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Table 4b
Discarded
commercial
chemicals
Description and Shipping Name
Ammonium picrate, wetted uniformly
with not less than 10 percent water, by mass
PIN
UN1310
Arsenic
Arsenic acid, liquid, or Arsenic acid, solution
Arsenic acid, solid
Arsenic bromide
Arsenic chloride, see Arsenic trichloride, etc.
ARSENIC COMPOUNDS, LIQUID, N.O.S.*,
including arsenates, n.o.s., arsenites, n.o.s.;
arsenic
sulphides, n.o.s.; and organic compounds of
arsenic, n.o.s.
ARSENIC COMPOUNDS, LIQUID, N.O.S.*,
including arsenates, n.o.s., arsenites, n.o.s.;
arsenic sulphides, n.o.s.; and organic compounds
of arsenic, n.o.s.
ARSENIC COMPOUNDS, LIQUID, N.O.S.*,
including arsenates, n.o.s., arsenites,
n.o.s.; arsenic sulphides, n.o.s.; and
organic compounds of arsenic, n.o.s.
ARSENIC COMPOUNDS, SOLID, N.O.S.*,
including arsenates, n.o.s., arsenites,
n.o.s.; arsenic sulphides, n.o.s.; and
organic compounds of arsenic, n.o.s.
ARSENIC COMPOUNDS, SOLID, N.O.S.*,
including arsenates, n.o.s., arsenites,
n.o.s.; arsenic sulphides, n.o.s.; and
organic compounds of arsenic, n.o.s.
UN1558
UN1553
UN1554
UN1555
TDG
Item No.
207
Class
4.1
Special
Provisions
10 46 48 58 99
Packing
Group
I
6.1
6.1
6.1
6.1
118
46 102 118
118
118
II
I
II
II
UN1556
275
276
277
290
291
292
6.1
9.2
46 48 94 109
188
I
UN1556
293
6.1
9.2
109 118
III
UN1556
294
6.1
9.2
109 118
III
UN1557
295
6.1
9.2
46 48 93 109 118
I
UN1557
296
6.1
9.2
109 188
II
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Table 4b
Discarded
commercial
chemicals
(continued)
Description and Shipping Name
ARSENIC COMPOUNDS, SOLID, N.O.S.*,
including arsenates, n.o.s., arsenites,
n.o.s.; arsenic sulphides, n.o.s.; and
organic compounds of arsenic, n.o.s.
Arsenic iodide, solid, see
ARSENIC COMPOUNDS, SOLID, N.O.S.*,
etc.
Arsenic pentoxide
PIN
UN1557
TDG
Item No.
297
Packing
Group
III
298
UN1559
299
Arsenic sulphide(s), solid, see
ARSENIC COMPOUNDS, SOLID, N.O.S.*,
etc.
Arsenic trichloride or Arsenic chloride
UN1560
302
Arsenic trioxide
UN1561
303
Arsine
UN1228
305
Barium cyanide
UN1565
337
Benzyl bromide
UN1737
380
Beryllium, powder
UN1567
392
Bromoacetone, LIQUID
Brucine
Calcium cyanide
UN1569
UN1570
UN1575
434
454
568
Camphene
Carbon bisulphide, see Carbon disulphide, etc.
NA9011
589
609
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Class
6.1
9.2
Special
Provisions
109 188
6.1
9.2
109 118
II
6.1
9.2
6.1
9.2
2.3
2.1
6.1
9.2
6.1
8
6.1
4.1
6.1
6.1
6.1
9.2
4.1
46 109 118
I
109 118
II
46 48 56 79 88
99 102
46 102 109 118
X
46 56 99
II
46 48
II
46 48 88 99 102
89
46 102 109
II
I
I
40
III
301
I
Table 4b
Discarded
commercial
chemicals
(continued)
Description and Shipping Name
Carbon disulphide or Carbon bisulphide
PIN
UN1131
TDG
Item No.
