food, 30 thy get food by 1 Iv I no on Not all arc harmful , other organisms. many are helpful. All are microscopic, but many produce large fruiting structures such as mushrooms. Most fungi reproduoe by spores, which function much like seeds. Fungi may attack a plant both above and below the soil surf ace. Some fungi cause problems through wood rot or dlaooloration. Root rot and stem galls are other examples of fungus diseases. are easily oarried along in bulbs, roots, outtings, and seeds. Some viruses are transmitted when machines or workers touch healthy plants after touohing diseased plants. A few are transmitted in pollen or by nematodes, and, at least one, by a fungus. Myooplasma-like Organisms These living organisms are intermediate in size between bacteria and viruses. It has been discovered recently that they oause many plant diseases formerly thought to be viruses. These organjsms are veotored by insects. Bacteria c ,’ Bacteria are mioroscopia, one-celled plants. They usually reproduoe by simply dividing in half. Eaoh half becomes a fully developed baoterium. Bacteria oan reproduoe at a fast rate under ideal oondltions. Some can divide every 30 minutes. Often witches’-brooms, stem galls or leaf spota are oaused by bacteria. VOUNG ROOIS , ! Viruses Nematodes Viruses are nonliving oompounds, Even though they are nonliving, they are infectious. Once within the host, they produce more viral structures. They are so small that they cannot be seen with the unaided eye or even with an ordinary microscope. They gre generally recognized by their effects Many viruses that cause on plants. plant disease are vectored by inseots, usually aphids or leafhoppers. Viruses Nematodes are small, usually miorosobplc, roundworms, also oalled eelworms. Many nematodes are Others may attack crops and harmless. Some species attaok ornamental plants. the above-ground plant parts, such as But most leaves, stems, and seeds. species feed on or in the roots. Nematodes usually do not kill plants, but reduce growth and plant health. They may weaken the plsnt and make it susceptible to other disease agents. 9-4 The three main responses diseases are: All nematodes that are parasites on plants have a hollow feeding stylet (specialized mouthparts). They use it to puncture plant cell walls and feed on the cell contents. Nematodes may develop and feed either inside or outside a plant. of a host to - overdevelopment of tissue resulting in galls, swellings, or leaf curls, - underdevelopment of tissue resulting in stunting, lack of chlorophyhl, incomplete development of organs, etc., and - death of tissue as in blights, leaf spots, wilting, and cankers. Development of Plant Diseases A parasitic disease depends on the life cycle of the parasite. The environment greatly affects this cycle. Temperature and moisture are especially important. They affect -- Plant Diseases We cannot always tell one plant disease from another by looking at the symptoms on the plant. Because many diseases produce similar symptoms, we need other evidence, Identifying the cause is the best way to identify the disease. A microscope is needed to see such things as fungal spores, nematodes or their eggs s and bacteria. - the activity of the parasite , - the ease with which a plant becomes diseased, and - the way the disease develops. The disease process starts when the parasite arrives at a part of a plant where an infection can occur. This step is called Matlog. If environmental conditions are good, the parasite will begin to develop, This stage -- where the pathogen is aotive, but the host is as yet unaffected -- is called &M&&&L Invnaion Is the process of attaoking and penetrating living host material. L&@&g occurs when a food-based relationship is established between the host and pathogen. Us&#@ begins when the host to infection. renponda adversely 9-5 SELF TEST AH) ANSWERS 9-7 1. A nonparaaitfo plant disease a. a disease that -. _.-. b. a disease that another, can be pa%s%d from oae plant to an&her. oannot be passed from ohe plant to -m--w 2. Which of the following _.__ __-_I_ ___ 3. Fungi E --- a. b. C. d. oause parasitic plant &i%w%e% -- nematodes fungi viruses all of the above are plants that -- a. have chlorophyll b. live on other organisms c, reproduos mstky by seeds 4. Which of these are required --___ is -- a. b. o. d. before a parasltio di%%%se can develop a susoeptible host a parasitic agent a favorable environment all of the above 5. Nematodes -_--- a. b. c. d. are all harmful are easily diagnosed usually kill plants can reduce plant growth 6. Temperature and moistwe parasitfo diseases. __ - are r& and health f-tom in the development by insects. such as aphids. key a. True b. False 7. A nematode is -a. a nonparasltio disease -b. % one-celled plant -..-.- - c . a ssall roundwom or eelwom 8. Some plant I_ ___ diseases may be carried a. True b. False 9-8 of -- * . 9. Plant diseases pass through three stages. z - a. b. c. &. Inoculation, incubation and Induction Imubation, Invasion, and canpletlon Inoculation, Incubation, and lnvaslon Imxztiiation, frmubation and protection 10. Pathogens in&Me: Z - a. b. c. d. They are -- Nemfiades Fungi Baoterfa All of the above g-9 1. b 6. b 2. d 7. a 3. b 8, 8 I(. 9. 0 d 10. d 5. d 9-10 . A weed is any plant (i~%lUdlng a tree!) growing where it la not wanted. Weeds reduce crop yields, inoroests of pwlauotion, and reduce the quality ef crap and l$vesteok preduota~. In addition, mxaa weedo cause skin and OQRISare poisonous to liVe8tOCk and man. Irritation and hay fever, Weeds harm desirable - planks by: competing for water, nutrients, light and spaae. contaminating the product at harvest, and harboring pest inBoots, mites, vertebrates, or plant releasing toxic SUb8tarXes. disease agents How well do you know lome @f the ~~~a that are important in the use of pesticides? 'feet your know&@ rri: #Aem by writing down the definitions the terms below. h *eak y&.MarrclJlsD refer to Cbe glarsary. 1. Decidwur 4. Herbicide 10-l for 6. Translooated 7. Defoliant 8. Des&want 9. Allelopsthy 10-Z . DEVELOPMENTSTAGES of All plants have four development: stages - seedling plantlets. vulnerable -- small, - vegetative -- rapid growth; production of stems, roots and foliage. Water and nutrient uptake and movement is rapid. - mature -- little or no energy production or movement of water nutrients. and - seed production -- energy directed toward production of seed. Uptake of water and nutrients is slow and is direated mainly to flower, fruit and seed strua tures. Summer annuals are plants that result from seeds that sprout in the spring. They grow9 mature, produce seed, and die before winter. SOME COHMONFEATURES OF WEEDS To control something important their life weeds, you need to know about how they grow, An feature is the length of cycle. Plants with a l-year annuals. They grow and produce seed for generation in 1 year life cycle are from seed, mature, the next or less, Winter annuals are plants that grow from seeds that sprout in the fall. They grow, mature, and die before summer. lo-3 During the winter, they may lose their foliage and the stems of others may die baok to the ground. Some grow from seed. More often reproduaing by tubers, bulbs, rhizomes (below ground rootlike stems) or, stolons (above-ground stems) that produce roots. Established perennial weeds are more dlffioult to control, with herbicides, beoause of the large reserves of stored energy in the root system that can support life after treatment. rhlamer ml sto1onr. Plants with a a-year life cycle are biennials. They grow from seed and develop a heavy root and compact cluster of leaves the first year. In the second year they mature, produce seed, and die. Siaplo perannlrls mramlly reproduce by rmdr. But root pleoe8 mry produoe new plmt8. &itbUJS ~rWUlis;lS may reproduce by SC&, bublets, Or bulbs. Plants that live more than 2 years1 and may live indefinitely, are perennials. lo-4 ’ . year in both hardwood species. Terrestrial Plants Pest plants on land sedges, broadleaves, Aquatic include grasses, and woody plants. Plants Aquatic plant pests plants and algae. *asses. -- Grass seedlings have only one leaf as they emerge from the seed. Their leaves are generally narrow and Most upright with parallel veins. grasses have fibrous root sy:jtems. The growing point on seedling grasses is sheathed and located below the soil Some grass species are surface. annuals; others are perenni.als. Vascular include vascular Plants Many aquatic plants plants having stems, Most act and roots. plants - dying back dormant in the fall growth in the spring. generally classified se_Qges. -- Sedges are similar to grasses except that they have triangular stems and leaves in whorls of three. They are often listed under greases on the pestiaide label. Some herbicides control grasses are weak on sedges. and conife! are similar to land leaves, flowers, as perennial and becoming and producing new They are as: - emergent (emeraed) -- most of the plant extends above the water surfaoe. Examples are cattails, bulrushes, arrowheads, and reeds. - floating -- all or part of the plant floats on the surface. Examples are waterlilies, duckweeds, waterlettuce, and waterhyacinth; Boadleavey. -- Broadleaf seedlings have two leaves as they emerge from the seed. Their leaves are generally broad, with netlike veins. Broadleaves usually have a taproot and a fairly All actively coarse root system. growl.ng broadleaf plants have exposed growing points at the end of each stem Perennial and in each leaf axil. broadleaf plants may also have growing points on roots and stems above and below the aurfaoe of the soil.. Broadleaves can be speaies with annual, h I ccnnj 411, urNI yol*erlnl nl ‘I 1fl. rlyrll~rl, - aubmergent (submersed) -- all of the plant grows beneath the water surf ace. Examples are watermilfoil, elodea, naiads, pondweeds and coontails. Emergent and floating plants, like some land plants, have a thick outer layer on their leaves and stems which hinders herbicide abaorptlon. Submergent ~rlafrt,a hnvel I4 VlII’y ttr.fri !llll.