618
Chloroacetaldehyde
Copper cyanide
CYANIDE SOLUTIONS, n.o.s.*
UN2232
UN1587
UN1935
653
779
832
CYANIDE SOLUTIONS, n.o.s.*
UN1935
833
CYANIDE SOLUTIONS, n.o.s.*
UN1935
834
CYANIDES, INORGANIC, N.O.S.*
UN1588
835
CYANIDES, INORGANIC, N.O.S.*
UN1588
836
CYANIDES, INORGANIC, N.O.S.*
UN1588
837
Cyanogen bromide
UN1889
838
Cyanogen chloride
UN1589
839
Cyanogen, liquefied or Cyanogen, gas
UN1026
840
Cyanuric chloride
UN2670
841
UN1045
842
1400
Cyanuric triazide
Fluorine, compressed or Fluorine
Class
3.1
6.1
9.2
6.1
6.1
6.1
9.2
6.1
9.2
6.1
9.2
6.1
9.2
6.1
9.2
6.1
9.2
6.1
8
2.3
2.3
2.1
8
2.3
5.1
Special
Provisions
46 56 99 102 109
Packing
Group
I
99 102
46 102 118
46 102 109
II
II
I
102 109
II
109
III
46 102 109
I
102 109
II
109
III
46 48 56 90 99
102 118
33 46 48 56 79 88
98 99
102 118
I
X
X
46 48 56 79 88
99 102
III
46 48 56 88 99
102
X
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Table 4b
Discarded
commercial
chemicals
(continued)
Description and Shipping Name
Fluoroacetic acid
HEXAETHYL TETRAPHOSPHATE, liquid
PIN
UN2642
UN1611
TDG
Item No.
1401
1481
HEXAETHYL TETRAPHOSPHATE, liquid
UN1611
1482
6.1
HEXAETHYL TETRAPHOSPHATE, liquid
HEXAETHYL TETRAPHOSPHATE, solid
UN1611
UN1611
1483
1484
6.1
6.1
HEXAETHYL TETRAPHOSPHATE, solid
Hexaethyl tetraphosphate and
compressed gas mixtures
Hexaethyl tetraphosphate mixture, dry
(containing more than 2 percent
hexaethyl tetraphosphate)
Hexaethyl tetraphosphate mixture, liquid
(Containing more than 25 percent hexaethyl
tetraphosphate)
Hydrogen cyanide, anhydrous, stabilized or
Hydrocyanic acid, liquefied or Hydrocyanic
acid, aqueous solutions, with more than
20 percent hydrogen cyanide
Hydrogen cyanide, anhydrous, stabilized,
absorbed in a porous inert material
Mercuric acetate, see Mercury acetate, etc.
Mercuric ammonium chloride,
see Mercury ammonium chloride, etc.
Mercuric arsenate
Mercuric benzoate, see Mercury benzoate, etc.
UN1611
UN1612
1485
1486
6.1
2.3
NA2783
1487
46 48 56 99
102 118
99 118
46 48 56 93 99
102 118
99 118
46 48 56 88 99
102
55
NA3018
1488
55
UN1051
1544
2.3
2.1
45 56 79 84 89 99
102 118
X
UN1614
1545
6.1
46 48 83 99
102 118
I
6.1
118
II
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Class
6.1
6.1
Special
Provisions
46 56 99
46 48 56 94 99
102 118
Packing
Group
I
I
II
III
II
III
X
1772
1773
UN1623
1774
1775
Table 4b
Discarded
commercial
chemicals
(continued)
Description and Shipping Name
Mercuric bromide, see Mercury bromides, etc.
Mercuric chloride
UN1624
TDG
Item No.
1776
1777
Mercuric iodide, see Mercury iodide, etc.
Mercuric nitrate
UN1625
1778
1779
Mercuric oleate, see Mercury oleate, etc.
Mercuric oxide, see Mercury oxide, etc.
Mercuric oxycyanide, see
Mercury oxycyanide, desensitized, etc.
Mercuric potassium cyanide
Mercuric potassium iodide,
see Mercury potassium iodide, etc.
Mercuric subsulphate,
see MERCURY COMPOUNDS, etc.
Mercuric sulphate
Mercuric thiocyanate,
see Mercury thiocyanate, etc.
Mercurous acetate, see Mercury acetate, etc.
Mercurous bromide, see Mercury bromides, etc.
Mercurous iodide, see Mercury iodide, etc.
Mercurous nitrate
Mercurous oxide, black,
see Mercury oxide, etc.
PIN
Class
Special
Provisions
Packing
Group
6.1
56 102 118
II
5.1
6.1
9.2
109 118
II
6.1
46 102 118
I
6.1
9.2
109 118
II
46 48 89 109 118
I
1780
1781
1782
UN1626
1783
1784
1785
UN1645
1786
1787
UN1627
1788
1790
1791
1792
5.1
6.1
9.2E
1793
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Table 4b
Discarded
commercial
chemicals
(continued)
Description and Shipping Name
Mercurous sulphate
Mercury
PIN
UN1628
UN2809
TDG
Item No.
1794
1795
Mercury
Mercury acetate or Mercuric acetate
or Mercurous acetate
Mercury ammonium chloride or
Mercuric ammonium chloride
Mercury benzoate or Mercuric benzoate
Mercury bisulphate
Mercury bromides or Mercuric bromide
or Mercurous bromide
MERCURY COMPOUNDS, LIQUID, N.O.S.*
UN2809
UN1629
1796
1797
8
6.1
48 100
118
III
II
UN1630
1799
6.1
118
II
UN1631
UN1633
UN1634
1810
1811
1812
6.1
6.1
6.1
II
II
II
UN2024
1813
MERCURY COMPOUNDS, LIQUID, N.O.S.*
UN2024
1814
109
II
MERCURY COMPOUNDS, LIQUID, N.O.S.*
UN2024
1815
109
III
MERCURY COMPOUNDS, SOLID, N.O.S.*
UN2025
1816
MERCURY COMPOUNDS, SOLID, N.O.S.*
UN2025
1817
MERCURY COMPOUNDS, SOLID, N.O.S.*
UN2025
1818
Mercury cyanide or Mercuric cyanide
UN1636
1819
Mercury gluconate or Mercurous gluconate
Mercury iodide or Mercurous iodide
UN1637
UN1638
1820
1822
6.1
9.2
6.1
9.2
6.1
9.2
6.1
9.2
6.1
9.2
6.1
9.2
6.1
9.2
6.1
6.1
118
118
56
118
46 94 109
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Class
6.1
8
Special
Provisions
118
46 48 95
Packing
Group
II
II
I
46 93 109
I
109
II
109
III
46 102 109 118
II
118
118
II
II
Table 4b
Discarded
commercial
chemicals
(continued)
Description and Shipping Name
Mercury iodide, solution or
Mercuric iodide, solution
Mercury nucleate
PIN
UN1638
TDG
Item No.
1823
UN1639
1825
6.1
Mercury oleate or Mercuric oleate
Mercury oxide, or Mercuric oxide
or Mercurous oxide, black
Mercury oxycyanide, desensitized
or with phlegmatizer
Mercury potassium iodide or
Mercuric potassium iodide
Mercury salicylate or Mercuric salicylate
Mercury thiocyanate or Mercuric thiocyanate
UN1640
UN1641
1826
1827
6.1
6.1
118
118
II
II
UN1642
1828
6.1
46 84 118
II
UN1643
1829
6.1
118
II
UN1644
UN1646
1830
1831
118
109 118
II
II
Methylhydrazine
UN1244
1915
46 56 90
I
Methyl isocyanate
UN2480
1920
46 48 99
I
Napthylthiourea
Nickel carbonyl
UN1651
UN1259
1984
1992
Nickel cyanide
UN1653
1996
Nitric oxide
UN1660
2026
Nitric oxide and nitrogen tetroxide, mixtures
UN1975
2027
Nitroanilines (o-, m-, p-)
UN1661
2031
6.1
6.1
9.2
3.2
8
6.1
3
6.1
6.1
3
6.1
9.2
2.3
5.1
2.3
5.1
6.1
Class
6.1
Special
Provisions
118
Packing
Group
II
II
46 48 56 99 102
118
40 109
46 56 79 88 99
102
46 56 79 88 99
102
II
I
III
X
X
III
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Table 4b
Discarded
commercial
chemicals
(continued)
Description and Shipping Name
Nitrogen dioxide, liquefied or
Nitrogen dioxide, liquid or Nitrogen oxides,
n.o.s.* or Dinitrogen tetroxide, liquefied
Osmium tetroxide
Phenyldichloroarsine,
see ARSENIC COMPOUNDS, etc
Phosgene or Diphosgene
PIN
UN1067
TDG
Item No.