~~l~ Iny-I’ ‘PII their leaves and sterna and oo are vul*y susceptible to herbicides. handwood and JiQQdY-Plants. -- Includes conifer species. Handwood species are usually broad leaf and deciduous. The plants are normally dormant during the winter, although root growth may begin before the leaves appear in the spring. Root growth may also continue past leaf drop in the fall. Conifers have needle or scale-like leaves and are usually evergreen, with foliage persisting for 2 or more year-s. Active growth (photosynthesis) can occur during mild periods throughout the winter months. Cambial growth lays down a new layer of woody mat,erJal each Algae Algae are aquatic plants without trut? stems, leaves, or vascular systems. For control purposes, they may be classified as: - plankton algae -- microscopic plants floating in the water. Many multiply rapidly and cause “blooms” in which the surface water appears soupy green, brown or reddish brown. 10-5 - filamentous algae -- long, thin strands of plant growth that form floating mats or long strings extending from rooks, bottom sediment, or other underwater surfaces. - a macroscopio freshwater algae -large algae that look like vascular aquatic plants. Many are to the bottom and grow attaohed tip to 2 feet tall; however, they have no true roots, stems, or leaves, 10-6 SELF TEST AND ANSWERS 10-7 1: Match the following: --- --__ -.- -2. a. Lives for b. Sprouts in and lives ce Lives for d. Sprouts in liven for Plants that often are called : ______a. ____ b. c. --_ __ d. 3. several years the spring for 1 growing season 2 years the fall and 1 growing 6eason. reproduce from tubers, 1. 2. 3. 4. bulbs, Biennial Perennial SumnJer annual Winter annual rh.i.zomes, or stolons Annuals Biennials Perennials Summer annuals A pesticide used to control brush and trees: ( ____ a. Avicide b. Piscicide c. Silvicide -4. As a rule perennial weeds are more diffioult annual. weeds bccauoc -- to control with herbicides in the spring than do perennial _- a. Annual weeds start growth earlier weeds. __ b. Perennial weeds are not sensitive to most pestioides. weeds have large reserves of stored energy that can -- -.- c. Perennial support life for a while after treatment. 5. Seedlings --_-- 6. 'I that have only one leaf as they emerge from the seed: a. Broadleaves b. Grasses c. Woody plants Plants that grow from seed, mature, in 1 year or less are: and produce .- - a. Perennial -_ b. Annual - .-.- c. Both of the above 10-8 sec:d for a new generation than 7. The direct chemical. that _- .-__ a. -.--- b. _. -.- c. __.._ d. 8. or indirect effeot of one plant on another through affect the growth of the other plant is called: Stm:tlar to grasses leaves -- Seedlings that except that they have triangular stems and three c plant:; have two leaves as they emerge from the seed -- ___ __ a. Broadleaf _ _._ b. Grasses -- .._ c. Sedges 10. Match the following on aquatic --- -_ a. All or part of ____ b. Grows beneath c. Aquatic plant --d. Most of plant --.- ‘:f i Allelop:: thy Cambral growth Germination Translocation ._ ._ a. parasitj -- -- b. algae c. sedges -_. 9. the productioo plants - the plant floats the water surface without a vascular system. extends above water surface lo-9 1. 2. 3. 4, Submergent Floaters Emergent Algae whorled lo. b, 2 3 6. : 7. 2. 0 a. 3. c 9. 4, 0 5. b lOa, b. 1 c. 4 d. 3 C. d. 10-10 YENXBRATE PESTS All animals have a jointed backbone. They include fish, snakes, alligators, lizards, frogs, toads, salamanders, birds and mammals. Vertebrate pest:i are sinlply animals whose presence or activities conflict with human interests and well-being. What may be a pest animal in some situations may be a highly delrirable animal in others. vertebrate turtles, How well do you know some of the terms that are important in the use of pesticides? Test your knowledge of them by writing down the definitions for the terms below. To check your answers, refer to the glossary. 1. Vertebrate 2. Predacide 3. Habitat 5. Mammals 6. Avic:Ide 11-1 7, Reptiles 8. Rodent 9. Rodenticide 10. Piscicide 11. Ecosystem 11-2 C. DJSC- Moat vertebrate animals are not peats. Many are a necessary and an enjoyable part of our environment. A few vertebrate animals can be peats in some situations. Some, auoh as birds, rodents, raccoons, and deer, may eat or injure forest trees, cropa, and ornamental plants. Birds and small mammals may eat newly-planted seeds. Birds and rodents consume stored food, but often contaminate and ruin even more than they eat. Birds and mammals such as foxes and coyotes, prey on livestock and poultry. In forestry reforestation activities, clipping and browsing of regeneration seedliq$ by rabbits, pocket gophers, deer, and elk are often serious problems. REPTILES AND AMPHIBIANS Reptiles (snakes, lizards, turtles, and and amphibians (frogs, toads., and salamanders) may cause local Although they may cause grobbem. little damage, many people dislike or can hew them. Snakes and turtles create many problems in fish hatcheries or waterfowl production areas. rlli(tator8) FISH People have caused most fish problems by putting some species where they normally would not have been. We consider some fJ sh to be undesirable because they are not useful for sport some undesirable or food. Moreover, fish compete with more desirable species. Some fish are intermediate hosts for parasites of man. BJRDS Bird damage is usually quite varied. It includes -- structural damage by woodpeckers, - destruction of feed, fruit, nut, grain, timber, and vegetable crops seed- and fruit-eating birds, - hazards to animal and human health caused by diseases spread by birds such as pigeons and parakeets, - annoyance caused by birds roosting or near dwellings. 11-3 by in Control of bird pests requires highly specialized knowledge and techniques. Nany birds are proteoted by State and Federal laws and regulations. Contact your county agent before you undertake any bird control program. MAMMALS Damage by mammals is rather varied. Some cause serious health problems to livestock and humans. Diseased mammals may transmit to humans diseases suah as rabies, plague, food poisoning, and tularemia. Killing of mammal3 is costly and in some instances, controversial. Some damage fruit , vegetables, nut, grain, range and tree crops, The damage they do to dams and ditches can be very costly. Mice and rats cost millions of dollars in damage each year4 How do you tell what mammal caused the damage? You can eliminate some suspects if you know -- which animals are found in your part of the country, - what kinds of places they live in, and - what their habits are. Exaeptions to this general rule are made for rats and mioe, which are usually overwhelmingly detrimental. Wild mammal and bird population3 are an important part of our natural ecosystem, but at times individuals of a certain ::pecies can trespass on human Interests. When a rabbit damages garden crop3 ( shrubs, or trees, it becomes a pest. When a ooyote or domestic dog kills sheep, jt hft~ofms a l.J abi1.l t.y. We rlhoul d k+tqJ in mind that any control direotrctl al. one regment of the ecosystem oan have For effects on other components, example, intensive predator control may lead t&s mt rabbit and rodent problems. The se1 ective control of problem pests, or preventing damage by nonlethal means tends to minimize effects on the total eoosystem. State and local laws may prohibit the trapping and killing of some animals such as birds, ooyotes, muskrats, and beavers, unless you have a special permit . Always check with local authorities before beginning a control program. Methods of vertebrate pest control include mechanical control, sanitation, These methods and ohemioal control. are reviewed in the following sections. Meohanloal control methods include traps, barriers, gunning, attractants, and repellents. Animal signs ( tracks, droppings, toothmarks, diggings, burrows, hair, and scent) plus the type of damage will give you more clues. CONTROLLING VERTEBRATES The objective of any animal damage control program should be to oontrol the damage and should be limited to offendI.ng pests or particular groups not to the species as a whole. Traps -Traps arc often used in vertebrate pest control. traditionally nonselective animals. location, pests are always be Sanitation Leg-hold traps have: been used, but such trap6 are and often injurt! nontarget Traps which, by design or quickly kill only target IDoro drsirable. Traps should checked daily. Removing sources of food and shelter can help to suppress some vertebrate pests. Sanitation techniques are more often used to oontrol rodents in and around homes, institutions, reatouranta, food-processing facilities, and other related areas. Barriers Barriers are designed to prevent pests from passing through. Exa~pi08 itEclud@ fences, screens e and other bmriers that cover openings, stop tunneling, Materials used and prevent gnawing. are sheet metal, hardware cloth, concrete, expanded nletal , etc. This approach is oftan l ffeotivo in oOntl3& of rodents, bata, and birds in structures. Gunning 1 Control Pesticides for rodent pest control usually are formulated in baits. The chemicals can be toxic in sufficient amount6 to humans, livestock, and other animals. Therefore, correct bait plsoa8ont is Important to control the peat wkils