2055
Class
2.3
5.1
Special
Provisions
46 56 79 88 99
102
Packing
Group
X
UN2471
2157
2267
6.1
46 48 102 118
I
UN1076
2292
UN2199
2294
Potassium cyanide, solid
UN1680
2373
46 56 79 88 99
102
46 48 56 79 88
99 102
46 102 109 118
X
Phosphine
Potassium cyanide, solution
UN1680
2374
46 102 109 118
I
Propyleneimine, inhibited
Silver nitrate
UN1921
UN1493
2428
2551
46 48 56 84
48 109 110
I
II
Sodium azide
Sodium chloroacetate
Sodium chromate (RL-50)
Sodium cuprocyanide, solid
Sodium cuprocyanide, solution
Sodium cyanide, solid
UN1687
UN2659
NA9145
UN2316
UN2317
UN1689
2569
2578
2579
2580
2581
2582
2.3
8
2.3
2.1
6.1
9.2
6.1
9.2
3.2
5.1
9.2
6.1
6.1
6.1
6.1
6.1
6.1
9.2
48
II
III
I
I
I
I
6.1
46 48 56 93 99
102 118
Sodium cyanide, solution,
see CYANIDE SOLUTIONS, n.o.s.*
TETRAETHYL DITHIOPYROPHOSPHATE,
DRY OR MIXTURE
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46 102 118
46 102 118
46 102
46 102 109 118
X
I
2583
UN1704
2705
I
Table 4b
Discarded
commercial
chemicals
(continued)
Description and Shipping Name
TETRAETHYL DITHIOPYROPHOSPHATE,
DRY OR MIXTURE
TETRAETHYL DITHIOPYROPHOSPHATE,
DRY OR MIXTURE
TETRAETHYL DITHIOPYROPHOSPHATE,
LIQUID OR MIXTURE
TETRAETHYL DITHIOPYROPHOSPHATE,
LIQUID OR MIXTURE
TETRAETHYL DITHIOPYROPHOSPHATE,
LIQUID OR MIXTURE
Tetraethyl dithiopyrophosphate and gases,
in solution or Tetraethyl dithiopyrophosphate
and gases, mixtures
Tetraethyl pyrophosphate
and compressed gas mixtures
Tetranitromethane
Thallium chlorate
PIN
UN1704
TDG
Item No.
2706
UN1704
2707
6.1
99 118
UN1704
2708
6.1
UN1704
2709
6.1
46 48 56 94 99
102 118
48 56 99 102 118
II
UN1704
2710
6.1
99 118
III
UN1703
2711
2.3
46 56 88 99 102
X
UN1705
2714
2.3
X
UN1510
UN2573
2735
2746
Thallium compounds, n.o.s.
UN1707
2747
89 108 118
II
Thallium nitrate
UN2727
2748
5.1
5.1
6.1
6.1
9.2
6.1
5.1
46 48 56 88 99
102
46 48 56 99 102
46 48 118
46 118
II
46 109
II
46 102 109 118
III
Thallium sulphate, solid,
see Thallium compounds, n.o.s.*
Vanadium pentoxide
UN2862
2900
Zinc cyanide
UN1713
3047
Class
6.1
Special
Provisions
48 56 99 102 118
Packing
Group
II
III
I
I
II
2749
6.1
9.2
6.1
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