protecting nontarget SpWlOB. Thorough knowledge of the pea’s habits is important. (Shooting) Gunning, though selectiva, and time consuming. It combination with other l Gunning will ofton take predators not controlled toxic devices. Cou puticldas are available for pest oontrol, and luql raqulra special, local rmoqeraltr. The pesticides that are t%gt#kred for this purpose are usually used aa bait applications. m&uwdent i:+ a%pOn&v~ works hart b WW&. ““. I’“” larger by traps or vertebrate It is possible to use a broad-spectrum pesticide (a pesticide having an effect on several species) selectively; however, knowledge of the chemical anti area’s vertebrate species, along with their habits, is necessary. The program should also be carefully supervised. Attractam Techniques such as light and sound are used to attract pests to a trap. Predator calling is Yometimes a part of gunning efforts against larger predators. The chemicals used to control vertebrate pests include rodenticides, plsoiaides (fish), avicides (birds), and predaoideo (predators). An integrated pest management approach Js usually necessary for vertebrate pest oontrol, These materia1.s inolude a vut*foty of devices deslgned to keep pests frow doing damage. Automatia exploders, noise-makers, recordings of L;c8ra calls, moving objeots, and 1 i.ghtr are some of the repellents usrd. Another category of repellants is tht? nontoxic chemicals. These produce an undesirable taste, odor, feel, or smell. These may be applied to forest seedlings and other crops to protect from vertebrate pests. 11-5 * . , SELF TEST AND ANSWERS 11-7 1. Check a single feature that distinguishes or separates all vertebrates a. They lay eggs b. They bear live young - .-..- c. They are mm bloodsd d. They have baakhones -I -- 2. Mont pestiafdrs mntroJ 1@de ___ are towio only z - -- a. b. c. d. a. b. 0. d. rrsul,t&ng in L- oontrolllng natural IL wild rnfml systems when St -- a. poses a pub110 hqalth t&w&t b. oauses serious eootmPo lossen ct. beoomes d. all 6. Most ffsh an unbearabxo nm1isam6 of the above problems have been oaured a. Nature b. Birds oarry%.l& fish 0. People 7. Many birds _ __ methods am t&u Least negative improt oa relat6d All of the above - -- animal -- Maximum effect on the problem rspeoiea Minimum reduation of no&e problra! upsoies. - -- be* Bluegill fish Coyote Rattlesnake Honey bee 5. We should aonaider ___ ape&s is not a verbebrate 4. The most fc !*:.Lble oontrol - the a. True b. False 3. One of the following - to are proteoted a. True b. False by -- e#@! by State and Federal laws end regulations. -- 8. Match the following: --.--__ -_. ____ a. b. c. d. e. f. Avl.cide Reptile Habitat Predator Predacide Piscicide 1. 2. 3. 4. 5. 6. 9. When trying to identify you should know -__ --.---.---- a. b. c. d. e. 10. Increased a specific Feeds on insects and animals Place where an organism lives Used to control birds Used for control of predator Controls fish Snakes, turtles, and lizards mammal that the animals that live in your area the kinds of places in which they live their habitat their signs, such as tracks, dropplngs, all of the above. predator a. decreased .----- b. Increased --- -- u. no affect control often leads la oausing toothmarks., to -- rodent and rabbit problems rodent and rabbit problems on the rodent and rabbit problems 11-9 damage, etc. 1. d 7. 2. b 8a, b. oa d. 2 1 :: : 3. d 4. d 5. d 6. c a 3 6 9. 0 10. b Many of the words defj.ned here have additional meanings. here are related to pesticides, pests, and their oontrol. Absorption -- Acarlcide Adaptation --- Adjuvant A pesticide used to kill. The adverse effeats mites, spiders, from a one-time exposure. A substance added to a pesticide formulation or spray to make it work better. Examples : surfactant, emulsifier, penetrant, spreader, wetting agent, drift agent. Also called an additive. Adaorpt i on -- The process by which a material is held surface of a soil partiole or mineral. organic soils have a tendency to adsorb Compare this term to absorption. Allelopathy The direct or indirect through the production of the other plant. Avicide Benign -- -- A harmless Rioaccumulation Biochemical Bioconcentration so that the effect effects. A pesticide used to control pest birds. to only repel birds, not kill. Lumor -- -- Usually is designed growth. The storage of a chemical in some storage body, e. g. body fat, bone. A chemical or bound to the Clay and highly pesticides. effect of one plant on another of chemicals that affect the growth Two or more things acting together less than the sum of the individual -- Cancel 1ed -- and ticks. The process whereby repeated exposures to small amounts of a chemical make the platn or animal tolerant of very much. -- Antagonism given The process by whioh a pesticide is taken into a plant, animal, or the soil. plant absorption is through the leaves, stems, or roots; animals absorb through the skin, mouth breathing organs, stomaoh, or intestines. Compare this term to adsorption. -- Acute toxicity The definitions that can be used by a living depot in the organism. -- The process in which a pesticide becomes concentrated in plants or animals. The ahemioal lnoreases in concentration at each sucaeeding link in the food chain. A pesticide or use that is no longer registered as a legal use by the Environmental Protection Agency. Remaining stocks can be used by order of the Administration, EPA. Gl c Crur~inogen -- An agent that oaueee oanaer. Cat-cl nogenc?aJ 8 -- To give Carbamate -- A family of pesticides which are chemically similar. all attack a pest in the same way. Examples inolude oarbaryl (Sevin) and oarbofuran (Furadan) . Certified applicator -- Chfm i cnl Chronic nmfj rise to oanoers. %?~ey An individual who is oertified to use or supervise the uscS of a restricted-use pesticides oovered by her/his certJfioatlon. A fiolantJfio namrt forthe active j.ng.,*edient In H psotlcidr! l.hr~I~ I denti fies the chamloal , its r.~t~po~j t,Jon ~td/or* structure. -- -- The adverse toxicity efeots from many, many repeated exposures. Common name -- A simple name (compared to the ohemloal name) of a pestioide aocepted by the Pestloide Regulation Division olt EPA. A pestioide with two or more brand names may have the same oommon and ohemioal names, Compatible Two or more pesticides are said to be compatible if can be mixed, and one does not affeot the properties other -- Contaminate Corrosive Coverage Deciduous -- To make impure or to pollute; material, suoh as a pesticide, -- -- The spread of a pestiuide plant -- -- A plant Desiccant -- -- that lives two over an area. or more years and loses its leaves the winter. A pesticide that onuses the leaves of a plant TV fall without killing, or immediately killing, the plant. Generally used to facilitate q eohanical harvesti%. CQMpare Degradation the addition of an unwanted where it is not wanted. A substance that usually oontains a strong acid or base types of which may burn the skin, eyes , and damage certain spray tanks and other equipment. during De%01iant they of tks t0 off DeSiCOant. The breakdown of a complex ohemical into a less complex form; this process can result from the action of micr*obt?su or other agents. water, air, sunlight, A pestioide that promotes removal of moisture from plants or insects. Desicoants are used mainly for preharvest drying of aotively growing planta. 02 t Refers to the rate for a given area in pesticide application. Also, used as a consistent measure in testing to determine acute and chronic toxicities. Dosage is usually expressed in milligrams per kilogram (mg/kg) or parts per million (ppm). Dosage -- Dose-time relationship Drift -- -- The combination of how much ohemjcal how often the exposure occurs. The movement of a pesticide wind and air currents from intended for treatment. Economic threshold -- one is exposed to and spray or dust particles by target area to an area not the It is a point in pest infestation where the application of control measures would return more money than the cost of the control. Ecosystem -- The interaction their nonliving Emulsion A mixture in which one liquid is suspended (mixed up) as minute droplets in another liquid. Example: oil in water. Compare to invert emulsion. -- Environment -- EPA registration number-Food chain Foreign of the living environment. Our surroundings, including people and other animals, exist among them. organisms of an area and water, air, land, plants, and the interrelationships A number assigned by EPA to a pesticide when it is All pesticide labels must display this registered. -- that number. A phrase that describes how all living organi:ms are linked together and depend on each other for food. Example: Plant eaters, plant and meat eaters, or meat eaters. ahemical -- A chemical that cannot be used by a living organJ.am. The pesticide product which may contain one or more active ingredients, a oarrler, and other additives required to make It ready for sale. Fungi tide -- A pestJcJ.de used to kill CPA (g.p.a.1 -- Gallons per acre. CPM (g.p.m.1 -- Gallons per minute. Germination -- Beginning seed. of growth; fungi. as the beginning C-3 of growth from a Habitat -- Herbicide The physical -- A pestlolde Host -- The plant Ingest -- place where an organism used to kill affected by a pathogen In the establishment The precesses involved a host organlsm. Inorganic -- Those compounds that -- Inversion A pesticide -- (kg) used to prevent the of a disease carbon. or destroy IlW! insects. --- The water is diapersed in the oil rather the water.. Example is salad dressing. A unit of weight in the metric pounds. 1 kg equals 1~000~000 than the oil system equal in to about 2.2 -- Printed teohnical information about a pesticide that attached to or printed on the pestici.de container. Larva -- A young, growing inseot in the stage of its life that starts when it hatches from an egg and ends when it In this early stage, the immature develops into a pupa. insect is wormlike or grublike and usually does not look Many insects cause most or all of their like an adult. damage as larvae. LC 50 -- An expression of acute inhalation toxicity. lethal dose for 50 percent of animals tested. LD 50 -- An expression of acute oral and dermal lethal dose for 50 percent of animals -- toxicity. It is means It means tested. The movement of a substance downward or out of the soil the result of water movement. g-4 -WV mgs. Label Leaching in A condition resulting when the te!.perature increases with A normal condition elevation from the earth’s eurfaoe. without an inversion is when the temperature deoreases with elevation. During an inversion, the air does not rise or rises very slowly from the earth08 surfaoe” Emulsion Kilogram do not contain way takf? into A 11l1111 I J ) IIJVI!l’l,o~r”ll,r’ llrlIIlltll w.ll.11 I ll1’1W bwly IT)r, Illlln six jointed legs; may have twoI Pour, or no wings. Insecticide Invert plants. in a disease. or in some other -- -- utnvanted To eat, swallow, drink, digestive system. Infection [llr!fvtl or inhibit lives. as Liter A unit of volume in the metric more than one quart. -- Low volatile pesticide -Malignant A pesticide that temperatureis. tumor -- Mammals --- (mg) -- A unit equals -- Molluscicide -- Mutagen -- chemcial. Nematjcjde -- level mites. A pesticide used to kill and oontrol that One-hundred-fold mal’gj n-of-safety -- young with hair. milk; rise Most often to ohanges about 28,500 1 kg. slugs 39.37 mg and snails. (mutations). made by natural processes. a soil used to kill fumigant A synthf:tic rubber often offer protection against spray hoses. -- to about ohanges the DNA struoture. nematodes. used to make gloves and boots that for most pesticides; also used Any 1evc.l of chronic exposure to a chemical that no observable adverse effeot in test animals. The early stage In the development not have a larvae stage. Nymph -- Organic used to kill -- A chemical Naoyr~eno -- No-offoct at normal system equal A pesticide To give -- in the metric of weight in the metric system; l,OOO,OOO mgs equal one ounce, An agent Mutagenesis Natural quickly A cance!‘. A unit of length inches. Milligram to a little A change in the shape, form (or structure), and size of an insect from the egg through the larvae and pupa to the adult. -- Mitioide does not evaporate Warm-blooded animals that nourish their their skin Js more or less covered with Metamorphosis Meter system equal -- The safety factor to humans. Compounds containing given humans when translating carbon. C-5 of those produce:! Insects that animal do data Organochlorines -- Organophosphates Orifice -- A family of pesticides whioh all contain chlorine. They as compared to rarbamates or include chlordane, lindane, are chemically similar - they are generally very persistent organophosphates, Examples and DDT. -- A family of pesticides which are chemically similar - they al.1 contain phosphorous. They are generally less persistent than the ohlorinated hydrocarbon family, They act by Inhibiting a blood chemioal called cholinesterase. Examples include malathion, Diazinon, and parathion, The opening In a nozzle tip through wh.i.ch a liquid forced out as a stream or bro&en into a spray. Any diseauo-producl parasites. Penetration -- The ability entering. ng ol*giln 1::m. to get through Mo:tt leaf, g:dt.tqp?n:+ stem, etc.; Perennial -- A plant that normally lives Examples: Shrubs and trees. Pesticide -- A chemical substance, compound, or other control, destroy, or prevent damage by, something from, a pest. Phytotoxicity -- Piscicicle Pups -- (injurious) the process of more than 2 years. agent or’ used to protect to plants. used to kill fish. A chemical that is aoutely toxic (LD 50 of 50 qg/kg or less) -- Predacide Barmful A pesticide -- Potable Predator UK*F A measurement scale used to express the acidity or alkalinity of a solution. Examples: a pH of 7, the value for pure distilled water, is regarded as neutral; a pH of 1 to 7 is in the acid range; and a pH of 7 to 111 is in the alkaline range. pn -- Poison for is water --- -- Water that A pesticide is suitable in very and intended used tc, cop?!roi for vertebrzte An insect or other animal that attacks, destroys other insecta c;r animals. small quantities. human consumption. predator feeds pests. on, and The resting stage of many insects. Hany pupae 3pend thi.3 period in cocoons, from which they r!merge a3 adulta. G-6 Registered peoticj des -- Reptiles A pesticide Protectjon container. Vertebrate animals that are cold-blooded and possess scaly Examples: snakes, turtles and lizards. skin. -- Residual pesticide A pesticide remaining in the environment for a fairly time; the pesticide may continue to be effective for weeks, or months. -- Residue -Restricted pesticide use -- A pesticide that FIFRA (Amended), applicator. A root-l Rodent -- Any animal squirrel.s, Rodenticide -- ike, A pesticide has been classified, under provisions of for use only by an appropriately certified underground Sensitization -- words -- The process something. in the order Rodentia. Examples : rats, beavers, woodchucks and gophers. used to kill or mice, rodents. repel by which a person -- to and VautiorP (for low order toxicity). The symbol ::kull and wossbones must appear on the labels of highly toxlo pesticides “Danger-Poison” 1. -- becomes allergic Words that must appear on pestioide labels to show how toxic the pesticide is. The signal words are: “DangerPoison” (for h.ighly toxic), “Warning” (for moderately toxic), of the Solution stem. Rebuttable Presumption Against Registration. A process used by EPA to Identify pesticides that present Qnreasonable adverse effects on the environment.” RPAR -- Silvicjde long days, The amount of pesticide that remains on or in a crop or Residues are animal or on a surface after treatment. usually measured in ppm (parts per million). Rhizome -- Signal that is approved by the U.S. Environmental Agency for use as stated on the label of the A pesticide used to kill (along with unwanted the words brush and trees. A combiration of one or more substances with a liquid in which the ingredients are completely dissolved without changing their chemical characteristics. These will not settle out or separate in normal use. Example: sugar dissolved in water. Compare with Emulsion and Suspension. Stage of development _- Time iadd period in its stages Stolen -*. Stylet -- during the growth from newborn Example: An insect goes through growth from and egg to an c?dul.t~; the of development. A horizontal branch from the base ol’ a plant.. A stolen produces new plants from buds at 11s t,ips also celled a nrunnern. A small, stiff, hyperdermic-like strltcture used by nematodes to pierce plant or ardml i.iaaue for the purpose of feeding. ~‘,uffJcient Sstaallenge The theory -- that exposure may stimulate making the body chemcials thereby Surfactant -- Suspended stranger. the ewul.M’ying, a pesticide, dispersing, A pesticide that is no longer legal; the rewnJ.ni.ng stocks Compare to Q’Cax~cell~:dw, which Is less cannot be used. Also to describes particles that. arca disgerszd or severe. heid but rot dissolved in a liou1.d. -- A pesticide A:oJ.id particles and Solution. -- fornulatjon dispersed The width of ground trip across a field Synergism to very small amoml,~ of EoreJgn th~3 hody t ,s d~ense meohanl szs, An adjuvant used to improve and spreading properties of -- Suspension Swath egg to many changes periods between OK' thood. -- When the combined greater than the cons3:.:t:Irsg o5 very finely divided in ;I I Jqui 11. Compar*e tcu Emulsion covered or other action of by A spr ryer when treated area. it of two or rn~~re pesticides their in~divlllual activity. sum makes one iu Synthetic chemical -- A chemical Systemic -- A pesticide that is taken up by one !XU% of a plant or animal and moved to another, section where it acts against a pest. Fxmgle : ;i sy::tf*mJc insecticsitle can bs applied to the soil, be taken up by a plant”s roots,, move into the and then contraol Irma!. :.z bfh*?~i t;hey f’(\c-d on thrn Icaves, 1 I?a v 6’R , Teratogen -- Teratogenesis Thresh01 d -- An agent --, To give made in that rise the laboratory mal.forared produces to malformed The highest no-effect 1 ine between no-effect babies or oft‘; industri.al apt*ings e (w~or~:>LersJ. level of“ a chew iical. and effect Je\Jflls of 68 plant. The djviding :I chemical. Tol.erarv?e -- The maxi num amount of pesticide that may remain jn or on raw agr2cultural products at the t,l.me of sale. Al so, the ability of an organism to withstand unfavorable conditions, such as pest attacks, extreme weather, or pesticides. Toxicology The science -- Trade name -- Vector plant -- Volatile Volatility One that moves within entered by some path. translocated. -- A plant phloem, A Carrie!,, Vertebrate ---- studies the harmful effects of chemicals. Same as brand name. The name given to a pesticide manufacturer to identify the product. Translocated pesticide -- Vascular that that that a plant or animal after it Systemic pesticides are has specialized conducting convey water and food. such as an insect, that An animai with a bony spinal column. fish, bil.ds, snakes, frogs or toads. Evaporates at ordinary Describes evaporates how quickly at ordinary temperatures cells, transmits by the has xylem, and a pathogen. Examples: when exposed mammals, to air. and easily a liquid or solid temperatures when exposed to air. c-9